Search results for "complex"
showing 10 items of 5889 documents
Gas confinement in compartmentalized coordination polymers for highly selective sorption
2016
Discrimination between different gases is an essential aspect for industrial and environmental applications involving sensing and separation. Several classes of porous materials have been used in this context, including zeolites and more recently MOFs. However, to reach high selectivities for the separation of gas mixtures is a challenging task that often requires the understanding of the specific interactions established between the porous framework and the gases. Here we propose an approach to obtain an enhanced selectivity based on the use of compartmentalized coordination polymers, named CCP-1 and CCP-2, which are crystalline materials comprising isolated discrete cavities. These compar…
Alhydrogel® adjuvant, ultrasonic dispersion and protein binding: A TEM and analytical study
2011
Aluminium-based vaccine adjuvants have been in use since the 1920s. Aluminium hydroxide (alum) that is the chemical basis of Alhydrogel, a widely used adjuvant, is a colloid that binds proteins to the particular surface for efficient presentation to the immune system during the vaccination process. Using conventional TEM and cryo-TEM we have shown that Alhydrogel can be finely dispersed by ultrasonication of the aqueous suspension. Clusters of ultrasonicated aluminium hydroxide micro-fibre crystals have been produced (∼ 10-100 nm), that are significantly smaller than those present the untreated Alhydrogel (∼ 2-12 μm). However, even prolonged ultrasonication did not produce a homogenous susp…
European Association for the Study of the Liver Hepatocellular Carcinoma summit 2014: old questions, new (or few) answers?
2014
, the European Association for the Study of the Liver (EASL) organized the 2014 EASL HCC Summit in Geneva, Switzerland from 13 to 16 February 2014. A number of interesting issues on the management of hepatocellular carci-noma (HCC) have been addressed during this meeting. However, our feeling is that only few answers have been given to those questions, mainly because of the still poor knowledge of the molecular basis and the natural history of HCC.HCC is a complex disease, associated in the wide majority of cases with under -lying cirrhosis. In addition, HCC pre-sents with high heterogeneity
Role of Wood Macromolecules on Selective Sorption of Phenolic Compounds by Wood
2008
Wood is a complex structure of various macromolecules, mainly cellulose, hemicellulose, and lignin. Although the sorption process of some organic compounds by wood has been elucidated, the relative contribution of its different fractions in the sorption mechanism is not clearly determined. Certain works predict the amount of organic compounds sorbed on wood as a direct relationship to its lignin fraction. All wood macromolecules, however, seem to have the capacity to sorb organic compounds. Sorption of phenolic compounds on individual wood macromolecules has been studied and compared to that on wood. Wood-water partition coefficients ( K wood) for phenolic volatiles and their sorption rates…
Immobilised Humic Substances as Low-Cost Sorbents for Emerging Contaminants
2021
Environmental pollution with contaminants of emerging concern (CECs) is a worldwide problem that is receiving increasing attention. Although these substances have been released in the aquatic environment for a long time, wastewater treatment plants are still incapable of removing emerging contaminants completely. Consequently, trace metals, metalloids and pharmaceuticals, as well as surfactant leftovers, are often found in environmental samples. Environmentally friendly and cost-effective sorbents such as humic substances can be used for purification if their sorption properties are increased by immobilization. To our knowledge, immobilized humic substances have not been widely studied as s…
Quantum counter automata
2011
The question of whether quantum real-time one-counter automata (rtQ1CAs) can outperform their probabilistic counterparts has been open for more than a decade. We provide an affirmative answer to this question, by demonstrating a non-context-free language that can be recognized with perfect soundness by a rtQ1CA. This is the first demonstration of the superiority of a quantum model to the corresponding classical one in the real-time case with an error bound less than 1. We also introduce a generalization of the rtQ1CA, the quantum one-way one-counter automaton (1Q1CA), and show that they too are superior to the corresponding family of probabilistic machines. For this purpose, we provide gene…
Assessing maintainability change over multiple software releases
2008
The focus of the paper is to reveal the relationships between software maintainability and other internal software quality attributes. The source code characteristics of five Java-based open-source software products are analyzed using the software measurement tool SoftCalc. The relationships between maintainability and internal quality attributes are identified based on the Pearson product moment correlation analysis. Our results show negative correlations between maintainability and some well-known internal software quality attributes, as well as the ones between maintainability and complexity metrics. Particularly, according to our results, the Number of Data Variables Declared and the De…
Space‐time dynamical models
2008
Purpose – The purpose is to present a new formal approach based on a partial integro‐differential equation, the space‐time state transition equation (STSTE), and on a set of general equations with which space‐time dynamical models of complex systems, such as social systems and ecosystems, can be built.Design/methodology/approach – The STSTE provides the partial derivative of the density of a state‐variable with regard to time as a sum of time rates and space‐time rates. Time rates describe the dynamics of the system for each space‐point irrespectively of the other points, whilst space‐time rates describe this evolution as a consequence of the relation of each space‐point with a given set of…
Coxeter on People and Polytopes
2004
H. S. M. Coxeter, known to his friends as Donald, was not only a remarkable mathematician. He also enriched our historical understanding of how classical geometry helped inspire what has sometimes been called the nineteenth-century’s non-Euclidean revolution (Fig. 35.1). Coxeter was no revolutionary, and the non-Euclidean revolution was already part of history by the time he arrived on the scene. What he did experience was the dramatic aftershock in physics. Countless popular and semi-popular books were written during the early 1920s expounding the new theory of space and time propounded in Einstein’s general theory of relativity. General relativity and subsequent efforts to unite gravitati…
Routing Algorithm for Maximizing Lifetime of Wireless Sensor Network for Broadcast Transmission
2018
In the article we discuss solutions of the maximum lifetime broadcasting problem in wireless sensor networks. Due to limited energy resources of the network nodes to find an optimal transmission route of the broadcasted data we minimize the maximum energy consumed by the nodes. We give an analytical solution of the problem in one dimensional regular sensor network for the point-to-point and point-to-multipoint data transmission scheme. We show that in such a network, when the cost of data transmission is a polynomial function of distance between transmitter and receiver, there exist solutions with an equal energy, i.e., all nodes of the network consume the same amount of energy. We assume t…