Search results for "column"

Solution versus Fluorous versus Solid-Phase Synthesis of 2,5-Disubstituted 1,3-Azoles. Preliminary Antibacterial Activity Studies

2009

A small library of compounds with an oxa(thia)zole scaffold and structural diversity in both positions 2 and 5 has been synthesized. Double acylation of a protected glycine affords intermediate α-amido-β-ketoesters, which in turn can be dehydrated to afford 1,3-oxazoles or reacted with Lawesson’s reagent to furnish 1,3-thiazoles. This procedure was designed with its adaptation to fluorous techniques in mind. Thus, when a protected glycine with a fluorous tag in the ester moiety is used as a starting material, the synthesis can be easily completed without column chromatography purification of intermediate compounds with good to excellent yields, thus affording a suitable entry to the prepara…

4-hydroxy-ONN-azoxybenzene

2000

The oxidation of 4-hydroxy­azo­benzene provided a mixture of two azoxy compounds, which were separated by column chromatography. The isomer with the higher melting point appeared to belong to the α (ONN) series, as determined by X-ray diffraction. The mol­ecule, C12H10N2O2, is almost planar. The benzene rings are twisted by 11.7 (2) (substituted) and 4.1 (1)° (unsubstituted) with respect to the ONN plane. The mol­ecules are connected to one another by strong O—H⋯O hydrogen bonds forming chains extended along [001], which are bound by much weaker C—H⋯O hydrogen bonds forming layers in the bc plane.

Invasion Ability and Disease Dynamics of Environmentally Growing Opportunistic Pathogens under Outside-Host Competition

2014

Most theories of the evolution of virulence concentrate on obligatory host-pathogen relationship. Yet, many pathogens replicate in the environment outside-host where they compete with non-pathogenic forms. Thus, replication and competition in the outside-host environment may have profound influence on the evolution of virulence and disease dynamics. These environmentally growing opportunistic pathogens are also a logical step towards obligatory pathogenicity. Efficient treatment methods against these diseases, such as columnaris disease in fishes, are lacking because of their opportunist nature. We present a novel epidemiological model in which replication and competition in the outside-hos…

A link between ectoparasite infection and susceptibility to bacterial disease in rainbow trout

2006

Rainbow trout, Oncorhynchus mykiss, were infected concomitantly with Argulus coregoni and Flavobacterium columnare and their survival was compared with that of fish infected with either the parasite or the bacterium alone. The mortality of fish challenged with A. coregoni was negligible while infection with F. columnare alone led to significantly lower survival. However, compared with single infections, the mortality was significantly higher and the onset of disease condition was earlier among fish, which were concomitantly infected by A. coregoni and F. columnare. This data presents, for the first time, experimental support for the hypothesis that an ectoparasite infection increases suscep…

Bioaccumulation of hepatotoxins : A considerable risk in the Latvian environment

2014

Abstract The Gulf of Riga, river Daugava and several interconnected lakes around the City of Riga, Latvia, form a dynamic brackish-freshwater system favouring occurrence of toxic cyanobacteria. We examined bioaccumulation of microcystins and nodularin-R in aquatic organisms in Latvian lakes, the Gulf of Riga and west coast of open Baltic Sea in 2002–2007. The freshwater unionids accumulated toxins efficiently, followed by snails. In contrast, Dreissena polymorpha and most lake fishes (except roach) accumulated much less hepatotoxins. Significant nodularin-R concentrations were detected also in marine clams and flounders. No transfer of nodularin-R and microcystins between lake and brackish …

Noticias del caos

2007

Bomberos pirómanos / 2

2008

Barcelone capitale du Sud?

1987

Experimental Investigation on the Compressive Behaviour of Clay Brick Masonry Columns Confined by BFRP or Steel Wires

2016

This paper presents the results of an experimental research aiming to investigate on the compressive behavior of full size clay brick masonry columns reinforced with Basalt Fiber Reinforced Cementitious Matrix (BFRCM) or with steel wires collaring. Uniaxial compressive tests were performed on eight retrofitted columns and four control specimens. Two masonry strength were considered by varying the mortar grade. Results are presented and discussed in terms of axial stress-strain relationships, failure modes and crack patterns of the specimens tested up to failure. For the limit of investigated variables, comparisons with unreinforced specimens show the ability of these alternative techniques …

Stiffness and strength of composite truss beam to R.C. column connection in MRFs

2015

Abstract The results of experimental and numerical investigations on the cyclic behavior of composite truss beam to reinforced concrete column connection of moment resisting frames are reported. The beams are constituted by a steel truss and end zone added rebar embedded within a concrete block cast in place, so that, after curing, the steel truss and the added rebar work together with the concrete matrix as reinforcement of the composite beam. Particularly, three specimens of two-span continuous beams were tested under monotonic and cyclic actions as three point bending test. With the goal to investigate about the behavior of the end zone of the beam integrated into a moment resisting fram…