Search results for "complex"
showing 10 items of 5889 documents
Some Considerations on 3-D and 2-D Numerical Models for the Assessment of the Stability of Underground Caves
2014
The application of numerical modeling to the analysis of the stability of both natural and man-made underground caves is rapidly increasing due to the availability of powerful numerical codes, that can account for either continuum or discontinuum behavior of the rock masses. Numerical methods allow to overcome traditional methods for cave stability analysis that assume too simplified geometrical, geological and geomechanical conditions. Further, they are also able to assess the potential failure mechanisms of underground systems. On the other hand, the application of numerical methods requires availability of a detailed geo-structural survey of the cave, as well as a proper geomechanical ch…
The Nhlangano gneiss dome in south-west Swaziland – A record of crustal destabilization of the eastern Kaapvaal craton in the Neoarchaean
2015
Abstract The Nhlangano granite-gneiss in south-west Swaziland, dated at 2.98 Ga, forms an elliptical dome of remobilised, migmatitic crust. Strongly deformed supracrustal rocks wrap around or form synformal keels infolded with subdomes of Nhlangano Gneiss and represent Mesoarchaean Pongola Supergroup strata at amphibolite- to granulite-facies metamorphic grade. Amphibolites represent the metamorphosed equivalents of Nsuze Group basalts and andesites on the basis of similar trace element and Nd isotope data. Garnetiferous Mahamba Gneiss, dated at c. 2.96 Ga, represents the metamorphosed equivalents of felsic to intermediate volcanic rocks and minor pelitic interflow sedimentary units of the …
Variation characteristics of soil respiration fluxes in four types of grassland communities under different precipitation intensity
2005
A two consecutive years’ field experiment was carried out on four types of semiarid grassland along precipitation gradient in Xilin River Basin of Inner Mongolia during 2001–2003 using a static enclosed black chamber technique. The variation characteristics of soil respiration fluxes from four different types of grassland along precipitation gradient were compared. The possible effect of water-heat factors on characteristics of grassland soil respiration was statistically analyzed and the numerical relational model between soil respiration and water-heat factors was established. Meanwhile the soil CO2 annual emissions of different types of grassland were estimated based on the consecutive a…
Toxicity of waste dump leachates and sugar factory effluents and their impact on groundwater and surface water quality in the Opole Province in Poland
2000
A battery of Toxkit microbiotests with 4 aquatic species from different trophic levels has been used to evaluate the toxicity of 2 types of point source pollution in the Voivoidship of Opole in Poland: percolating waters from drainage systems of 4 municipal waste dumps and the effluents of a sugar factory. In addition, the toxicity of groundwaters from 2 wells near 2 waste dumps was also assessed. All the drainage waters of the waste dumps and the groundwaters near one dump (an unprotected landfill) showed toxic effects on all the test species, for samples taken in spring as well as in autumn. The well water of the (more recent) waste dump of the City of Opole in turn did not show any toxic…
Complex-forming properties of peat humic acids from a raised bog profiles
2013
Abstract Humic substances (HS) belong to the most powerful complex-forming agents, significantly affecting major and trace element speciation in natural environment. Several authors have focused on humic–metal interactions, using differing methods and comparing humic substances on different sources. However, the intrinsic differences among the HS of different origin and the impact of humification degree on the complex formation between humic substances and metals have not received the necessary attention until now. The aim of this study is to determine the Cu(II) complexing capacity and stability constants of Cu(II) complexes of humic acids (HA) isolated from two well-characterized raised b…
Equilibrium Studies in Natural Fluids. A Chemical Speciation Model for the Major Constituents of Seawater.
1994
AbstractThe speciation of CI−, OH− and SO42- in synthetic sea water has been studied by Potentiometric measurements (pH-metric and ISE-Na methods) and by literature data analysis, using a well tested complex formation model. Stability constants, together with distribution of hypothesised species in synthetic sea water, as a function of temperature and salinity, are reported. The speciation model proposed in this work is discussed on the basis of chemical and statistical considerations. Comparison with some literature sea water models is given.
Stratospheric aerosol-Observations, processes, and impact on climate
2016
Interest in stratospheric aerosol and its role in climate have increased over the last decade due to the observed increase in stratospheric aerosol since 2000 and the potential for changes in the sulfur cycle induced by climate change. This review provides an overview about the advances in stratospheric aerosol research since the last comprehensive assessment of stratospheric aerosol was published in 2006. A crucial development since 2006 is the substantial improvement in the agreement between in situ and space-based inferences of stratospheric aerosol properties during volcanically quiescent periods. Furthermore, new measurement systems and techniques, both in situ and space based, have be…
Age and isotopic evidence for the origin of the Archæan granitoid intrusives of the Johannesburg Dome, South Africa
1999
Abstract Results of RbSr, PbPb and SmNd whole rock, Rbr biotite and PbPb zircon evaporation analyses are presented for certain granitoid rocks from the Johannesburg Dome. These data indicate that the granodiorite, granite and leucosome from migmatite were emplaced ∼ 3090 Ma ago, were genetically related and were derived primarily from a source between ∼ 3300 and ∼ 3500 Ma old. A portion of the granodiorite and granite might have been derived from a source between ∼ 4000 and ∼ 4300 Ma old. The tonalite was emplaced ∼ 3170 Ma ago and was derived from a source between 3.3 and 3.5 Ga old. RbSr biotite-whole rock ages, ranging between about ∼ 2614 and ∼ 2080 Ma, probably reflect complete r…
Byers Peninsula: A reference site for coastal, terrestrial and limnetic ecosystem studies in maritime Antarctica
2009
Abstract This article describes the development of an international and multidisciplinary project funded by the Spanish Polar Programme on Byers Peninsula (Livingston Island, South Shetlands). The project adopted Byers Peninsula as an international reference site for coastal and terrestrial (including inland waters) research within the framework of the International Polar Year initiative. Over 30 scientists from 12 countries and 26 institutions participated in the field work, and many others participated in the processing of the samples. The main themes investigated were: Holocene changes in climate, using both lacustrine sediment cores and palaeo-nests of penguins; limnology of the lakes, …
Continental extension: From core complexes to rigid block faulting
2005
Extension of overthickened continental crust is commonly characterized by an early core complex stage of extension followed by a later stage of crustal-scale rigid block faulting. These two stages are clearly recognized during the extensional destruction of the Alpine orogen in northeast Corsica, where rigid block faulting overprinting core complex formation eventually led to crustal separation and the formation of a new oceanic backarc basin (the Ligurian Sea). Here we investigate the geodynamic evolution of continental extension by using a novel, fully coupled thermomechanical numerical model of the continental crust. We consider that the dynamic evolution is governed by fault weakening, …