Search results for "coating"
showing 10 items of 2834 documents
Chemical composition and microencapsulation suitability of sumac (Rhus coriaria L.) fruit extract
2021
Sumac (Rhus coriaria L.), a spice obtained by grinding whole sumac berries, is a complex natural product with a plethora of biological activities that can be favorably explored in nutraceutical and pharmaceutical fields. Sicilian sumac is herein chemically investigated by means of a combined NMR/HR MS-based profiling. A hydroalcoholic extract was prepared and its complexity unraveled following fractionation in an alcoholic and an aqueous fraction. The 1H-NMR spectrum of this latter fraction was dominated by the signals of gallic acid and its derivatives, whereas HR MS and HR MS/MS analyses highlighted the diversity in malic acid derivatives. Gallotannins and galloyl flavonol glycosides with…
Excitation Transfer Engineering in Ce-Doped Oxide Crystalline Scintillators by Codoping with Alkali-Earth Ions
2018
This work has been supported by the European Social Fund Measure No. 09.3.3-LMT-K-712 activity Improvement of Researchers Qualification by Implementing the World-Class R&D Projects, and by grant #14.W03.31.0004 of the Russian Federation Government. Authors are grateful to CERN Crystal Clear Collaboration and COST Action TD1401 "Fast Advanced Scintillator Timing (FAST)" for support of collaboration.
Chromogenic detection of nerve agent mimics
2008
The current rise in international concern over criminal terrorist attacks via chemical warfare (CW) agents has resulted in an increasing interest in the detection of these lethal chemicals. Among CW species, nerve agents are extremely dangerous and their high toxicity and ease of production underscore the need to detect these deadly chemicals via quick and reliable procedures. A number of detection systems have been developed, most of them based on enzymatic and physical methodologies. However, these usually show limitations such as low selectivity, lack of portability and a certain complexity in their use. An alternative to these classical methods that has been gaining interest in recent y…
Multiphoton Absorption of Myoglobin Nitric-Oxide complex: Relaxation by D-NEMD of a Stationary State
2012
ABSTRACT: The photodissociation and geminate recombination of nitric oxide in myoglobin, under continuous illumination, is modeled computationally. The relaxation of the photon energy into the protein matrix is also considered in a single simulation scheme that mimics a complete experimental setup. The dynamic approach to non-equilibrium molecular dynamics is used, starting from a steady state, to compute its relaxation to equilibrium. Simulations are conducted for the native form of sperm whale myoglobin and for two other mutants, V68W and L29F, illustrating a fair diversity of spatial and temporal geminate recombination processes. Energy flow to the heme and immediate protein environment …
Hyaluronan‐coated poly(propylene imine) dendrimers as biomimetic nanocarriers of doxorubicin
2022
A coating technology based on low molecular weight hyaluronic acid (HA) and ferulic acid (FA) was applied to the coating of low generation poly(propylene imine) dendrimers through a biocompatible hexa(ethylene glycol) spacer. The ensuing HA-FA-HEG-PPID dendrimeric materials showed interesting loading capability (between 7.65% and 9.08%) regarding anticancer agent doxorubicin, and their interactions with the drug appeared to hamper the drug release in the physiological environment. Thus, the stable nanostructured loaded delivery systems were able to internalize into cells expressing the HA receptor CD44 and to demonstrate high cytotoxicity comparable to that shown by equivalent amounts of fr…
Statistical study of the influence of CNTs purification and plasma functionalization on the properties of Polycarbonate-CNTs nanocomposites
2014
This work reports a statistical study on the relationship between the chemical-physical properties of CNTs, which vary by changing the conditions of purification and plasma treatment, and the macroscopic properties of PC-based nanocomposites. CNTs are synthesized and then purified in two different ways and used as fillers for the preparation of PC/CNTs nanocomposites. In some cases, oxygen plasma treatment is carried out to improve their affinity to the matrix. The CNTs are characterized by TGA, ICP/OES and FT-Raman spectroscopy, titration and morphological analysis. Mechanical, dynamic-mechanical, electrical and morphological tests are used for characterizing PC/CNTs nanocomposites.
Ferritin-Coated SPIONs as New Cancer Cell Targeted Magnetic Nanocarrier
2023
Superparamagnetic iron oxide nanoparticles (SPIONs) may act as an excellent theragnostic tool if properly coated and stabilized in a biological environment, even more, if they have targeting properties towards a specific cellular target. Humanized Archaeoglobus fulgidus Ferritin (HumAfFt) is an engineered ferritin characterized by the peculiar salt-triggered assembly-disassembly of the hyperthermophile Archaeoglobus fulgidus ferritin and is successfully endowed with the human H homopolymer recognition sequence by the transferrin receptor (TfR1 or CD71), overexpressed in many cancer cells in response to the increased demand of iron. For this reason, HumAfFt was successfully used in this stud…
Bright Visible Luminescence in Silica Nanoparticles
2011
International audience; We demonstrate that a porous film of silica nanoparticles emits a bright visible luminescence associated with defects stabilized by oxygen chemisorption at oxygen deficient center sites. Time-resolved spectra excited by a tunable laser allow us to distinguish the luminescence at 1.99 eV, characteristic of the nonbridging oxygen hole center (NBOHC) (Si-O)3 Si-O*, and a fast and a slow emission: the first (lifetime τ ≈ 25 ns) is peaked at 2.27 eV with an excitation spectrum centered at 5.5 eV; the second (τ ≈ 7.5 μs) is peaked at 2.41 eV and is excited around 3.2 and 5.2 eV. Reaction in an air atmosphere leads to the disappearance of the NBOHC luminescence and of the …
Study of Intumescent Coatings Growth for Fire Retardant Systems in Naval Applications: Experimental Test and Mathematical Model
2022
Onboard ships, fire is one of the most dangerous events that can occur. For both military and commercial ships, fire risks are the most worrying; for this reason they have an important impact on the design of the vessel. The intumescent coatings react when heated or in contact with a living flame, and a multi-layered insulating structure grows up, protecting the underlying structure. In this concern, the aim of the paper is to evaluate the intumescent capacity of different composite coatings coupling synergistically modeling and experimental tests. In particular, the experiments have been carried out on a new paint formulation, developed by Colorificio Atria S.r.l., in which the active comp…
A probabilistic long‐term framework for site‐specific erosion analysis of wind turbine blades: A case study of 31 Dutch sites
2021
Abstract Rain‐induced leading‐edge erosion (LEE) of wind turbine blades (WTBs) is associated with high repair and maintenance costs. The effects of LEE can be triggered in less than 1 to 2 years for some wind turbine sites, whereas it may take several years for others. In addition, the growth of erosion may also differ for different blades and turbines operating at the same site. Hence, LEE is a site‐ and turbine‐specific problem. In this paper, we propose a probabilistic long‐term framework for assessing site‐specific lifetime of a WTB coating system. Case studies are presented for 1.5 and 10 MW wind turbines, where geographic bubble charts for the leading‐edge lifetime and number of repai…