Search results for "confinement."
showing 10 items of 183 documents
Theoretical principles of near-field optical microscopies and spectroscopies
2000
International audience; This paper deals with the principles of detection of optical signals near a surface in a manner permitting the mapping of the distribution of the fields close to various kinds of illuminated samples. We begin with a discussion of the main physical properties of the optical fields near a surface in the absence of any probe tip. This mainly concerns phenomena involving evanescent waves for which the local decay lengths are governed not only by the sizes but also by the intrinsic properties of the surface structures. The interpretation of the detection process is reviewed on the basis of a discussion about the possibility of establishing direct comparisons between exper…
Progress in the interpretation of near-field optics
1998
International audience
Local detection of the optical magnetic field in the near zone of dielectric samples
2000
International audience; We present a study of the influence of the probe composition on the formation of constant-height photon scanning tunneling microscope images when observing a dielectric sample. Dramatic effects due to the metallization of the tip are presented and discussed in detail. We show how the recorded images can look quite different when the probe is dielectric or coated with gold. Comparison with numerical calculations indicate that the experimental signals are of electric or magnetic nature depending on the composition of the tip. For well-defined conditions, gold-coated tips provide images of the distribution of the magnetic field intensity associated with the optical near…
Manger confiné : quel impact sur nos habitudes alimentaires ?
2020
Il y a peu de temps, la population française vivait une période inédite : neuf semaines confinées à la maison. Des chercheurs du CSGA se sont intéressées à l'impact du confinement sur les habitudes alimentaires en déployant une vaste enquête auprès de 500 parents d'enfants de 3-11 ans.
Strengthening of Masonry Columns with BFRCM or with Steel Wires: An Experimental Study
2016
Nowadays, innovative materials are more frequently adopted for strengthening historical constructions and masonry structures. The target of these techniques is to improve the structural efficiency with retrofitting methods while having a reduced aesthetical impact. In particular, the use of basalt fiber together with a cementitious matrix emerges as a new technique. This kind of fiber is obtained by basalt rock without other components, and consequently it could be considered a natural material, compatible with masonry. Another innovative technique for strengthening masonry columns consists of applying steel wires in the correspondence of mortar joints. Both techniques have been recently pr…
FT-IR investigation of the state of iron (III) chloride clusters confined in AOT reverse micelles dispersed in carbon tetrachloride
2007
The state of the water-soluble salt iron(III) chloride in AOT reverse micelles dispersed in carbon tetrachloride has been investigated by FT-IR spectroscopy. Interestingly, while the entrapment of a lot of water-soluble inorganic salts in AOT reverse micelles requires preliminarily the presence of significant amounts of water within the micellar core, solubilization of FeCl3 occurs without the need to add water in the micellar solution reaching the very high solubility value, expressed as the maximum salt-to-surfactant molar ratio, of 1.30. The analysis of the spectral features of the investigated samples leads to hypothesize that iron(III) chloride is confined within the reverse micellar c…
Chiroptical Phenomena in Reverse Micelles: The Case of (1R,2S)- Dodecyl (2-hydroxy-1-methyl-2-phenylethyl)dimethylammonium Bromide (DMEB)
2014
(1R,2S)-Dodecyl(2-hydroxy-1-methyl-2-phenylethyl)dimethylammonium bromide (DMEB) aggregates dispersed in carbon tetrachloride have been investigated by Fourier transform infrared (FT-IR), vibrational circular dichroism (VCD) and 1H nuclear magnetic resonance (NMR) spectroscopy at various surfactant concentration and water-to-surfactant molar ratio. Experimental data indicate that, even at the lowest investigated concentration and in absence of added water, DMEBmolecules associate in supramolecular assemblies. At higherDMEBconcentration the aggregates can confine watermolecules,making it plausible to think thatDMEB form reverse micelles and that watermolecules are quite uniformly distributed…
1H-NMR and FT-IR study of the state of melatonin confined in membrane models: location and interactions of melatonin in water free lecithin and AOT r…
2004
The state of melatonin confined either in dry lecithin or bis(2-ethylhexyl) sulfosuccinate sodium salt (AOT) reversed micelles has been investigated by H-1-NMR and FT-IR spectroscopies as a function of the melatonin to surfactant molar ratio (R). The analysis of experimental results leads to hypothesize that, independently of R and the surfactant nature and as a consequence of anisotropic melatonin/surfactant interactions, melatonin is totally solubilized in reversed micelles and mainly located by opportune orientation in the nanodomain constituted by the surfactant head groups. The absence of significant spectral changes related to the protons linked to the first carbon atoms of surfactant…
Confinement of L and D dimethyl tartrate in reverse micelles: an FT-IR and VCD study
2008
Research on happiness and affect during Covid-19 confinement [Dataset]
2020
Two databases: Research on happiness and affect during Covid-19 confinement