Search results for "clay mineral"
showing 10 items of 84 documents
A multi-technique characterisation of cronstedtite synthetized by iron-clay interaction in a step by step cooling procedure
2013
International audience; The cooling of steel containers in radioactive-waste storage was simulated in a step-by-step experiment from 90 to 40 degrees C. Among newly formed clay minerals observed in run products, cronstedtite was identified by a number of analytical techniques (powder X-ray diffraction, transmission electron microscopy, and scanning electron microscopy). Cronstedtite has not previously been recognized to be so abundant and so well crystallized in an iron-clay interaction experiment. The supersaturation of experimental solutions with respect to cronstedtite was due to the availability of Fe and Si in solution, as a result of the dissolution of iron metal powder, quartz, and m…
The pore structure of compacted and partly saturated MX-80 bentonite at different dry densities
2014
Compacted MX-80 bentonite is a potential backfill material in radioactive-waste repositories. Pore space in MX-80 has been the subject of considerable debate. 3D reconstructions of the pore space based on tomographic methods could provide new insights into the nature of the pore space of compacted bentonites. To date, few such reconstructions have been done because of problems with the preparation of bentonite samples for electron microscopy. The nanoscale intergranular pore space was investigated here by cryo-Focused Ion Beam nanotomography (FIB-nt) applied to previously high-pressure frozen MX-80 bentonite samples. This approach allowed a tomographic investigation of the in situ microstru…
Interfacial premelting of ice in nano composite materials
2018
Physical chemistry, chemical physics 21, 3734 - 3741 (2019). doi:10.1039/C8CP05604H
The Suitability of Chemically and Thermally Activated Quaternary Clays of Latvia as Raw Material for Geopolymer Binders
2013
It is now accepted that new binders are needed to replace Portland cement (PC) for enhanced environmental and durability performance. The urge to reduce emissions of carbon and the fact that PC structures having built a few decades ago are already facing disintegration problems points out the handicaps of PC binders. Research works carried out in developing of alkali-activated binders show that this new type of binder could have a huge potential to become as alternative building material. Latvian Quaternary clays were studied from the point of view of the national economy, analysing the physical properties and chemical composition of those sediments in connection with the possibilities of …
The Use of Some Clay Minerals as Natural Resources for Drug Carrier Applications
2018
The goal of modern research is to use environmentally preferable materials. In this context, clay minerals are emerging candidates for their bio- and ecocompatibility, low cost and natural availability. Clay minerals present different morphologies according to their layer arrangements. The use of clay minerals, especially in biomedical applications is known from ancient times and they are regaining attention in recent years. The most representative clay minerals are kaolinit, montmorillonite, sepiolites and halloysite. This review summarizes some clay minerals and their derivatives for application as nanocontainer for biologically active species.
Major and trace element compositions (including REE) of mineral, thermal, mine and surface waters in SW Germany and implications for water–rock inter…
2013
Abstract The near-surface water cycle in a geologically complex area comprises very different sources including meteoric, metamorphic and magmatic ones. Fluids from these sources can react with sedimentary, magmatic and/or metamorphic rocks at various depths. The current study reports a large number of major, minor and trace element analyses of meteoric, mineral, thermal and mine waters from a geologically well-known and variable area of about 200 × 150 km in SW Germany. The geology of this area comprises a Variscan granitic and gneissic basement overlain in parts by Triassic and Jurassic shales, sandstones and limestones. In both the basement and the sedimentary rocks, hydrothermal mineral…
Mineral and trace element composition of the Lokpanta oil shales in the Lower Benue Trough, Nigeria
2011
Abstract The concentrations of minerals and trace elements in the Lokpanta oil shale from the Lower Benue Trough, Nigeria have been determined by X-ray diffraction (XRD) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), respectively. X-ray diffraction data were evaluated using the SIROQUANT™ interactive data processing system based on Rietveld interpretation methods. A new method of trace element determination in oil shale, involving LA-ICP-MS analysis of glass beads prepared by fusing oil shale ash on an iridium strip heater was used, and the accuracy of the method was assessed by including a standard shale reference material (SGR-1b) in the analysis program. The…
Application of differently treated illite and illite clay samples for the development of ceramics
2017
Abstract This study represents the results of investigations on the possible geopolymer formation of an alkali, mechanically and thermally (including hydrothermally) activated 2:1 layer silicate, namely, illite and illite clay, for low-temperature ceramic products. The main starting materials were Quaternary illite clay samples taken from the Apriki–Laza pit in Latvia. For the investigations, an intermediate composition of illite clay and separated illite were used. The following research methods for the treated illite and illite clay were used: the phase transition was analysed by differential thermal analysis, while the phase compositions, microstructures and structures were analysed by X…
Sm-Nd dating of Fig Tree clay minerals of the Barberton greenstone belt, South Africa.
1994
Sm-Nd isotopic data from carbonate-derived clay minerals of the 3.22-3.25 Ga Fig Tree Group, Barberton greenstone belt, South Africa, form a linear array corresponding to an age of 3102 +/- 64 Ma, making these minerals the oldest dated clays on Earth. The obtained age is 120-160 m.y. younger than the depositional age determined by zircon geochronology. Nd model ages for the clays range from approximately 3.39 to 3.44 Ga and almost cover the age variation of the Barberton greenstone belt rocks, consistent with independent evidence that the clay minerals are derived from material of the belt. The combined isotopic and mineralogical data provide evidence for a cryptic thermal overprint in the …
Actinide Sorption Studies Using the Isotopes237Np and239Np
2008
The sorption of Np(V) on γ-Al2O3 and the reference clay mineral kaolinite was studied in batch experiments in the presence and absence of ambient CO2 with 0.1 M NaClO4 as background electrolyte. The short-lived isotope 239Np (t1/2 = 2.36 d) was used instead of 237Np (t1/2 = 2.14 × 106 a) to study the sorption behaviour of Np(V) at environmentally-relevant concentrations, i.e., 7 pM Np. In addition, 239Np served as tracer to measure sorption isotherms over six orders of magnitude in neptunium concentration. γ-Al2O3 served as a reference for clay minerals like kaolinite to investigate the interaction of Np(V) with aluminol groups, which are crucial binding sites of clays.