Search results for "composition"
showing 10 items of 2675 documents
Efficiency of dihydroxamic and trihydroxamic siderochelates to extract uranium and plutonium from contaminated soils
2021
International audience; Actinide-based mineral phases occurring in contaminated soils can be solubilized by organic chelators excreted by plants, such as citrate. Herein, the efficiency of citrate towards U and Pu extraction is compared to that of siderophores, whose primary function is the acquisition of iron(III) as an essential nutrient and growth factor for many soil microorganisms. To that end, we selected desferrioxamine B (DFB) as an emblematic bacterial trishydroxamic siderophore and a synthetic analog, abbreviated (LCy,Pr)H2, of the tetradentate rhodotorulic acid (RA) produced by yeasts. Firstly, the uranyl speciation with both ligands was assessed in the pH range 2–11 by potentiom…
Efficient Analysis and Synthesis Using a New Factorization of the Gabor Frame Matrix
2018
In this paper, we consider the case in which one needs to carry out Gabor analysis and synthesis on large signals using a short support analysis window and its corresponding, possibly longer canonical dual window, respectively. In this asymmetric context, we propose a novel factorization of the Gabor frame operator that exploits its strong and well-known structure and leads to a computational cost for synthesis, which is comparable to the one needed for short support analysis. The proposed factorization applies to any Gabor system with very mild conditions and leads to a potentially promising alternative to current synthesis algorithms in the case of short analysis windows whose support is …
On the Design of Fast Wavelet Transform Algorithms With Low Memory Requirements
2008
In this paper, a new algorithm to efficiently compute the two-dimensional wavelet transform is presented. This algorithm aims at low memory consumption and reduced complexity, meeting these requirements by means of line-by-line processing. In this proposal, we use recursion to automatically place the order in which the wavelet transform is computed. This way, we solve some synchronization problems that have not been tackled by previous proposals. Furthermore, unlike other similar proposals, our proposal can be straightforwardly implemented from the algorithm description. To this end, a general algorithm is given which is further detailed to allow its implementation with a simple filter bank…
Robust subspace DOA estimation for wireless communications
2002
This paper is concerned with array signal processing in non-Gaussian noise typical in urban and indoor radio channels. Robust and fully nonparametric high resolution algorithms for direction of arrival (DOA) estimation are presented. The algorithms are based on multivariate spatial sign and rank concepts. The performance of the algorithms is studied using simulations. The results show that almost optimal performance is obtained in wide variety of noise conditions.
Probing the radio emission from air showers with polarization measurements
2014
The emission of radio waves from air showers has been attributed to the so-called geomagnetic emission process. At frequencies around 50 MHz this process leads to coherent radiation which can be observed with rather simple setups. The direction of the electric field induced by this emission process depends only on the local magnetic field vector and on the incoming direction of the air shower. We report on measurements of the electric field vector where, in addition to this geomagnetic component, another component has been observed which cannot be described by the geomagnetic emission process. The data provide strong evidence that the other electric field component is polarized radially wit…
Novel silicon microparticles to improve sunlight stability of raw polypropylene
2015
Oxidation of polyolefins by ultraviolet/visible irradiation is a significant limitation for their use in several technological applications. The use of high-tech additives such as silicon microparticles becomes a compositing strategy that can improve the performance of these materials at long-term service conditions. Silicon particles were added to non-additivated raw polypropylene (PP) prepared by hot melt extrusion and subjected to accelerated sunlight irradiation tests. The stability of thermal properties, mechanical performance and thermal decomposition behaviour of composites was evaluated by differential scanning calorimetry, dynamic mechanical thermal analysis and thermogravimetry. T…
Analysis of archaeological pottery by X-ray fluorescence spectrometry applying the limit dilution method
1994
A method for correcting the intensity of x-ray fluorescence (limit dilution method) is proposed for the analysis of samples with a complex matrix such as ceramic materials of archaeological interest. This method corrects the interelement effects, resolving the wide deviations which occur in the quantitative results obtained by x-ray fluorescence without correction. The contents of sodium, magnesium, aluminium, silicon, potassium, calcium, titanium and iron in sixteen archaeological ceramic samples of different origins and from different locations were determined. The results obtained are comparable to the values obtained by chemical analysis. A statistical study of the data was carried out …
The silver collection of San Gennaro treasure (Neaples): A multivariate statistic approach applied to X-ray fluorescence data
2021
Abstract In this work we report an X-ray fluorescence spectroscopy (XRF) study combined with a multivariate approach allowing to detect compositional differences and similarities among the alloys used in realization of silver collection of San Gennaro items collection. The San Gennaro treasure in Naples (Italy) represents, in fact, one of the most important silver collections in the world. The classification of the collection items is very complex, not only for the large number of objects, but also in consideration that between 1600 and 1700, in Naples, more than 350 laboratories were active, most of them specialized in specific art of work. As a consequence, a given collection object could…
La gestion de l'hétérogénéité des publics d'élèves au collège
1997
International audience; Depuis l'instauration du collège unique, tous les élèves d'une classe d'âge sont supposés être scolarisés en premier cycle secondaire dans des contextes de scolarisation identiques. Le texte examine dans quelle mesure les collèges suivent ce principe ou bien constituent en leur sein des classes de niveau ; on conclut, sur la base d'observation de plus de 200 collèges qu'il y a des pratiques variées à cet égard mais qu'une proportion forte de collèges recourt clairement à ce mode de groupement ; on observe qu'il y a en fait davantage de variété produite par les collèges par la constitution de classes que les collèges n'en héritent de par la carte scolaire.Le texte exa…
Identification and Evaluation of Hazardous Pyrolysates in Bio-Based Rigid Polyurethane-Polyisocyanurate Foam Smoke
2021
In this study, rigid polyurethane (PU) and polyisocyanurate (PIR) foam samples made from renewable material (tall oil fatty acid) based polyols were analyzed by pyrolysis gas chromatography mass spectrometry (Py-GC/MS) to obtain information about the full relative smoke content, with a focus on substance identification by their functional groups and hazardousness. The relative content of gaseous products produced during the thermal degradation was evaluated between the two samples, differenced by their assigned isocyanate (NCO) index value—150 and 300. The main thermal degradation components of the rigid PU-PIR foam were found to originate from the decomposition of isocyanate, primarily for…