Search results for "confinement."

showing 10 items of 183 documents

Physicochemical investigation of cobalt?iron cyanide nanoparticles synthesized by a novel solid?solid reaction in confined space

2004

Cobalt–iron cyanide (Cox[Fe(CN)6]) nanoparticles have been synthesized by a novel solid–solid reaction in the confined space of dry sodium bis(2-ethylhexyl)sulfosuccinate (AOT) reversed micelles dispersed in n-heptane. The reaction has been carried out by mixing two dry AOT/n-heptane solutions containing CoCl2 and K4Fe(CN)6 or K3Fe(CN)6 nanoparticles in the micellar core, respectively. By UV-Vis spectroscopy it was ascertained that, after the mixing process, the formation of stable nanoparticles is fast and complete. Microcalorimetric measurements of the thermal effect due to the Cox[Fe(CN)6] nanoparticle formation allowed the determination of the stoichiometric ratio (x) and of the molar e…

Polymers and PlasticsSmall-angle X-ray scatteringCyanidechemistry.chemical_elementNanoparticleMicellechemistry.chemical_compoundColloid and Surface ChemistryAdsorptionCobalt–iron cyanide complexes Nanoparticles Solid–solid reaction Confinement effect AOT reversed micelleschemistryX-ray photoelectron spectroscopyMaterials ChemistryPhysical chemistryOrganic chemistryPhysical and Theoretical ChemistryCobaltStoichiometrySettore CHIM/02 - Chimica FisicaColloid and Polymer Science
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Size dependent light absorption modulation and enhanced carrier transport in germanium quantum dots devices

2015

Quantum confinement in closely packed arrays of Ge quantum dots (QDs) was studied for energy applications. In this work, we report an efficient tuning mechanism of the light harvesting and detection of Ge QDs. Thin films of SiGeO alloys, produced by rf-magnetron sputtering, were annealed at 600 degrees C in N-2 to induce precipitation of small amorphous Ge QDs into the oxide matrix. Varying the Ge content, the QD size was tailored between 2 and 4 nm, as measured by high resolution transmission electron microscopy. X-ray photoelectron spectroscopy (XPS) measurements indicate the formation of pure SiO2, as well as the presence of a sub-stoichiometric Ge oxide shell at the QD interface. Light …

Precipitation (chemical)Materials scienceAmorphous alloyBand gapchemistry.chemical_elementHigh resolution transmission electron microscopyPhotoconductive gainGermaniumNanocrystalMetal-insulator semiconductor deviceSettore ING-INF/01 - ElettronicaSettore FIS/03 - Fisica Della MateriaAbsorption spectroscopyQuantum confinement effectQuantum confinementElectromagnetic wave absorptionLight absorptionThin filmGermanium oxideOxide filmHigh-resolution transmission electron microscopyGermanium quantum dotPotential wellMIS deviceAmorphous filmGermaniumQuantum dotsRenewable Energy Sustainability and the Environmentbusiness.industryPhotoconductivitySolar cellPreferential trappingMIM deviceSemiconductor deviceSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsPhotovoltaicschemistryMetal insulator boundarieQuantum dotrf-Magnetron sputtering Semiconductor quantum dotOptoelectronicsCharge carrierX ray photoelectron spectroscopy Effective mass approximationbusinessQuantum chemistryPhotovoltaicMagnetron sputteringSolar Energy Materials and Solar Cells
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Protein Thermal Denaturation and Matrix Glass Transition in Different Protein−Trehalose−Water Systems

2011

Biopreservation by saccharides is a widely studied issue due to its scientific and technological importance; in particular, ternary amorphous protein-saccharide-water systems are extensively exploited to model the characteristics of the in vivo biopreservation process. We present here a differential scanning calorimetry (DSC) study on amorphous trehalose-water systems with embedded different proteins (myoglobin, lysozyme, BSA, hemoglobin), which differ for charge, surface, and volume properties. In our study, the protein/trehalose molar ratio is kept constant at 1/40, while the water/sugar molar ratio is varied between 2 and 300; results are compared with those obtained for binary trehalose…

Protein DenaturationdenaturationMolecular Dynamics SimulationPhase TransitionDSCMatrix (chemical analysis)Hemoglobinschemistry.chemical_compoundDifferential scanning calorimetryMaterials ChemistryAnimalsglass transitionPhysical and Theoretical ChemistrytrehaloseSettore CHIM/02 - Chimica FisicaChromatographyCalorimetry Differential ScanningMyoglobinTemperatureProteinsWaterSerum Albumin BovineTrehaloseSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)Surfaces Coatings and FilmsAmorphous solidchemistryChemical engineeringMyoglobinconfinementCattleMuramidaseLysozymeTernary operationGlass transitionThe Journal of Physical Chemistry B
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Book Review: Spirituality in Dark Places: The Ethics of Solitary Confinement

2015

PsychoanalysisSociology and Political ScienceSolitary confinementSpiritualitySociologyCriminologyThe Sociological Review
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On the Delta-nucleon and rho-pi splittings: A QCD-inspired look in free hadrons versus nuclei

1997

Relationships between mass intervals for free hadrons and in nuclei are studied in two theoretical approaches inspired by QCD: naive quark model and skyrmion model, taking one example each from mesons and baryons, that of pi-rho splitting in mesons, and nucleon-Delta splitting in baryons. Possible deconfinement effects in nuclei are examined.

Quantum chromodynamicsPhysicsNuclear and High Energy PhysicsParticle physicsNuclear TheoryMesonHigh Energy Physics::LatticeSkyrmionHigh Energy Physics::PhenomenologyNuclear TheoryHadronQuark modelFísicaFOS: Physical sciencesDeconfinementNuclear Theory (nucl-th)BaryonHigh Energy Physics::ExperimentNuclear ExperimentNucleonNuclear Physics A
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Two-flavour lattice QCD correlation functions in the deconfinement transition region

2013

We report on a lattice QCD calculation with two dynamical flavors of the isovector vector correlator in the high-temperature phase. We analyze the correlator in terms of the associated spectral function by performing a fit for the difference of the thermal and vacuum spectral functions, using also an exact sum rule that constrains this difference. Additonally we carry out a direct fit for the thermal spectral function, and obtain good agreement between the two analyses for frequencies below the two-pion threshold. Under the assumption that the spectral function is smooth in that region, we give an estimate of the electrical conductivity.

Quantum chromodynamicsPhysicsSpectral representationNuclear TheoryCondensed matter physicsHigh Energy Physics::LatticeLattice field theoryFlavourHigh Energy Physics - Lattice (hep-lat)FOS: Physical sciencesLattice QCDDeconfinementNuclear Theory (nucl-th)High Energy Physics - PhenomenologyHigh Energy Physics - LatticeHigh Energy Physics - Phenomenology (hep-ph)Lattice (order)Color confinement
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Effective Lagrangians for QCD: Deconfinement and Chiral Symmetry Restoration

2004

Effective Lagrangians for Quantum Chromodynamics (QCD) especially suited for understanding deconfinement and chiral symmetry restoration at nonzero temperature and matter density are reviewed. These effective theories allow one to study generic properties of phase transitions using non-order parameter fields without loosing the information encoded in the true order parameter. {}For the pure gauge theory we demonstrate that, near the deconfining phase transition, the center group symmetry is naturally linked to the conformal anomaly. Another relevant outcome is that when the theory contains also quarks we can explain the intertwining of chiral symmetry restoration and deconfinement for QCD w…

Quantum chromodynamicsQuarkPhysicsHigh Energy Physics - TheoryNuclear TheoryConformal anomalyHigh Energy Physics::LatticeHigh Energy Physics - Lattice (hep-lat)High Energy Physics::PhenomenologyAdjoint representationFOS: Physical sciencesDeconfinementNuclear Theory (nucl-th)BaryonTheoretical physicsHigh Energy Physics - PhenomenologyHigh Energy Physics - Phenomenology (hep-ph)High Energy Physics - LatticeHigh Energy Physics - Theory (hep-th)Gauge groupGauge theory
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Towards the N_f=2 deconfinement transition temperature with O(a) improved Wilson fermions: An update

2010

We give an update on our current project to determine the transition temperature and the order of the deconfinement transition in the chiral limit of two flavour QCD. We use nonperturbatively O(a) improved Wilson fermions of the Sheikholeslami-Wohlert type, employing the efficient deflation accelerated DDHMC algorithm. We start at lattices with N_t>=12 and pion masses below 600 MeV, aiming at chiral and continuum limits with light quarks.

Quantum chromodynamicsQuarkPhysicsParticle physicsTransition temperatureHigh Energy Physics::LatticeFlavourHigh Energy Physics - Lattice (hep-lat)High Energy Physics::PhenomenologyFOS: Physical sciencesFermionDeconfinementPionHigh Energy Physics - LatticeHigh Energy Physics::Experiment
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The neutrinoless double beta decay of 76Ge, 82Se, 86Kr, 114Cd, 128, 130Te and 134, 136Xe in the framework of a relativistic quark confinement model

1991

The half-life of the 0+ → 0+ neutrinoless double beta decay is calculated for 76Ge, 82Se, 86Kr, 114Cd, 128, 130Te and 134, 136Xe and the upper limit for the effective neutrino mass of 3.0 eV is deduced from available experimental data. In addition, the contribution of the right-handed charged weak currents to the effective weak hamiltonian is estimated. The relevant parameters attain the values |〈Λ〉| < 4.1 × 10−6 and |〈ν〉| < 6.6 × 10−8. The nucleonic weak current is treated starting from the current quark level and evaluating the quark current using relativistic quark wave functions obtained from a Dirac equation with a harmonic confinement potential. The nuclear matrix elements of the thus…

QuarkPhysicsNuclear and High Energy PhysicsParticle physicsCurrent quarkNuclear physicssymbols.namesakeDirac equationDouble beta decaysymbolsHigh Energy Physics::ExperimentColor confinementNeutrinoWave functionRandom phase approximationNuclear Physics A
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Spherical multiquark states in the chiral bag model

1984

Abstract We study n-quark systems (n = 3, 6, 12) in the chiral bag model. In order to handle the non-linearities of the model, the hedgehog ansatz for the Goldstone pion field is used. It is found that due to “warping” of the quark orbits in the presence of mean-field pion clouds, a strong repulsion is developed when more than three quarks are put in a bag. This repulsion mechanism turns out to be close to the soliton mechanism discovered by Skyrme two decades ago. Even the magnitude of the repulsion agrees with his. It is also possible to relate the repulsion to the effective quenching of the axial charge of the multiquark system and a suggestion is made that the recently observed quenchin…

QuarkPhysicsNuclear and High Energy PhysicsParticle physicsHigh Energy Physics::LatticeHigh Energy Physics::PhenomenologyNuclear TheoryCharge (physics)Nuclear matterBaryonPionSolitonColor confinementAnsatzNuclear Physics A
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