Search results for "confinement."
showing 10 items of 183 documents
Nanoconfined mixed Li and Mg borohydrides as materials for solid state hydrogen storage
2012
Abstract Several mixtures of LiBH4 and Mg(BH4)2 borohydrides in different stoichiometric ratios (1:0, 2:1, 1:1, 1:2, 0:1), prepared by high energy ball milling, have been investigated with X-ray powder diffraction and thermal programmed desorption (TPD) volumetric analysis to test the dehydrogenation kinetics in correlation with the physical mixture composition. Afterwards mixed and unmixed borohydrides were dispersed on high specific surface area ball milled graphite by means of the solvent infiltration technique. BET and statistical thickness methods were used to characterize the support surface properties, and SEM micrographs gave a better understanding of the preparation techniques. It …
Analysis-oriented stress–strain model of CRFP-confined circular concrete columns with applied preload
2018
The compressive behavior of FRP-confined concrete is a current issue in the field of structural retrofitting. The available models well predict the stress–strain behavior under monotonic and cyclic loads. However, in the practical applications, columns that need an increasing of bearing capacity are often strengthened under serviceability load conditions, with a stress and strain state that could change the response of the reinforced systems with respect to the case of the unloaded state. In this paper, the compressive behavior of circular FRP-confined concrete columns with preload is analyzed with the introduction of a modified analysis-oriented model. Differently from the classical formul…
Effect of corner over-reinforcing strips on the compressive behaviour of TRM confined masonry columns
2020
Several recent works studied the efficiency of inorganic matrix composites, namely Textile Reinforced Mortar (TRM) or Fabric Reinforced Cementitious Matrix, for enhancing the strength and shortening capacity of masonry columns subjected to axial load. Literature studies were addressed to study the great number of variables involved in the problem, such as the nature and the grade of mortar, the strength of the fabric, the number of reinforcing layers, the type, the arrangement and the strength of the masonry, and helped to draw the first technical guidelines for practitioners and designers. All the experimental works highlighted that the actual performance of TRM confinement in masonry memb…
Compressive behaviour of eccentrically loaded slender masonry columns confined by FRP
2018
Abstract Fibre Reinforced Polymer (FRP) confinement represents an effective tool for retrofitting masonry piers or columns enhancing their structural performance. This technique has been widely studied in the literature mainly with reference to short columns, while no extensive information is available on the influence of second order effects on its efficacy in case of slender members. Within this framework, the presented study concerns a simplified method able to assess the effects of FRP confinement on the compressive behaviour of slender masonry columns. A proper constitutive law of FRP confined masonry in compression is adopted for performing a sectional analysis, in which also consider…
Compressive behavior of short fibrous reinforced concrete members with square cross-section
2011
In the present paper a mechanical model to predict the compressive response of high strength short concrete columns with square cross-section confined by transverse steel is presented. The model allows one to estimate the equivalent confinement pressures exercised by transverse steel during the loading process taking into account of the interaction of the stirrups with the inner core both in the plane of the stirrups and in the space between two successive stirrups. The lateral pressure distributions at hoop levels are obtained by using a simple model of elastic beam on elastic medium simulating the interaction between stirrups and concrete core, including yielding of steel stirrups and dam…
Strength and ductility of R.C. columns strengthened with steel angles and battens
2012
Abstract In this paper the behaviour of R.C. members externally strengthened with steel angles and battens subjected to axial force and bending moment is analysed. A fibre model was utilised to predict the moment–curvature diagrams of the strengthened members on the basis of stress–strain curves of the constituent materials (confined concrete, steel bars and angles) recently derived by the author. The stress–strain curves utilised for compressed concrete were able to take into account the confinement effects induced by longitudinal (bars and steel angles) and transverse (stirrups and battens) steel reinforcements. Constitutive laws in compression for confined concrete and steel bars and ang…
Flexural behaviour of concrete corbels containing steel fibers or wrapped with FRP sheets
2005
In the present paper an analytical and experimental investigation referring to the flexural behaviour of reinforced concrete corbels subjected to vertical forces is presented. For fixed shape and dimensions of the corbels the experimental investigation analyses the effects of the following: longitudinal and transverse steel reinforcements; fiber reinforced concrete (FRC) with hooked steel fibers; external wrapping retrofitting technique with a thin layer of carbon fiber sheet (CFRP). The analytical model based on equivalent truss structures, allows one to determine the bearing capacity of corbels, distinguishing the different ultimate states reached. The analytical results are then compared…
Numerical Modeling Approaches of FRCMs/SRG Confined Masonry Columns
2019
The Fabric Reinforced Cementitious Matrices (FRCMs) and Steel Reinforced Grout (SRG) are a promising strengthening solution for existing masonry since inorganic matrix is considerably compatible with historical substrates. The present paper is focused on a Finite Element (FE) analysis of masonry columns confined with FRCM composites developed by Abaqus-code. The masonry columns were modelled using a macro model approach. The model was performed by using the following functions Concrete Damage Plasticity (CDP) and the Plastic (P) in order to describe the constitutive laws of material for masonry columns and external reinforcement, respectively. Typical failures of FRCM-systems are slippage o…
Confinement inside a Crystalline Sponge Induces Pyrrole To Form N−H⋅⋅⋅π Bonded Tetramers
2021
Based on the DFT‐level calculated molecular volume (V mol ) of pyrrole and its liquid density, pyrrole manifests the highest liquid density coefficient LD c (defined as [V mol • density • 0.6023]/FW) value of 0.7. Normal liquids have LD c < 0.63. This very high LD c is due to the strong N‐H … π interactions in solution and hence pyrrole can be considered to be a pseudo‐crystalline liquid. When trapped inside the confined space of the crystalline sponge a reorientation of the N‐H … π interaction is observed leading to specific cyclic N‐H … π tetramers and N‐H … π dimers, verified by single crystal X‐ray crystallographic and computational methods. These tetramers are of the same size as four …
Autonomous molecularly crowded confinement in inkjet printed femtoliter-scale aqueous compartments
2019
Natural evolution has chosen the localization of biomolecular processes into crowded sub-cellular femtoliter (fL) scale compartments for organizing complex biological processes. [1] Many synthetic biology platforms with life-like activities have been able to mimic these systems under different compartment sizes regimes. [2] However, the fabrication of crowded compartments down to sub-cellular scales is challenging, mainly because of high surface-volume ratio of these systems, finally compromising the stability of the encapsulated biomolecules. In this regard, we here bridge this gap by showing the possibility to produce femtoliter-scale aqueous droplets using a novel inkjet printing approac…