Search results for "complex"
showing 10 items of 5889 documents
Analysis of Chromatin Structure and Composition
1989
Introduction Biochemistry, like many other sciences, is currently undergoing increasing specialization which is thought to be unavoidable because of the rapid progress within this field. Obviously education in Biochemistry and Molecular Biology is also affected. Consequently, the student may lose the ability to integrate his knowledge, which should be a requirement during the training of a scientist. The solution to this problem is quite easy in the case of theoretical courses because, here, the lecturer may include several 'integrative lessons' which give a global view of previously explained facts and place them within the general context of the course. However, in practical courses it is…
The Neural Basis of Idea Density During Natural Spoken Language
2019
Idea density (ID) evolved as a quantification of propositional base structure. Besides its function as a measure of linguistic complexity, ID has also been used as an index of general linguistic ability. In order to find the neural basis for the processing of high or low ID during spontaneous speech, a sample of healthy adults was assessed using the functional resonance imaging (fMRI) technique; participants described pictures presented to them while in the scanner. Differential patterns of activation were observed for the low- and high-ID conditions, providing new insights into the processing correlates of ID.
Opposing Forces of Social Attraction and Social Avoidance Drive Network Modularity
2020
SUMMARY: How interactions between individuals contribute to the emergence of complex societies is a major question in biology. Nonetheless, little remains known about how simple rules of social attraction (e.g. to information) and social avoidance (e.g. of disease) interact to shape sociality. We developed an individual-based model where individuals choose with whom to interact depending on the status of group mates (informed and/or infected). Statistical models indicate that the emergence of social structure depends on the cost/benefit trade-offs underlying the system. Critically, pressures that optimize social relationships – i.e. minimize risky connections while favouring those that maxi…
An Analysis of the Internal Organization of Facebook Groups
2019
With the rapid development and growth of online social networks (OSNs), researchers have been pushed forward to improve the knowledge of these complex networks by analyzing several aspects, such as the types of social media, the structural properties of the network, or the interaction patterns among users. In particular, a relevant effort has been devoted to the study and identification of cohesive groups of users in OSNs (also referred as communities) because they are the basic building block of each OSN. While several research works on groups in OSNs have mainly focused on identifying the types of groups and the contents created by their members, the analysis of internal organizations of …
Reactivity of the ansa-Bridged Metallocene Dichlorides [X(η5-C5H4)2]MCl2 (X = SiMe2, CMe2; M = Mo, W) toward Metallophosphide Anions [PPh2M‘(CO)x]- (…
1997
Two kinds of ansa derivatives, [SiMe2(η5-C5H4)2]MCl2 and [CMe2(η5-C5H4)2]MCl2 (M = Mo, W), are reacted with metallophosphide anions [PPh2M‘(CO)x]- (M‘ = Cr, Mo, W, x = 5; M‘ = Fe, x = 4). The silicon-bridged derivatives give the bimetallic systems [SiMe2(η5-C5H4)(η5-C5H3PPh2M‘(CO)x)]M(H)(Cl), which result from a regioselective substitution at the 3-position on the cyclopentadienyl ligand. In contrast, with the CMe2-bridged compounds, the substitution reaction occurs at the metallic center, giving μ-phosphido bimetallic complexes [CMe2(η5-C5H4)2]M(Cl)(μ-PPh2)M‘(CO)x. The solid-state structure of the bimetallic complex [CMe2(η5-C5H4)2]W(Cl)(μ-PPh2)Fe(CO)4 (7d) is reported.
Iridium(III) Complexes with Phenyl-tetrazoles as Cyclometalating Ligands
2014
Ir(II) cationic complexes with cyclometalating tetrazolate ligands were prepared for the first time, following a two-step strategy based on (i) a silver-assisted cyclometalation reaction of a tetrazole derivative with IrCl3 affording a bis-cyclometalated solvato-complex P ([Ir(ptrz)(2)(CH3CN)(2)](+), Hptrz = 2-methyl-5-phenyl-2H-tetrazole); (ii) a substitution reaction with five neutral ancillary ligands to get [Ir(ptrz)(2)L](+), with L = 2,2'-bypiridine (1), 4,4'-di-tert-butyl-2,2'-bipyridine (2), 1,10-phenanthroline (3), and 2-(1-phenyl-1H-1,2,3-triazol-4-yl)pyridine (4), and [Ir(ptrz)(2)L-2](+), with L = tertbutyl isocyanide (5). X-ray crystal structures of P, 2, and 3 were solved. Elect…
Hydrogels for potential colon drug release by thiol-ene conjugate addition of a new inulin derivative.
2008
Inulin was chosen as a starting polymer for biocompatible, pH-sensitive and biodegradable hydrogels. Three INUDVSA-TT hydrogels were obtained by crosslinking inulin derivatives with trimethylolpropane tris(3-mercaptopropionate) under varying conditions. The resulting hydrogels were cell compatible, as demonstrated by MTS and trypan blue exclusion assays acting on Caco-2 cells, and were biodegraded by inulinase and esterase, thus suggesting their use as colonic drug delivery systems. 2-Methoxyestradiol, an anti-cancer drug, was soaked in INUDVSA-TT hydrogels and its in vitro release and apoptotic effect on Caco-2 cells were evaluated.
Labile carbon alleviates wood ash effects on soil fauna
2008
The combined effects of wood ash, sucrose and oxalic acid on enchytraeid size and biomass, the abundance of microbial-feeding nematodes and pH were studied in a full three-factorial design in laboratory microcosms containing 30 g of Norway spruce forest humus. Wood ash treatment reduced enchytraeid size and abundance, but these effects were offset by sucrose without any change in pH or moisture. The positive effects of sucrose were partially counteracted by oxalic acid. Both carbon compounds increased the abundance of obligate microbial-feeding nematodes, indicating enhanced microbial production.
Volumetric Behaviour of Lime Treated High Plasticity Clay Subjected to Suction Controlled Drying and Wetting Cycles
2017
The paper presents some experimental results collected on samples recovered from an experimental embankment obtained by compacting a lime-treated clay. Samples were collected soon after the in situ compaction and they were cured in controlled environmental conditions for at least 18 months. Mercury intrusion porosimetry tests (MIP) were carried out on freeze-dried specimens to characterize the microstructure of the material. In order to assess the durability of the improved material, laboratory tests focused on the effects of cyclic variations of the degree of saturation on the water retention properties and the volumetric behaviour of the stabilized clay. Collected results show that the li…
Triggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by RuII photocatalysis
2014
The preparation of [FeIV(O)(MePy2tacn)]2+ (2, MePy2tacn = N-methyl-N,N-bis(2-picolyl)-1,4,7-triazacyclononane) by reaction of [FeII(MePy2tacn)(solvent)]2+ (1) and PhIO in CH3CN and its full characterization are described. This compound can also be prepared photochemically from its iron(II) precursor by irradiation at 447 nm in the presence of catalytic amounts of [Ru II(bpy)3]2+ as photosensitizer and a sacrificial electron acceptor (Na2S2O8). Remarkably, the rate of the reaction of the photochemically prepared compound 2 toward sulfides increases 150-fold under irradiation, and 2 is partially regenerated after the sulfide has been consumed; hence, the process can be repeated several times.…