Search results for "columns"
showing 10 items of 40 documents
Performance of different C18 columns in reversed-phase liquid chromatography with hydro-organic and micellar-organic mobile phases
2014
Column selection in reversed-phase liquid chromatography (RPLC) can become a challenge if the target compounds interact with the silica-based packing. One of such interactions is the attraction of cationic solutes to the free silanols in silica-based columns, which is a slow sorption-desorption interaction process that gives rise to tailed and broad peaks. The effect of silanols is minimised by the addition of a competing agent in the mobile phase, such as the anionic surfactant sodium dodecyl sulphate (SDS). In micellar-organic RPLC, the adsorption of an approximately fixed amount of SDS monomers gives rise to a stable modified stationary phase, with properties remarkably different from th…
Modelling of FRP and FRCM-Confined Masonry Columns: Critical Review for Design and Intervention Strategies
2022
This paper presents a critical review of the most established analytical models for the prediction of the compressive strength of FRP and FRCM-confined masonry columns. In particular, two types of fibres are analysed, i.e. glass and basalt. A wide dataset available in the literature is used for the application of the analytical models and for the development of parametric analyses useful for the critical comparison of FRP vs. FRCM confinement technique and glass vs. basalt fibres to be adopted as reinforcement of masonry substrate. The effects of stiffness and strength of the reinforcement, the number of reinforcing layers, the compressive strength of masonry and the cross-section shape are…
Simplified analytical model for moment–axial force domain in the presence of shear in R.C. members externally strengthened with steel cages
2015
Equations for a hand calculation of moment–axial force domain in the presence of shear for R.C. beam/column externally strengthened with steel angles and strips are developed. The analytical derivation is made assuming, for axial load and flexure, the equivalent stress-block parameters for internal forces, considering the confinement effects induced in the concrete core by external cages both in the cases of strips or angles yielding. Limit states due to bond failure, concrete crushing and yielding of steel angles and strips in flexure and in shear, including moment-to-shear interaction, are considered. The proposed model gives results in a good agreement with available experimental data an…
Experimental Investigation on the Compressive Behaviour of Clay Brick Masonry Columns Confined by BFRP or Steel Wires
2016
This paper presents the results of an experimental research aiming to investigate on the compressive behavior of full size clay brick masonry columns reinforced with Basalt Fiber Reinforced Cementitious Matrix (BFRCM) or with steel wires collaring. Uniaxial compressive tests were performed on eight retrofitted columns and four control specimens. Two masonry strength were considered by varying the mortar grade. Results are presented and discussed in terms of axial stress-strain relationships, failure modes and crack patterns of the specimens tested up to failure. For the limit of investigated variables, comparisons with unreinforced specimens show the ability of these alternative techniques …
“A Miracle of Architecture”: The Billiemi limestone Columns of the Church of San Giuseppe dei Teatini in Palermo and Domenico Fontana’s Method for Li…
2014
La chiesa di San Giuseppe dei Teatini di Palermo (costruita a partire dal 1619), è un’architettura singolare nel panorama internazionale del Sei-Settecento. La realizzazione di una spregiudicata conformazione basilicale con copertura a volte, impostata su una sequenza di colonne monolitiche giganti nelle navate e nella crociera con cupola con sostegni alti fino a 10m, è il risultato della convergenza di più fattori. Il conseguimento di questo traguardo si deve alla scoperta nel territorio di Palermo, alla fine del XVI secolo, di un calcare compatto (il “Billiemi”) dalle qualità estetiche e strutturali assimilabili al marmo e in grado di generare poderosi monoliti. Questa opportunità innescò…
Retrofitting of Existing Steel MR-Frames by Encasing the Columns
2005
Summary The study concerns the behaviour of steel MR-frames subjected to vertical and lateral forces, not properly designed according to capacity design criteria, and upgraded by means of encasing the steel columns with concrete having different grade. The purpose of the paper is to examine if the proposed technique allows one to adequately increase the lateral stiffness and the resistance of the frames. Pushover analyses on multi-storey frames are performed trough a non-linear calculus program, able to take into account of the second order effects. The behaviour of frames with encased columns was compared with those of the bare frames, highlighting that with the proposed technique it is po…
Classification of extra virgin olive oils according to their geographical origin using phenolic compound profiles obtained by capillary electrochroma…
2009
Abstract A simple and reliable method for the evaluation of the phenolic fraction of extra virgin olive oils (EVOO) by capillary electrochromatography (CEC) with UV–Vis detection, using lauryl acrylate (LA) ester-based monolithic columns, has been developed. The percentages of the porogenic solvents in the polymerization mixture, and the mobile phase composition, were optimized. The optimum monolith was obtained with a monomers/porogens ratio of 40:60% (wt/wt) using a LA/1,3-butanediol diacrylate ratio of 70:30% (wt/wt) and a 1,4-butanediol/1-propanol ratio of 25:75% (wt/wt). A satisfactory resolution between the phenolic compounds was achieved in less than 25 min with a 15:85 (v/v) ACN–wat…
Experimental results of RC columns strengthnened with Fiber Reinforced Cementitious Mortars
2012
The structural behaviour of reinforced concrete columns strengthened with a system made up of fibre nets embedded in an inorganic stabilized cementitious matrix was investigated. Specimens with circular and square cross-section were cast and subjected to monotonic uniaxial compression to investigate the efficiency of a Polypara-phenylene-benzo-bisthiazole (PBO) Fibre Reinforced Cementitious Mortars (FRCM) system in increasing both carrying capacity and ductility. The experimental results show that confinement with PBO fibre produced a noticeable increment in strength and ductility, though the low mechanical ratios of fibre considered were not always able to ensure hardening behaviour up to …
Compressive response of substandard steel-jacketed RC columns strengthened under sustained service loads: From the local to the global behavior
2018
Abstract This paper presents an experimental investigation on substandard partially steel jacketed RC columns strengthened under sustained loads and loaded until failure. The aim of the study is to compare the compressive response of preloaded columns with respect to the tests without preload to obtain a more realistic prediction of load-carrying capacity of structural columns after retrofitting under serviceability loads. The influence of the preload level, the delayed contribution of the confining device during the loading process and the time dependent effects are highlighted for the tested specimens. Based on the experimental observations, an analysis-oriented model is proposed for the …
Analytical prediction of ultimate moment and curvature of RC rectangular sections in compression
2013
This paper presents closed form expressions linking the ultimate bearing capacity to the ultimate curvature of rectangular RC sections subjected to axial load and bending moment acting in one of the two symmetry planes of the section. With respect to possible simplified formulations the following effects are also considered: confinement of the concrete, hardening of the longitudinal reinforcement, and presence of reinforcing bars distributed orthogonally to the neutral axis. The formulation is proposed in dimensional terms after a preliminary definition of the geometrical and mechanical parameters governing the structural response of the class of sections considered. The analytical expressi…