Search results for "conductivity"
showing 10 items of 1988 documents
Effect of Isovalent Substitution on the Thermoelectric Properties of the Cu2ZnGeSe4–xSx Series of Solid Solutions
2013
Knowledge of structure–property relationships is a key feature of materials design. The control of thermal transport has proven to be crucial for the optimization of thermoelectric materials. We report the synthesis, chemical characterization, thermoelectric transport properties, and thermal transport calculations of the complete solid solution series Cu_2ZnGeSe_(4–x)S_x (x = 0–4). Throughout the substitution series a continuous Vegard-like behavior of the lattice parameters, bond distances, optical band gap energies, and sound velocities are found, which enables the tuning of these properties adjusting the initial composition. Refinements of the special chalcogen positions revealed a chang…
POSS-tetraalkylammonium salts: A new class of ionic liquids
2012
A series of new polyhedral oligomeric silsesquioxane ionic liquids (POSS-ILs) based on the trimethylpropylammonium dielectric constants, which, conversely, display slight differences originating from the nature of the anions. The long alkyl-chain substituents on the POSS core infer on this series of ILs an overall hydrophobic character and solution properties comparable to those of classic cationic surfactants, resulting in an effective extractant capability of polyanions from aqueous solutions. Their solution diffusion properties, as investigated by room-temperature dynamic light scattering, solution conductivity, density, and osmometric measurements, do not provide evidence for the occurr…
Nafion® and polyaniline composite modification with Li and Mg ions
2019
Funding from European Union`s Horizon 2020 Research and Innovation Program project under grant agreement No 768789 is greatly acknowledged.
Proton Conducting Electrospun Sulfonated Polyether Ether Ketone-Graphene Oxide Composite Membranes
2017
[EN] A series of novel composite membranes, based on sulfonated poly(ether ketone) (SPEEK) with a graphene oxide (GO) layer, were prepared. One contained a GO layer sandwiched between the SPEEK-polyvinyl alcohol (PVA) matrix (SPEEK/PVA@GO), and another deposited thin layers of GO on the nanofibers of SPEEK-polyvinyl butyral (PVB), with both sandwiched in the phase matrix of SPEEK-PVA (SPEEK/PVA@GO-NF). Various nanofiber thicknesses were studied by varying the electrospinning time. The prepared composite membranes with different nanofiber thicknesses were characterized by scanning electron microscopy, water uptake, ionic exchange capacity, thermogravimetric analysis, mechanical properties an…
Ionic Liquids-Cobalt (II) Thermochromic Complexes: How the Structure Tunability Affects "Self-contained" Systems
2021
With the aim of obtaining thermochromic systems with potential applications in solar energy storage, we evaluated the behavior of some sugar-based ionic liquids (ILs)–Co(NTf₂)₂ complexes, in IL solution, as a function of temperature. Different structural changes on the cation, the nature of the anion, and the nature of the IL used as the solvent were considered. The analysis of the above factors was carried out through a combined approach of different techniques, that is, variable temperature UV–vis and NMR spectroscopies, conductivity, and thermal gravimetric analysis. The thermochromic systems were analyzed both as solutions and as thin films, and the data collected highlight the defining…
Synthesis and characterisation of a ternary composite of polyaniline, reduced graphene-oxide and chitosan with reduced optical band gap and stable aq…
2019
A ternary composite comprising of p-toluene sulfonic acid doped polyaniline (PANI), chitosan and reduced graphene oxide (RGO) with stable aqueous dispersibility has been synthesised via oxidative polymerisation of aniline in chitosan/RGO dispersion. For comparison; PANI, PANI/chitosan and PANI/RGO composites were also synthesised using the same procedure. FTIR, Raman, XPS, XRD and UV-VIS confirmed the successful synthesis of the PANI and the composites. The aqueous dispersions of the PANI/chitosan and the ternary composites were found to be stable even after more than four months. The stability of the dispersion was attributed to the polycationic nature of the chitosan. The thermogravimetri…
Thermal and hygrometric properties of traditional calcarenite stones in the area of Palermo
2017
Il contributo espone le misure di conducibilità termica svolte su tre conci di calcarenite conchiliare e la caratterizzazione igrometrica di uno di essi. I risultati sono confrontati con i dati termici e igrometrici riportati dalle norme tecniche esistenti (UNI 10351, UNI EN ISO 10456, UNI EN 1745). The energy improvement of historic buildings requires detailed knowledge of the thermal and hygrometric properties of traditional materials and components. These data should be collected for specific local contexts, where the features of historic constructions are comparable. For the purpose of developing this tool for the architectural heritage of Palermo, this research focuses on calcarenite s…
Estimating hydraulic conductivity of a crusted loamy soil from beerkan experiments in a Mediterranean vineyard
2017
In bare soils of semi-arid areas, surface crusting is a rather common phenomenon due to the impact of raindrops. Water infiltration measurements under ponding conditions constitute a common way for an approximate characterization of crusted soils. In this study, the impact of crusting on soil hydraulic conductivity was assessed in a Mediterranean vineyard (western Sicily, Italy) under conventional tillage. The BEST (Beerkan Estimation of Soil Transfer parameters) algorithm was applied to the infiltration data to obtain the hydraulic conductivity of crusted and uncrusted soils. Soil hydraulic conductivity was found to vary during the year and also spatially (i.e., rows vs. inter-rows) due to…
Conceptual Design and Modeling of Fast Discharge Unit for Quench Protection of Superconducting Toroidal Field Magnets of DTT
2020
The paper deals with the modelling and simulation of a Fast Discharge Unit (FDU) for quench protection of the Toroidal Field (TF) magnets of the Divertor Tokamak Test, an experimental facility under design and construction in Frascati (Italy). The FDU is a safety key component that protects the superconducting magnets when a quench is detected through the fast extraction of the energy stored in superconducting magnets by adding in the TF magnets a dump (or discharge) resistor. In the paper, two different configurations of dump resistors (fixed and variable respectively) have been analysed and discussed. As a first result, it is possible to underline that the configuration with variable dump…
Evolution of topological superconductivity by orbital-selective confinement in oxide nanowires
2019
We determine the optimal conditions to achieve topological superconducting phases having spin-singlet pairing for a planar nanowire with finite lateral width in the presence of an in-plane external magnetic field. We employ a microscopic description that is based on a three-band electronic model including both the atomic spin-orbit coupling and the inversion asymmetric potential at the interface between oxide band-gap insulators. We consider amplitudes of the pairing gap, spin-orbit interactions and electronic parameters that are directly applicable to nanowires of LaAlO$_3$-SrTiO$_3$. The lateral confinement introduces a splitting of the $d$-orbitals that alters the orbital energy hierarch…