Search results for "conduct"
showing 10 items of 4412 documents
Interligand Electron Transfer Determines Triplet Excited State Electron Injection in RuN3−Sensitized TiO2 Films
2004
Electron injection from the transition metal complex Ru(dcbpy)(2)(NCS)(2) (dcbpy = 2,2'-bipyridine-4,4'-dicarboxylate) into a titanium dioxide nanoparticle film occurs along two pathways. The dominating part of the electron injection proceeds from the initially excited singlet state of the sensitizer into the conduction band of the semiconductor on the sub-hundred-femtosecond time scale. The slower part of the injection occurs from the thermalized triplet excited state on the picosecond time scale in a nonexponential fashion, as was shown in a previous study (Benko, G.; et al. J. Am. Chem. Soc. 2002, 124, 489). Here we show that the slower channel of injection is the result of the excited s…
Physically-consistent parameterization in the modeling of solar photovoltaic devices
2011
This research tests the standard one-diode model of a crystalline-Si photovoltaic cell, focusing on the physical accuracy. In particular, the (apparent) shunt resistance and the diode ideality factor are studied. Current-voltage characteristics of illuminated crystalline-Si photovoltaic modules are analyzed, and some limits of applicability of the standard model are given. Typical values of the ideality factor for crystalline-Si devices are derived from own experimental data as well as from recently published literature. It is shown that the contribution of the apparent shunt resistance is only significant for cell voltages below about 0.45 V, and depends on irradiance. This result is consi…
High-Efficiency Multi-Junction Photovoltaic Cells in School Physics Laboratory
2020
Energy consumption in the world is increasing more and more due to the huge energy request coming from emerging countries such as China, India, etc. To face the challenge of sustainability, a solution may be the use of solar energy, since it is the most abundant renewable energy source on Earth. The electromagnetic energy coming from the Sun can be converted into usable energy (electricity) by solar cells, whose conversion efficiency is continuously increasing due to scientific and technological progress. The proposed activity is thought to be carried out with secondary as well as high school students to allow teachers to discuss sustainability issues, and to provide students with an introd…
Key drivers of consumer loyalty to Facebook fan pages
2014
Purpose – With the rapid expansion of social networking sites, researchers and practitioners are challenged to understand drivers of customer loyalty in fan pages. The purpose of this paper is to identify the main drivers of Facebook fan page loyalty in order to promote the creation of affective links and long-term relationships with users. Design/methodology/approach – The impact of trust, fan page content dependency, attitude and consumer beliefs on loyalty to fan pages was tested through structural equation modelling techniques. The sample consisted of 691 Spanish Facebook users. Findings – Data analysis shows that attitude appears as a key variable in increasing loyalty to fan pages. T…
Artificial dielectric optical structures: A challenge for nanofabrication
1998
Diffractive optical components can be made using multiple level kinoforms or single level artificial dielectric structures. The latter require the fabrication of pillars of equal depth but differing width and spacing. As a demonstration device, the diffractive optic equivalent of a wedge has been made in GaAs for use at 1.15 μm. The need for all pillars to have the same height was met by using a selective etch and a very thin etch-stop layer on AlGaAs. The experimental diffraction efficiency was 87.8%, among the best ever obtained and close to the theoretical maximum of 97.6%. © 1998 American Vacuum Society.
Scalable Electro-Optic Control of Localized Bistable Switching in Broad-Area VCSELs Using Reconfigurable Funnel Waveguides
2017
We demonstrate a steplike optical modulation based on the activation and deactivation of a bistable localized structure using a photoinduced and reconfigurable miniaturized 30 × 30 μm electroactivated funnel waveguide. Control of a single 10-μm-diameter spot in a 200-μm-diameter vertical-cavity surfaceemitting laser at 980 nm is achieved modulating the phase of an exciting beam in the specific position of the spot in the cavity. This localized on-off response can be scaled into arrays and offer a possible route to fast integrated optical logical functions and memory at low intensities at near-infrared wavelengths.
Simulation of parasitic effects on Silicon Carbide devices for automotive electric traction
2020
Wide Band Gap (WBG) semiconductors are increasingly addressed towards Electric Vehicle (EV) applications, due to their significant advantages in terms of high-voltage and low-losses performances, suitable for high power applications. Nevertheless, the packaging in WBG devices represents a challenge for designers due to the notable impact that inductive and capacitive parasitic components can bring in high switching frequency regime in terms of noise and power losses. In this paper, a comparison between conventional Silicon (Si) and emerging Silicon-Carbide (SiC) power switching devices is presented. The effects of inductive parasitic effects and switching frequency are investigated in simul…
The impact of the age of vines on soil hydraulic conductivity in vineyards in eastern Spain
2017
Soil infiltration processes manage runoff generation, which in turn affects soil erosion. There is limited information on infiltration rates. In this study, the impact of vine age on soil bulk density (BD) and hydraulic conductivity (Ks) was assessed on a loam soil tilled by chisel plough. Soil sampling was conducted in the inter row area of six vineyards, which differed by the age from planting: 0 (Age 0; just planted), 1, 3, 6, 13, and 25 years (Age 1, Age 3, Age 6, Age 13, and Age 25, respectively). The One Ponding Depth (OPD) approach was applied to ring infiltration data to estimate soil Ks with an α* parameter equal to 0.012 mm-1. Soil bulk density for Age 0 was about 1.5 times greate…
Externalizing Behaviors and Cigarette Smoking as Predictors for Use of Illicit Drugs: A Longitudinal Study Among Finnish Adolescent Twins
2010
We examined whether externalizing problem behaviors (hyperactivity–impulsivity, aggressiveness, and inattention) predict illicit drug use independently, or whether their associations with drug use are mediated through cigarette smoking. We used a prospective longitudinal design within theFinnTwin12-17study among Finnish adolescents with baseline at age 12 and follow-up surveys at ages 14 and 17. Path models were conducted withMplusand included 1992 boys and 2123 girls. The outcome was self-reported ever use of cannabis or other illicit drugs at age 17. The predictors were: externalizing behaviors (hyperactivity–impulsivity, aggressiveness, and inattention) assessed by teachers and parents (…
Efficient Monolithic Perovskite/Perovskite Tandem Solar Cells
2016
Thin-film solar cells suffer from various types of recombination, of which leakage current usually dominates at lower voltages. Herein, we demonstrate first a three-order reduction of the shunt loss mechanism in planar methylammonium lead iodide perovskite solar cells by replacing the commonly used hole transport layer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) with a better hole-selective polyarylamine. As a result, these cells exhibit superior operation under reduced light conditions, which we demonstrate for the extreme case of moonlight irradiance, at which open-circuit voltages of 530 mV can still be obtained. By the shunt removal we also observe the VOC to dro…