Search results for "conica"

Una localidad nueva para Orchis champagneuxii y Orchis conica en el norte de Alicante

2006

Se da a conocer una nueva localidad en la que conviven dos orquídeas muy raras en el ámbito de la provincia de Alicante, y que resultan también escasas en la Comunidad Valenciana: Orchis champagneuxii Barnéoud [≡ O. morio subsp. champagneuxii (Barnéoud) E.G. Camus] y O. conica Willd. [− O. lactea auct.]. En ambos casos sólo se tiene referencias previas de su presencia en escasas localidades de las comarcas del norte de Alicante, a menudo en áreas próximas a la provincia de Valencia. Para ambas se aportan datos sobre su ecología y estado de conservación, y asimismo se propone la creación de una microrreserva de flora que asegure su continuidad en las comarcas alicantinas. A new site is repor…

Conical connection adjustment in prosthetic abutments obtained by different techniques

2019

Background The goal of this study is to compare the misfit (>150µm) generated once the restoration, made by different techniques, is retained to a single conical implant. Material and methods 15 internal connection implants (MIS C1 4'20x10mm) are embedded each one perpendicularly to an horizontal surface of the 1x1x2cm poliuretan resin model. The 15 samples obtained are divided in 5 groups depending on the framework process (n=3): 1/casting, 2/overcasting, 3/Ti-base, 4/milling and 5/laser sintering. The cobalt-chromium alloy frameworks are screw-retained to their respective implants to a 30-Ncm torque. Once it is retained the framework to the implant, the next step is to section the sample …

Toward an Understanding of Ultrafast Electron Transfer in Photosynthesis

2008

The mechanism of electron transfer (ET) from reduced pheophytin (Pheo−) to the primary stable photosynthetic acceptor, a quinone (Q) molecule, is addressed by using high-level ab initio computations and realistic molecular models. The results reveal that the ET process involving the (Pheo−+Q) and (Pheo+Q−) oxidation states can be seen essentially as an ultrafast radiationless transition between the two hypersurfaces taking place via conical intersections (CIs) and is favoured when the topology of the interacting moieties makes possible some overlap between the lowest occupied molecular orbitals (LUMO) of the two systems. Thus, it is anticipated that large scale motions, which are difficult …

2014

There have been a number of recent experimental investigations of the nonadiabatic relaxation dynamics of aniline following excitation to the first three singlet excited states, 1(1)ππ*, 1(1)π3s/πσ* and 2(1)ππ*. Motivated by differences between the interpretations of experimental observations, we have employed CASSCF and XMCQDPT2 calculations to explore the potential energy landscape and relaxation pathways of photoexcited aniline. We find a new prefulvene-like MECI connecting the 1(1)ππ* state with the GS in which the carbon-atom carrying the amino group is distorted out-of-plane. This suggests that excitation above the 1(1)π3s/πσ* vertical excitation energy could be followed by electronic…

Core-shifts and proper-motion constraints in the S5 polar cap sample at the 15 and 43 GHz bands

2018

We have studied a complete radio sample of active galactic nuclei with the very-long-baseline-interferometry (VLBI) technique and for the first time successfully obtained high-precision phase-delay astrometry atQband (43 GHz) from observations acquired in 2010. We have compared our astrometric results with those obtained with the same technique atUband (15 GHz) from data collected in 2000. The differences in source separations among all the source pairs observed in common at the two epochs are compatible at the 1σlevel betweenUandQbands. With the benefit of quasi-simultaneousUandQband observations in 2010, we have studied chromatic effects (core-shift) at the radio source cores with three d…

Jet stability and the generation of superluminal and stationary components

2001

We present a numerical simulation of the response of an expanding relativistic jet to the ejection of a superluminal component. The simulation has been performed with a relativistic time-dependent hydrodynamical code from which simulated radio maps are computed by integrating the transfer equations for synchrotron radiation. The interaction of the superluminal component with the underlying jet results in the formation of multiple conical shocks behind the main perturbation. These trailing components can be easily distinguished because they appear to be released from the primary superluminal component, instead of being ejected from the core. Their oblique nature should also result in distinc…

Can coupled-cluster theory treat conical intersections?

2007

Conical intersections between electronic states are of great importance for the understanding of radiationless ultrafast relaxation processes. In particular, accidental degeneracies of hypersurfaces, i.e., between states of the same symmetry, become increasingly relevant for larger molecular systems. Coupled-cluster theory, including both single and multireference based schemes, offers a size-extensive description of the electronic wave function, but it sacrifices the Hermitian character of the theory. In this contribution, we examine the consequences of anti-Hermitian contributions to the coupling matrix element between near-degenerate states such as linear dependent eigenvectors and compl…

Focal squeeze in axicons

2005

The on-axis irradiance distribution of a truncated conical wavefront is evaluated in terms of the Fresnel number of the focusing geometry. In agreement with geometrical optics, a focal line of increasing intensity is generated for extremely high Fresnel numbers. Otherwise clear deviations may be observed for the position of the maximum irradiance along the optical axis. A remarkable focal squeeze appears and, for decreasing Fresnel numbers, this effect manifests stronger. An analytical formula is provided for the fast evaluation of the focal squeeze.

Similar chemical structures, dissimilar triplet quantum yields: a CASPT2 model rationalizing the trend of triplet quantum yields in nitroaromatic sys…

2019

The photophysics of nitroaromatics compounds stand out for being characterized by an ultrafast decay into the triplet manifold and by a significant value of the triplet quantum yield. The latter quantity can change dramatically from one system to another, as proven for the molecules 2- nitronaphthalene, 1-nitronaphthalene, and 2methyl-1nitronaphthale, whose triplet quantum yield have been previously measured to be 0.93 ± 0.15, 0.64 ± 0.12, and 0.33 ± 0.05, respectively (J. Phys. Chem. A 2013, 117, 14100). In the present contribution we rationalize the reported trend for the triplet quantum yield on the basis of the different ability that the excited S 1 state has in the three molecules to r…

(2+1)-dimensional Einstein-Kepler problem in the centre-of-mass frame

1999

We formulate and analyze the Hamiltonian dynamics of a pair of massive spinless point particles in (2+1)-dimensional Einstein gravity by anchoring the system to a conical infinity, isometric to the infinity generated by a single massive but possibly spinning particle. The reduced phase space \Gamma_{red} has dimension four and topology R^3 x S^1. \Gamma_{red} is analogous to the phase space of a Newtonian two-body system in the centre-of-mass frame, and we find on \Gamma_{red} a canonical chart that makes this analogue explicit and reduces to the Newtonian chart in the appropriate limit. Prospects for quantization are commented on.