Search results for "convers"
showing 10 items of 1092 documents
La transición entre turnos conversacionales : Silencios, solapamientos e interrupciones
1993
Beatriz.Gallardo@uv.es En este artículo se estudia la problemática de la transición entre turnos. Los silencios, los solapamientos y las interrupciones son los fenómenos más evidentes derivados de las unidades conversacio nales. Se analizan la clasificación y la tipología de estos elementos. El silencio puede clasificarse como pausa, intervalo o lapso, según la posición en la conversación. En los casos de habla simultánea se pueden dar solapamientos colaborativos o competitivos (interrupciones), con una gradación interna regulada por la organización conversacional.
Conversion electron Mössbauer study of low carbon steel polarized in aqueous sulfate and sulfite containing sulfate solutions
1993
Abstract The passivation of low carbon steel was studied in aqueous solutions of 0.5 M Na 2 SO 4 (pH = 3.5 and 6.5) and of 0.5 M Na 2 SO 4 + 0.001 M NaHSO 3 (pH 3.5 and 6.5). The used conversion electron Mossbauer spectroscopy (CEMS) with the complementary electrochemical, microscopic and spectrophotometric investigations proved that the presence of sulfite ion induces pitting corrosion. The compositions and thichnesses of the passive films formed during the electrochemical treatments are determined from the conversion electron Mossbauer spectra. γ-FeOOH was found in each case as a major component. At pH = 3.5, the sextet belonging to Fe 3 C appears in the spectra in most cases, and also Fe…
Polychromatic femtosecond fluorescence studies of metal–polypyridine complexes in solution
2011
Femtosecond-resolved broadband fluorescence studies are reported for[ M(bpy)(3)](2+) (M = Fe, Ru), RuN3 and RuN719 complexes in solution. We investigated the pump wavelength dependence of the fluorescence of aqueous [ Fe(bpy)(3)](2+) and the solvent and ligand dependence of the fluorescence of Ru-complexes excited at 400 nm. For all complexes, the (MLCT)-M-1 fluorescence appears at zero time delay with a mirror-like image with respect to the absorption. It decays in <= 30-45 fs due to intersystem crossing to the (MLCT)-M-3 states, but a longer lived component of similar to 190 fs additionally shows up in RuN719 and RuN3. No solvent effects are detected. The very early dynamics are character…
Study of the Chemical Conversion of Aluminum Alloys by Coupling CFDE and EQCM
2004
The ability of the channel flow double electrode (CFDE) technique and electrochemical quartz crystal microbalance (EQCM) for studying in situ chromate phosphate conversion coating on 5182 aluminum alloys was explored. It was first demonstrated that aqueous Cr(VI) can be analyzed quantitatively with the CFDE technique by reduction into Cr(III) on a graphite electrode. Samples used for EQCM were quartz plated by physical vapor deposition using a 5182 alloy target, allowing thin layers of aluminum alloys with a similar chemical composition to be obtained. EQCM was adapted in order to account for the hydrodynamic conditions in an industrial process, by placing the quartz in a flow cell. In orde…
Degradation of passive layers of iron studied by conversion electron Mössbauer spectroscopy
1995
Integral electron Mossbauer spectroscopy (ICEMS) and additionally some electrochemical methods were used to characterize the passivation process of iron (low carbon steel) in sulfate, sulfate+sulfite (a possible model solution of acid rain) solutions and in phosphate buffer. The phase compositions and thicknesses of the passive layers formed due to the electrochemical polarizations were analyzed in dependence on the duration of the anodic passivations and on the pH of the used electrolytes. The passive layer, as determined from the Mossbauer spectra, consists mainly of γ-FeOOH, however in sulfite confining sulfate aqueous solution at pH 3.5 Fe 3 C and despite ex-situ circumstances FeSO 4 .H…
Mediterranean Great Conversation
2015
The exit from the Mediterranean emergency requires rethinking its identity in a new perspective. This means recognizing its legitimate role as a “Great Sea in Between”, as a cultural interface able to connect all the citizens that address to it, in everyday life and as individuals, involving them in a real “great conversation” based on the design disciplines. Design, Brand, Visual Identity, Packaging, Social Media, Fashion, Food, Architecture, Music may be powerful antidotes to the immobility of those who mourn a lost Mediterranean harmony and also a viable alternative to the ethnic closure led by the proponents of the Clash of Civilizations.
Eurípides, Helena 435-482. Elementos conversacionales, humor y guiños aristofánicos en una tragedia
2010
En este artículo el autor trata de estudiar en detalle los elementos conversacionales de un conocido pasaje de la Helena de Eurípides, su connatural asiento en la dicción de la tragedia, su interacción con algunos elementos humorísticos, los problemas que esto plantea y la ponderación de todo ello con una visión ecléctica. Se llega a la conclusión de que Eurípides introduce humor y guiños a la Comedia aristofánica en este caso y que, gracias a su talento dramático, no desvirtúa la esencia de la tragedia. This paper deals with a detailed study of conversational idioms in a well-known scene of Euripides’ Helen, their connatural place in the diction of tragedy, their interaction with some humo…
Intersystem crossing in Fe(II) coordination compounds
1994
Fe(II) spin-crossover systems can be quantitatively converted from the low-spin (LS) to the high-spin (HS) state well below the thermal transition temperature by irradiating either into the metal-ligand charge transfer or d-d absorption bands, and even in low-spin systems a transient population of the HS state can be achieved. This fact can be made use of to determine HS → LS relaxation rate constants for a wide variety of Fe(II) spin-crossover and low-spin systems. The HS → LS relaxation shows strong deviations from an Arrhenius behaviour, with nearly temperature-independent tunnelling below ∼70 K and a thermally activated process above ∼100 K. The range of more than 12 orders of magnitude…
Effect of raster resolution and polygon-conversion algorithm on landslide susceptibility mapping
2016
The choice of the proper resolution in landslide susceptibility mapping is a worth considering issue. If, on the one hand, a coarse spatial resolution may describe the terrain morphologic properties with low accuracy, on the other hand, at very fine resolutions, some of the DEM-derived morphometric factors may hold an excess of details. Moreover, the landslide inventory maps are represented throughout geospatial vector data structure, therefore a conversion procedure vector-to-raster is required.This work investigates the effects of raster resolution on the susceptibility mapping in conjunction with the use of different algorithms of vector-raster conversion. The Artificial Neural Network t…
Efficient generation of energetic ions in multi-ion plasmas by radio-frequency heating
2017
We describe a new technique for the efficient generation of high-energy ions with electromagnetic ion cyclotron waves in multi-ion plasmas. The discussed ‘three-ion’ scenarios are especially suited for strong wave absorption by a very low number of resonant ions. To observe this effect, the plasma composition has to be properly adjusted, as prescribed by theory. We demonstrate the potential of the method on the world-largest plasma magnetic confinement device, JET (Joint European Torus, Culham, UK), and the high-magnetic-field tokamak Alcator C-Mod (Cambridge, USA). The obtained results demonstrate efficient acceleration of 3He ions to high energies in dedicated hydrogen–deuterium mixtures.…