Search results for "conjugate"
showing 10 items of 644 documents
(1Z,3Z)-3-[Quinolin-2(1H)-ylidene]-1-(quinolin-2-yl)prop-1-en-2-ol: An unexpected most stable tautomer of 1,3-bis(quinolin-2-yl)acetone
2009
Abstract 1 H, 13 C and 15 N NMR spectra reveal that CDCl 3 solution of 1,3-bis(quinolin-2-yl)acetone contains only ( 1Z , 3Z )-3-[quinolin-2(1 H )-ylidene]-1-(quinolin-2-yl)prop-1-en-2-ol. The proton transfer takes place between two basic centers of the molecule, which means that the process is an identity reaction by character. The situation is completely different from that detected in chloroform solution of 1,3-bis(pyridin-2-yl)acetone where three different tautomers are in equilibrium with each other. Although the proton transfers in both ( 1Z , 3Z )-3-[quinolin-2(1 H )-ylidene]-1-(quinolin-2-yl)prop-1-en-2-ol and ( 1Z , 3Z )-3-hydroxy-1-[quinolin-2(1 H )-ylidene-4-quinolin-2-yl]but-3-e…
Evidence in the formation of conjugated linoleic acids from thermally induced 9t12t linoleic acid: a study by gas chromatography and infrared spectro…
2009
Accepted version of article published in the journal: Chemistry and Physics of Lipids. Published version available on Science Direct: http://dx.doi.org/10.1016/j.chemphyslip.2009.07.002 Thermally induced isomerisation leading to the formation of conjugated linoleic acids (CLAs) has been observed for the first time during the thermal treatment of 9t12t fatty acid triacylglycerol, and methyl ester. Fifteen microlitre portions of the triacylglycerol sample containing 9t12t fatty acid (trilinoelaidin) were placed in micro glass ampoules and sealed under nitrogen, then subjected to thermal treatment at 250 degrees C. The glass ampoules were removed at regular time intervals, cut open, and the co…
Gas chromatography-fourier transform infrared spectrometry of fatty acids: New Applications with a direct deposition interface
1998
Infrared spectroscopy is a suitable spectroscopic method to differentiate geometric Z and E isomers of unsaturated compounds. A direct-deposition Fourier transform infrared spectrometer (FTIR), coupled to a gas chromatograph, was used successfully to analyze with a high sensitivity traces of C18:1 fatty acid methyl ester (FAME) isomers. It could also conclusively distinguish between isomers of conjugated diunsaturated FAME. The achievable sensitivity of this direct-deposition device makes possible accurate FAME mixture analyses that are not currently attainable with the more conventional light-pipe interface.
Thermally Induced Isomerisation Kinetics of the 9c11t and 10t12c Conjugated Linoleic Acids in Triacylglycerols as Studied by FT-IR Spectrometry Aided…
2014
Published version of an article from the journal:The Open Spectroscopy Journa. Also available from the publisher:http://dx.doi.org/10.2174/1874383801004010041. Open Access Isomerisation kinetics of the 9c11t and 10t12c Conjugated Linoleic Acids (CLA) in triaclglycerols at isothermal conditions (250, 280 and 325oC) has been studied by infrared spectroscopy. Fifteen micro liter portions of the glycerides were placed in micro glass ampoules and sealed under nitrogen. Several glass tubes containing the same triacylglycerols were then subjected to thermal treatment. The glass tubes were removed at regular time intervals, cut open, and a part of the contents in each glass tube analysed by infrare…
Glutathione Transferase A1-1 Catalyzed Conjugation of Polycyclic Aromatic Hydrocarbon Diol-Epoxides with Glutathione
1996
Abstract The glutathione transferase A1-1 (GSTA1-1) isoenzyme catalyzes the formation of GSH-conjugates of the isomeric bay-region diol-epoxides (DEs) of trans-1,2-dihydroxy-3,4-epoxy-1,2,3,4-tetrahydrochrysene (CDE) and trans-3,4-dihydroxy-1,2-epoxy-1,2,3,4-tetrahydrodibenz[a,h]anthracene (DBADE) as well as the isomeric fjord-region DEs trans-3,4-dihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenzo[c]phenanthrene (BPhDE) and trans-9,10-dihydroxy-11,12-epoxy-9,10,11,12-tetrahydro-benzo[c]chrysene (BCDE) although with an approx. 20-fold variation in catalytic efficiency. With the anti-diastereomers and the syn-diastereomers of BPhDE and BCDE, GSTA1-1 demonstrated a significant preference for the enan…
IDENTIFICATION OF LECTINS IN THE KINETIDS OFTETRAHYMENA PYRIFORMIS
1997
Previously we described lectin-like molecules in the ciliate Tetrahymena pyriformis; by application of synthetic neoglycoconjugates it is now shown that T. pyriformis contains considerable amounts of both a beta-D-glucose- and a lactose-specific lectin. No evidence for the presence of alpha-D-mannose-, alpha-D-galactose- or of alpha-L-fucose-specific lectins could be obtained. The two lectins, identified in T. pyriformis, are associated with the kinetids. During cell division the lectins disappear or become masked in the fission furrow. Therefore, we assume that these lectins are involved in the organization of the distribution pattern of the kinetids during cell division perhaps due to lec…
Centralizers of Parabolic Subgroups of Artin Groups of TypeAl,Bl, andDl
1997
Abstract Let ( A , Σ) be an Artin system of one of the types A l , B l , D l . For X ⊆ Σ, we denote by A X the subgroup of A generated by X . Such a group is called a parabolic subgroup of ( A , Σ). Let A X be a parabolic subgroup with connected associated Coxeter graph. We exhibit a generating set of the centralizer of A X in A . Moreover, we prove that there exists X ′ ⊆ Σ such that A X ′ is conjugate to A X and such that the centralizer of A X ′ in A is generated by the centers of all the parabolic subgroups containing A X ′ .
Zur Hyperebenenalgebraisierung in desargues-Schen projektiven Verbandsgeometrien
1991
As a completion and extension of a result of A. Day and D. Pickering [5] we obtain the following structure theorem in the conceptual frame of projective lattice geometries: In a Desarguesian projective geometry the subgeometry of every at least one-dimensional hyperplane is module induced.
Soluble groups with their centralizer factor groups of bounded rank
2007
Abstract For a group class X , a group G is said to be a C X -group if the factor group G / C G ( g G ) ∈ X for all g ∈ G , where C G ( g G ) is the centralizer in G of the normal closure of g in G . For the class F f of groups of finite order less than or equal to f , a classical result of B.H. Neumann [Groups with finite classes of conjugate elements, Proc. London Math. Soc. 1 (1951) 178–187] states that if G ∈ C F f , the commutator group G ′ belongs to F f ′ for some f ′ depending only on f . We prove that a similar result holds for the class S r ( d ) , the class of soluble groups of derived length at most d which have Prufer rank at most r . Namely, if G ∈ C S r ( d ) , then G ′ ∈ S d…
Shift-and-scale-invariant pattern recognition using an elliptic coordinate-transformed phase-only filter
1992
A shift-and-scale-invariant elliptic coordinate-transformed phase-only filter in proposed. The filter is built in three steps: the complex conjugate of a basic-size target spectrum is calculated, its phase-only part is taken, and then the elliptic coordinate transformation is made. In the extreme case the scale ratio of recognizable objects equals 1:1.5, permitting good recognition of object sizes S within the range 0.83/= S/= 1.25. Discrimination abilities and relative Horner efficiencies of a few versions of the filter are calculated.