Search results for "clay minerals"
showing 10 items of 77 documents
Current Status of Nanoclay Phytotoxicity
2018
The use of nanotechnology in several fields has created a great interest and its rapid development with application in material science, nanomedicine, medical diagnosis, computer chips, catalysis and so on. The use of nanomaterials represents various advantages, including size, highly active surfaces, unique physico-chemical properties, and in some cases a controlled release of chemicals. In this context phyto-nanotechnology is growing and has promising application in agricultural aspects, such as use of soil remediation, antioxidants, adsorbents, nano-sensor for detection of soil quality, delivery of fertilizers and many others. Plants are very important components of the terrestrial eco-s…
Transformation of clay-sized minerals in soils exposed to prolonged regular alternation of redox conditions
2016
Abstract The direction of the transformation of Fe-bearing minerals under harshly changing redox conditions is still under debate. Some studies suggest preferential accumulation of weakly crystalline Fe oxides while other studies showed that repeated redox cycles favour the presence of crystalline phases. Since characterized by distinct redox cycles, paddy soils are ideal for studying redox-related transformations of Fe oxides and Fe-bearing clay minerals. We analysed changes in the Fe mineral assemblage upon long-term reduction–oxidation cycles along a chronosequence of 100, 700, and 2000-year-old paddy soils developed on comparable parent material relative to two non-irrigated counterpart…
Mineralverwitterung, tonmineralbildung und rubefizierung in Terrae calcis der slowakei Ein beitrag zum paläoklimatischen aussagewert von kalkstein-Ro…
1984
Mineral weathering, clay mineral formation and rubefication of Terrae calcis in Slovakia — A contribution to paleoclimatic evidence of limestone Rotlehm (terra rossa) in Central Europe Limestone Rotlehm (Terra rossa) is very often interpreted as a product of intensive mineral weathering and clay formation under subtropic (to tropic) climate. Especially the formation of hematite in soils as the main process of rubefication is generally believed to occur only in warm climates with a seasonal alternation of precipitation and drought. Fossil or relict Terrae rossae in Central Europe are therefore very often considered as witnesses of a corresponding paleoclimate. On the other side many authors …
Importance des variations latérales discrètes dans les apports détritiques, observées dans des faciès de rampe sédimentaire riches en matière organiq…
2017
17 pages; International audience; We studied a potential petroleum source rock deposited in a clastic-dominated ramp environment: the Argiles de Châtillon Formation (Kimmeridgian-Tithonian, Boulonnais area, northern France). The formation was deposited along a proximal-distal gradient on this ramp affected by synsedimentary fault movements. A sedimentological, mineralogical and geochemical study was conducted to decipher the distribution patterns of sedimentary parameters along such a depth increase over the ramp. It comes out that smectite distribution unexpectedly mimics the lateral depth evolution despite the good floatability of the mineral. It is also observed that the Argiles de Châti…
The behaviour of zirconium and hafnium during water-rock interaction
2018
Abstract Zr and Hf are two elements with same ionic charge and similar ionic size at a given coordination number. Despite the Zr/Hf ratio is quite constant in meteorites and lithospheric rocks, in natural waters can be either higher or lower compared to values of interacting minerals and rocks. Here, we reanalyze very recent published and present new data on continental and brine waters indicating that the Zr and Hf behavior is dependent on the properties of the authigenic phases formed during the water-rock interaction process. Our results show that water pH in the range between 1 and 9 and water ionic strength in the range between 0.001 and 4 mol kg−1 are responsible for the change of the…
Influence of Glass Additions on Illitic Clay Ceramics
2020
A mixture of an illitic clay and waste glass was prepared and studied during the sintering process. The illitic clay, from the Liepa deposit (Latvia), and green glass waste (GW) were disintegrated to obtain a homogeneous mixture. The addition of disintegrated GW (5&ndash
A multi-technique characterisation of cronstedtite synthetized by iron-clay interaction in a step by step cooling procedure
2013
International audience; The cooling of steel containers in radioactive-waste storage was simulated in a step-by-step experiment from 90 to 40 degrees C. Among newly formed clay minerals observed in run products, cronstedtite was identified by a number of analytical techniques (powder X-ray diffraction, transmission electron microscopy, and scanning electron microscopy). Cronstedtite has not previously been recognized to be so abundant and so well crystallized in an iron-clay interaction experiment. The supersaturation of experimental solutions with respect to cronstedtite was due to the availability of Fe and Si in solution, as a result of the dissolution of iron metal powder, quartz, and m…
The pore structure of compacted and partly saturated MX-80 bentonite at different dry densities
2014
Compacted MX-80 bentonite is a potential backfill material in radioactive-waste repositories. Pore space in MX-80 has been the subject of considerable debate. 3D reconstructions of the pore space based on tomographic methods could provide new insights into the nature of the pore space of compacted bentonites. To date, few such reconstructions have been done because of problems with the preparation of bentonite samples for electron microscopy. The nanoscale intergranular pore space was investigated here by cryo-Focused Ion Beam nanotomography (FIB-nt) applied to previously high-pressure frozen MX-80 bentonite samples. This approach allowed a tomographic investigation of the in situ microstru…
Interfacial premelting of ice in nano composite materials
2018
Physical chemistry, chemical physics 21, 3734 - 3741 (2019). doi:10.1039/C8CP05604H
The Suitability of Chemically and Thermally Activated Quaternary Clays of Latvia as Raw Material for Geopolymer Binders
2013
It is now accepted that new binders are needed to replace Portland cement (PC) for enhanced environmental and durability performance. The urge to reduce emissions of carbon and the fact that PC structures having built a few decades ago are already facing disintegration problems points out the handicaps of PC binders. Research works carried out in developing of alkali-activated binders show that this new type of binder could have a huge potential to become as alternative building material. Latvian Quaternary clays were studied from the point of view of the national economy, analysing the physical properties and chemical composition of those sediments in connection with the possibilities of …