Search results for "city"
showing 10 items of 12465 documents
Loading and release of the complex [Pt(DTBTA)(DMSO)Cl]Cl·CHCl3 with the 2,2′-dithiobis(benzothiazole) ligand into mesoporous silica and studies of an…
2018
Abstract Synthetic delivery systems have great potential for overcoming problems associated with systemic toxicity that accompanies chemotherapy with the use of cisplatin and family of platinum anticancer drugs. Mesoporous silicates have been studied in context of drug delivery and drug targeting. In this paper we report the studies of loading and release of a platinum complex, [Pt(DTBTA)(DMSO)Cl]Cl∙CHCl3 (1) where DTBTA = 2,2′-dithiobis(benzothiazole), that was recently synthesized and structurally characterized. Evaluation in vitro of antitumor activity against a human breast cancer cell line (MCF-7) showed a very potent activity of complex(1). Therefore, we thought to incorporate this co…
Self-assembled multivalent (SAMul) ligand systems with enhanced stability in the presence of human serum
2019
Self-assembled cationic micelles are an attractive platform for binding biologically-relevant polyanions such as heparin. This has potential applications in coagulation control, where a synthetic heparin rescue agent could be a useful replacement for protamine, which is in current clinical use. However, micelles can have low stability in human serum and unacceptable toxicity profiles. This paper reports the optimi- sation of self-assembled multivalent (SAMul) arrays of amphiphilic ligands to bind heparin in competitive conditions. Specifically, modification of the hydrophobic unit kinetically stabilises the self-assembled nanostructures, preventing loss of binding ability in the presence of…
Regulating blockchain for sustainability? The critical relationship between digital innovation, regulation, and electricity governance
2021
Abstract Blockchain technology has found several innovative applications in the electricity industry. However, its potential has still to be discovered. This is partly due to the role that regulation plays in electricity markets. To be introduced, experimented with, and eventually adopted on a commercial scale, blockchain-supported innovations need to fit the existing regulatory framework or the rules to be reshaped or updated. We focus on energy regulators' possible responses to the blockchain-enhanced market operations (both from the incumbents and potential newcomers), suggesting a monitoring mechanism that can support innovation.
Image retrieval system for citizen services using penalized logistic regression models
2020
This paper describes a procedure to deal with large image collections obtained by smart city services based on interaction with citizens providing pictures. The semantic gap between the low-level image features and represented concepts and situations has been addressed using image retrieval techniques. A relevance feedback procedure is proposed for Content-Based Image Retrieval (CBIR) based on the modelling of user responses. One of the novelties of the proposal is that the feedback learning procedure can use the information that citizens themselves can provide when using these services.The proposed algorithm considers the probability of an image belonging to the set of those sought by the …
5G IoT system for real-time psycho-acoustic soundscape monitoring in smart cities
2020
In Next-Generation Technologies, the monitoring of environmental noise nuisance in the Smart City should be as efficient as possible. 5G IoT systems offer a great opportunity to offload the node calculation, as they provide a number of new concepts for dynamic computing that previous technologies did not offer. In this case, a complete 5G IoT system for psycho-acoustic monitoring has been implemented using different options to offload the calculation of the parameters to different parts of the system. This offloading has been implemented by directly computing the metrics in the node (as a Raspberry Pi), and in a ESP32 device (FiPy) and by sampling the audio and sending it to the EDGE in the…
Energy and economic analysis of air-to-air heat pumps as an alternative to domestic gas boiler heating systems in the South of Italy
2019
Abstract According to the electricity tariff recently issued by the Italian government for the domestic heating systems fed with heat pumps (HP), an energy and economic analysis was carried out with the aim of investigating the effectiveness of the air-to-air heat pump systems (HPS) as an alternative to the traditional heating using domestic gas boilers systems (GBS). For the purpose of this study, the apartments of three residential buildings were examined. The hourly heating loads were calculated with the ASHRAE radiant time series and the coefficient of performance (COP) of the HPs was evaluated for each operating condition. The costs for the heating system installation and electricity a…
Five-years-long effects of the Italian policies for photovoltaics on the energy demand coverage of grid-connected PV systems installed in urban conte…
2016
Abstract The paper examines the responsiveness of the electricity demand coverage in urban contexts to the changes in the Italian policies for PV systems. The morphological configuration of building roofs according to the number of covered flats, annual data of PV generation and electricity consumptions were considered in the transition from the feed-in tariff (FIT) mechanism to the tax credits scheme currently in force. With the aim of assessing the changes over time in three representative cities, the fluctuations both in the premiums for the produced electricity and the tax credits applied to the PV system costs were observed from July 2010 to February 2016. Furthermore, the main time-va…
Solar and Heat Pump Systems for Domestic Hot Water Production on a Small Island: The Case Study of Lampedusa
2020
The achievement of United Nations Sustainable Development Goals, related to energy and resource use, is a critical issue for small and insulated communities. In many minor islands, solar energy is not correctly exploited, and electrical heaters are connected to weak grids with very a high share of generation by fossil fuels. As a consequence, there is the necessity to assess the potential and the suitability of diffusion of alternative systems to avoid dependency on the electrical grid and reduce carbon emissions. This paper aims to evaluate the technical and economic performances of some alternative systems exploiting renewable energy for domestic hot water production. Four different syste…
Sea water desalination and energy consumption: A case study of wave energy converters (WEC) to desalination applications in sicily
2016
Recent studies about interactions among energy and water are considered as a new field of research. As almost all energy generation processes require significant amounts of water, and water requires energy for treatment and transport, so these two resources are inextricably linked. The main aim of this work is a presentation of the use of renewable energy for desalination plants in Sicily: in particular exploitation of wave energy into electrical energy necessary for water treatment. Desalination is the most energy intensive water treatment technology but it could be solution for many problems in water supply for areas with chronic debt of water. The aim of this work is a description of a s…
Smart Urban Energy Districts and Energy Policies
2018
The deployment of smart cities appears a strategic factor for reducing environmental impact and increasing competitivity of economic systems across the world. Although terminology is similar worldwide, the different political assets and social enviroments largely affect the development models. Drivers indeed are quite different, such as the speed at which transformations take place. As a result, implementation of measures is carried out differently and realizations of smart city projects can be strongly different. Europe, China and U.S.A. approaches are compared in this paper to provide the reader with a broader view about different smart city implementations, with a focus on the electricit…