Search results for "complex"
showing 10 items of 5889 documents
Complexity and Nonlinearity Analysis of the Time Series of Electric Field Intensity
2021
In this work, the conditional entropy (CE) and the method of surrogate data are applied on time series of electric field (EF) intensity to explore their degree of complexity and the possible presence of nonlinear dynamics. The time series were obtained during the wide-band cumulative EF intensity monitoring, performed by one sensor of the Serbian EMF RATEL monitoring system installed in the campus area of the University of Novi Sad, and are re-sampled at one sample per two hours over consecutive time epochs of one month duration. The field intensity measurements during the years 2019 and 2020 allowed us to explore the effects of mobility restrictions related to the COVID-19 pandemic on the …
Measurement of ultra-low heating rates of a single antiproton in a cryogenic Penning trap
2019
Physical review letters 122(4), 043201 (2019). doi:10.1103/PhysRevLett.122.043201
Industry 4.0: Advanced digital solutions implemented on a close power loop test bench
2021
Abstract The paradigm of Industry 4.0 allows to increase the efficiency and effectiveness of the production. Companies that will implement advanced solutions in production systems will increase their level of competitiveness and will be able reach high market shares. The present paper is focused on the development of advanced digital solutions to be implemented on a close power loop test bench designed to test high power transmissions for naval unit. In particular, the test configuration consists of a back-to-back connection between two identical mechanical reducers. Since the efficiency of these systems are very high, it is not necessary to use large electric motors, thus managing to conta…
INVESTIGATION OF ELECTRODE MATERIAL-REDOX COUPLE FOR REVERSE ELECTRODYALISIS PROCESSES. PART I: IRON REDOX COUPLES.
2012
The performances of electrodialysis (ED) and reverse electrodialysis (RED) processes depend on several factors, including the nature of the electrode material and of the redox couple adopted to make possible the conversion between electric power and chemical potential. In this paper, the possible utilization of iron-based redox couples (FeCl3/FeCl2, hexacyanoferrate(III)/hexacyanoferrate(II) and Fe(III)-EDTA/Fe(II)-EDTA) on graphite and DSA electrodes for RED processes was studied by a detailed experimental investigation. The hexacyanoferrate(III)/hexacyanoferrate(II) system was stable for lonf time (more than 12 days) in the absence of light and oxygen at high redox couple concentrations a…
Simple electrochemical reduction of nitrones to amines.
2018
Only electricity is needed for the transformation of nitrones to amines. Such a direct double reduction has not been reported by any sole chemical reagent in a single step process.
Intracranial measurement of current densities induced by transcranial magnetic stimulation in the human brain
2003
Transcranial magnetic stimulation (TMS) is a non-invasive technique that uses the principle of electromagnetic induction to generate currents in the brain via pulsed magnetic fields. The magnitude of such induced currents is unknown. In this study we measured the TMS induced current densities in a patient with implanted depth electrodes for epilepsy monitoring. A maximum current density of 12 microA/cm2 was recorded at a depth of 1 cm from scalp surface with the optimum stimulation orientation used in the experiment and an intensity of 7% of the maximal stimulator output. During TMS we recorded relative current variations under different stimulating coil orientations and at different points…
Hidden Structural Features of Multicompartment Micelles Revealed by Cryogenic Transmission Electron Tomography
2014
The demand for ever more complex nanostructures in materials and soft matter nanoscience also requires sophisticated characterization tools for reliable visualization and interpretation of internal morphological features. Here, we address both aspects and present synthetic concepts for the compartmentalization of nanoparticle peripheries as well as their in situ tomographic characterization. We first form negatively charged spherical multicompartment micelles from ampholytic triblock terpolymers in aqueous media, followed by interpolyelectrolyte complex (IPEC) formation of the anionic corona with bis-hydrophilic cationic/neutral diblock copolymers. At a 1:1 stoichiometric ratio of anionic a…
Crystallization of Light-Harvesting Complex II From Vicia Faba (Fabaceae)
1998
The most abundant chlorophyll binding complex in plants is the intrinsic light-harvesting complex II (LHC II), comprising about half of the total chlorophyll in thylakoid membranes. The structure of LHC II has been determined by electron crystallography, providing a three-dimensional map at 3.4 A (1). Nevertheless, high-resolution structure based on x-ray crystallography is still missing because of the lack of highly ordered 3-D crystals. While delipidation of membrane proteins suitable for high-quality 3-D crystals seems to be a prerequisite, in case of LHC H delipidation leads to a loss of the ability to crystallize. So far, standard purification methods like chromatography have been proo…
The nature of inter- and intramolecular interactions in F2OXe…HX (X= F, Cl, Br, I) complexes
2015
Electronic structure of the XeOF2 molecule and its two complexes with HX (X= F, Cl, Br, I) molecules have been studied in the gas phase using quantum chemical topology methods: topological analysis of electron localization function (ELF), electron density, ρ(r), reduced gradient of electron density |RDG(r)| in real space, and symmetry adapted perturbation theory (SAPT) in the Hilbert space. The wave function has been approximated by the MP2 and DFT methods, using APF-D, B3LYP, M062X, and B2PLYP functionals, with the dispersion correction as proposed by Grimme (GD3). For the Xe-F and Xe=O bonds in the isolated XeOF2 molecule, the bonding ELF-localization basins have not been observed. Accord…
Theoretical Study of the 15- and 17-Electron Structures of Cyclopentadienylchromium(III) and Cyclopentadienylmolybdenum(III) Complexes. Dichloride an…
1997
International audience; The structure and the energetics of the model systems CpMX2(PH3) + PH3 ⇄ CpMX2(PH3)2 (Cp = cyclopentadienyl; M = Cr, Mo; X = Cl, CH3) are studied by performing Møller−Plesset second order (MP2) and density functional theory (DFT) calculations. Extended basis sets are employed in the geometry optimizations. The results indicate that the structural preference can be traced back to the competition between electron pairing stabilization and M−P bond dissociation energy along the spin doublet surface. At all levels of calculation, the energy splitting, a measure of the cost of pairing the electron during the promotion process from the quartet ground state to the excited d…