Search results for "composite"

PLLA-BASED SCAFFOLDS FOR OSTEOCHONDRAL TISSUE REGENERATION VIA THERMALLY INDUCED PHASE SEPARATION TECHNIQUE

L’ingegneria tessutale (TE) è una scienza multidisciplinare che mira a progettare e sviluppare sostituti biologici per migliorare, riparare e/o sostituire i tessuti negli organismi umani. Sulla base della tipica triade dell’ingegneria tessutale è incentrato il primo capitolo Scaffold, Source and Signal; lo scaffold funge da struttura tridimensionale, le cellule rappresentano la source mentre il bioreattore fornisce gli adeguati segnali chimico/fisici. In questo lavoro di tesi sono stati presi in considerazione tutti e tre questi aspetti avendo come obiettivo la rigenerazione osteocondrale. La guarigione dei difetti osteocondrali, riguardanti le lesioni della cartilagine che si esten- dono f…

Bis-urea macrocycles with a deep cavity.

2015

Two configurational isomers of bis-urea macrocycles have been synthesized, and their neutral molecule recognition was studied by X-ray crystallography and (1)H NMR experiments. Cooperative action between the deep cavity and the urea groups and the influence of dipole alignments on molecular recognition are discussed.

Preparation and characterization of polyolefin- based nanocomposite blown films for agricultural applications

2009

Polyolefin-based films were prepared in the presence of two different organo-modified clays and characterized. The influence of organo-modifier and matrix composition on film morphology and properties were investigated using SEM, XRD, UV-Vis, FT-IR, contact-angle measurements and mechanical tests. The filler increased the films' rigidity and tear strength. Transparencies were almost unchanged in the visible range, but were reduced for harmful radiation. The presence of the clay increases the greenhouse effect, i.e. it hinders the passage of thermal emission from the soil to the outer part of the greenhouse during the night. The wettability of the materials was not influenced by the presence…

Fluorescent Boron Oxide Nanodisks as Biocompatible Multi-messenger Sensors for Ultrasensitive Ni$^{2+}$ Detection

2023

Boron-based nanocomposites are very promising for a wide range of technological applications, spanning from microelectronics to nanomedicine. A large variety of B-based nanomaterials has been already observed, such as borospherene, B nanotubes and nanoparticles, and boron nitride nanoparticles. However, their fabrication usually involves toxic precursors or leads to very low yields or small boron atom concentration. In this work, we report the synthesis of nanometric B$_{2}$O$_{3}$ nanodisks, a family of nanomaterials with a quasi-2D morphology capable of intense fluorescence in the visible range. Such as boron-based nanomaterial, which we synthesized by pulsed laser ablation of a boron tar…

Farmland abandonment in Europe: Identification of drivers and indicators, and development of a composite indicator of risk

2015

Accounting for more than half of the European Union's (EU) territory, agriculture ensures food production, manages important natural resources and supports socio-economic development of rural areas. Moreover, it is estimated that 50% of all plant and animal species (including some of that are listed in the EU Habitat Directive) depend on agricultural practices. The continuation of appropriate agricultural land management is essential to ensure these primary functions. Avoidance of farmland abandonment is therefore an important rationale for the EU's Common Agricultural Policy which requires improved knowledge of this phenomenon at the European level. This study assesses the risk of farmland…

Study regarding the physical-mechanical properties of knits for garments – pilling performance

2017

The effect of the pilling degradation results is an important decreasing in garment quality and a negative influence on the user’s comfort to wear. There are a lot factors, such as the yarn spinning system, fabric geometry and finishing operation, which affect the pilling performance. This research paper presents the investigation of fabric surface concerning pilling formation, especially knits, influenced by the fibrous composition. As samples were used knitted fabric panels, obtained from carded yarns, with fibers composition like cotton, wool or mixed one. Regarding fabric geometry 3 types were used – single jersey, 2x2 rib and moss stitch. In order to establish which of the yarns are mo…

Flexural Test on a Full-Scale 60-kW Wind Turbine-Tower Telescopic Steel Pipe

2019

A full-scale static test to failure was conducted on 6-m (236.22 in.)-long steel pipes constituting a segment of a telescopic wind tower with a 60-kW wind turbine. The diameter of the circular cross section of the steel pipes was 900 mm (35.43 in.), and the nominal thickness was 10 mm (0.39 in.). The steel grade was 355 MPa (51,488 psi). The tests were conducted in a force-controlled mode in a four-point bending test with a shear-to-span ratio of 2.05. The flexural limit states developed in the form of ovalization of the cross section and of local buckling. The buckling occurred in the plastic range because of the diameter-to-thickness ratio of the section. Although local buckling caused sl…

Raman and optical reflection spectra of germanate and silicate glasses

2005

Abstract Germanate and phosphosilicate glasses made in oxygen surplus conditions were studied by Raman and optical reflection methods. We found that the optical reflection spectra of the germanate glasses are quite similar to the one those of a GeO 2 crystal with the α-quartz structure. The reflection of phosphosilicate glasses is very close to silica glass-related spectra. Hence, the determining influence of the tetrahedral structure on reflection spectra is revealed. The Raman spectra of germanate samples are similar to those reported the one known in the literature. Octahedral entities, namely bands similar to stishovite vibration modes, were difficult to detect in phosphosilicate glasse…

Digital selection of composite resin shade using cross polarized photography and a standardized white balance gray reference card

2021

Purpose The aim of the present case report was to describe, through a clinical case, a step-by-step technique, for the digital selection of composite resin shades using cross polarization and white balance employing a standardized reference card. Case Description After intraoral impression, a digital diagnostic wax up was developed. A 3D printed cast was used to fabricate a lingual polyvinyl siloxane matrix. First a cross-polarized image of the contralateral central incisor was taken in RAW format, using a gray reference card. The digital image was manipulated using this card as a reference, to obtain reliable color values. The obtained color values, from the contralateral central incisor, …

Intraperitoneal adhesions-an ongoing challenge between biomedical engineering and the life sciences

2011

Peritoneal adhesions remain a relevant clinical problem despite the currently available prophylactic barrier materials. So far, the physical separation of traumatized serosa areas using barriers represents the most important clinical strategy for adhesion prevention. However, the optimal material has not yet been found. Further optimization or pharmacological functionalization of these barriers could give an innovative input for peritoneal adhesion prevention. Therefore, a more complete understanding of pathogenesis is required. On the basis of the pathophysiology of adhesion formation the main barriers currently in clinical practice as well as new innovations are discussed in the present r…