Search results for "complex"
showing 10 items of 5889 documents
Quantum dynamics of the oxygen isotopic exchange : lifetimes of metastable states of the ozone intermediate complex
2021
This thesis aims to describe the ozone dynamics during the isotopic exchange reactions of oxygen of type xO + yO zO (xO yO zO)* xO yO + zO, where x, y and z are the atomic masses of the stable oxygen isotopes (16, 17, 18). Firstly, we analyze several methods of accurate description of the atom interactions and numerical schemes to obtain the observables for the collision. Then, in a full-quantum hyperspherical formalism, we study the actual dynamics of the reactive process O + O2 -> O3* -> O2 + O. The metastable ozone created can then either decompose into oxygen by the inverse reaction, or relax into stable ozone by exchanging energy with the environment, typically N2 or O2 molecules. Thes…
Second zero dispersion wavelength measurement through soliton self-frequency shift compensation in suspended core fibre
2008
International audience; A simple experimental technique to evaluate the second zero dispersion wavelength of very small core microstrutured fibres is described. Based on the effect of soliton self-frequency shift and its subsequent compensation in the vicinity of the second zero dispersion. the proposed method is applied to both standard and suspended core microstructured fibres by simply measuring the frequency stabilised soliton spectrum, avoiding any calculation and knowledge of any experimental parameters.
Full CNF Encoding: The Counting Constraints Case
2004
Many problems are naturally expressed using CNF clauses and boolean cardinality constraints. It is generally believed that solving such problems through pure CNF encoding is inefficient, so many authors has proposed specialized algorithms : the pseudo-boolean solvers. In this paper we show that an appropriate pure CNF encoding can be competitive with these specialized methods. In conjunction with our encoding, we propose a slight modification of the DLL procedure that allows any DLL-based SAT solver to solve boolean cardinality optimization problems. We show experimentally that our encoding allows zchaff to be competitive with pseudo-boolean solvers on some decision and optimization problem…
A Translation of Pseudo Boolean Constraints to SAT
2006
Research note; This paper introduces a new CNF encoding of pseudo-Boolean constraints, which allows unit propagation to maintain generalized arc consistency. In the worst case, the size of the produced formula can be exponentially related to the size of the input constraint, but some important classes of pseudo-Boolean constraints, including Boolean cardinality constraints, are encoded in polynomial time and size. The proposed encoding was integrated in a solver based on the zCha SAT solver and submitted to the PB05 evaluation. The results provide new perspectives in the field of full CNF approach of pseudo-Boolean constraints solving.
Impact of distribution heterogeneity of microorganisms and 2,4-D on biodegradation processes in soil : experiment and modelling
2013
Impact of distribution heterogeneity of microorganisms and 2,4-D on biodegradation processes in soil : experiment and modelling. Conference on Pesticide Behaviour in Soils, Water and Air (York 2013)
Effect of cropping cycles and repeated herbicide applications on the degradation of diclofop-methyl, bentazone, diuron, isoproturon and pendimethalin…
2002
A greenhouse study was conducted to investigate the ability of four crops (wheat, corn, oilseed rape and soybean) to influence the degradation of bentazone, diclofop-methyl, diuron, isoproturon and pendimethalin in soil. The present study showed that microbial biomass-carbon was significantly higher in planted soils than in bulk soil, especially with wheat and corn, after several cropping cycles. The biomass in corn and soybean planted soils was adversely affected by bentazone but recovered after three cropping cycles. In wheat-planted soils, diclofop-methyl application resulted in persistent increase of the amount of microbial biomass. Bentazone did not show accelerated degradation even af…
Monitoring of atrazine treatment on soil bacterial, fungal and atrazine-degrading communities by quantitative competitive PCR
2003
We report the development of quantitative competitive (QC) PCR assays for quantifying the 16S, 18S ribosomal and atzC genes in nucleic acids directly extracted from soil. QC-PCR assays were standardised, calibrated and evaluated with an experimental study aiming to evaluate the impact of atrazine application on soil microflora. Comparison of QC-PCR 16S and 18S results with those of soil microbial biomass showed that, following atrazine application, the microbial biomass was not affected and that the amount of 16S rDNA gene representing 'bacteria' increased transitorily, while the amount of 18S rDNA gene representing fungi decreased in soil. In addition, comparison of atzC QC-PCR results wit…
Leaching of glyphosate and AMPA under two soil management practices in Burgundy vineyards (Vosne-Romanée, 21-France)
2005
Some drinking water reservoirs under the vineyards of Burgundy are contaminated with herbicides. Thus the effectiveness of alternative soil management practices, such as grass cover, for reducing the leaching of glyphosate and its metabolite, AMPA, through soils was studied. The leaching of both molecules was studied in structured soil columns under outdoor conditions for 1 year. The soil was managed under two vineyard soil practices: a chemically treated bare calcosol, and a vegetated calcosol. After 680 mm of rainfall, the vegetated calcosol leachates contained lower amounts of glyphosate and AMPA (0.02% and 0.03%, respectively) than the bare calcosol leachates (0.06% and 0.15%, respectiv…
Mollusc shellomes: Past, present and future.
2020
13 pages; International audience; In molluscs, the shell fabrication requires a large array of secreted macromolecules including proteins and polysaccharides. Some of them are occluded in the shell during mineralization process and constitute the shell repertoire. The protein moieties, also called shell proteomes or, more simply, 'shellomes', are nowadays analyzed via high-throughput approaches. These latter, applied so far on about thirty genera, have evidenced the huge diversity of shellomes from model to model. They also pinpoint the recurrent presence of functional domains of diverse natures. Shell proteins are not only involved in guiding the mineral deposition, but also in enzymatic a…
Copper Dynamics and Impact on Microbial Communities in Soils of Variable Organic Status
2008
International audience; The effect of soil organic status on copper impact was investigated by means of a microcosm study carried out on a vineyard soil that had been amended with varying types of organic matter during a previous long-term field experiment. Soil microcosms were contaminated at 250 mg Cu kg−1 and incubated for 35 days. Copper distribution and dynamics were assessed in the solid matrix by a sequential extraction procedure and in the soil solution by measuring total and free exchangeable copper concentrations. Copper bioavailability was also measured with a whole-cell biosensor. Modifications of microbial communities were assessed by means of biomass-C measurements and charact…