Search results for "coupling"
showing 10 items of 1862 documents
Phonon coupling of non-bridging oxygen hole center with the silica environment: Temperature dependence of the 1.9 eV emission spectra
2008
Abstract We report an experimental study on the shape of the 1.9 eV emission associated with non-bridging oxygen hole centers in silica and its temperature dependence, from 4 up to 300 K, under visible and ultraviolet excitation. Our analysis points out that these defects are coupled with their environment by phonons whose contribution can be described by the single mode of mean frequency between 300–400 cm −1 and Huang–Rhys factor of ∼3. On increasing the temperature, the luminescence intensity undergoes a thermal quenching caused by non-radiative processes, its deviation from a pure Arrhenius law can be accounted for by an uniform distribution of activation energy, from 0.002 to 0.05 eV. …
Robust Neutrino Constraints by Combining Low Redshift Observations with the CMB
2009
We illustrate how recently improved low-redshift cosmological measurements can tighten constraints on neutrino properties. In particular we examine the impact of the assumed cosmological model on the constraints. We first consider the new HST H-0 = 74.2 +/- 3.6 measurement by Riess et al. (2009) and the sigma(8)(Omega(m)/0.25)(0.41) = 0.832 +/- 0.033 constraint from Rozo et al. (2009) derived from the SDSS maxBCG Cluster Catalog. In a ACDM model and when combined with WMAP5 constraints, these low-redshift measurements constrain Sigma m(v) < 0.4 eV at the 95% confidence level. This bound does not relax when allowing for the running of the spectral index or for primordial tensor perturbations…
Dark coupling
2009
30 pages, 10 figures, 3 tables.-- Pre-print archive.
Dark radiation sterile neutrino candidates after Planck data
2013
Recent Cosmic Microwave Background (CMB) results from the Planck satellite, combined with previous CMB data and Hubble constant measurements from the Hubble Space Telescope, provide a constraint on the effective number of relativistic degrees of freedom 3.62(-0.48)(+0.50) at 95% CL. New Planck data provide a unique opportunity to place limits on models containing relativistic species at the decoupling epoch. We present here the bounds on sterile neutrino models combining Planck data with galaxy clustering information. Assuming N-eff active plus sterile massive neutrino species, in the case of a Planck+WP+HighL+HST analysis we find m(nu,sterile)(eff) < 0.36 eV and 3.14 < N-eff < 4.15 at 95% …
Constraints on the Coupling between Axionlike Dark Matter and Photons Using an Antiproton Superconducting Tuned Detection Circuit in a Cryogenic Penn…
2021
We constrain the coupling between axionlike particles (ALPs) and photons, measured with the superconducting resonant detection circuit of a cryogenic Penning trap. By searching the noise spectrum of our fixed-frequency resonant circuit for peaks caused by dark matter ALPs converting into photons in the strong magnetic field of the Penning-trap magnet, we are able to constrain the coupling of ALPs with masses around $2.7906-2.7914\,\textrm{neV/c}^2$ to $g_{a\gamma}< 1 \times 10^{-11}\,\textrm{GeV}^{-1}$. This is more than one order of magnitude lower than the best laboratory haloscope and approximately 5 times lower than the CERN axion solar telescope (CAST), setting limits in a mass and cou…
Vibronic structures in the visible luminescence of silica nanoparticles
2014
Time resolved photoluminescence investigation in air and in vacuum atmosphere of the visible luminescence related to silica surface defects is here reported. Two contributions can be singled out: one, observed both in air and in vacuum, is the well-known blue band, peaked around 2.8 eV decaying in ∼5 ns; the other, only observed in vacuum, is a structured emission in the violet range characterized by two vibronic progressions spaced 1370 cm−1 and 360 cm−1 decaying in ∼100 ns. In contrast with previous attribution, the well distinguishable spectroscopic properties together with the observation of the effects induced by the interaction with nitrogen allow to state that the emission bands orig…
Measurement of untruncated nuclear spin interactions via zero- to ultralow-field nuclear magnetic resonance
2015
Zero- to ultra-low-field nuclear magnetic resonance (ZULF NMR) provides a new regime for the measurement of nuclear spin-spin interactions free from effects of large magnetic fields, such as truncation of terms that do not commute with the Zeeman Hamiltonian. One such interaction, the magnetic dipole-dipole coupling, is a valuable source of spatial information in NMR, though many terms are unobservable in high-field NMR, and the coupling averages to zero under isotropic molecular tumbling. Under partial alignment, this information is retained in the form of so-called residual dipolar couplings. We report zero- to ultra-low-field NMR measurements of residual dipolar couplings in acetonitrile…
FT Raman and DFT Study on a Series of All-antiOligothienoacenes End-Capped with Triisopropylsilyl Groups
2009
minal a positions. These substituents aid in purification and solution processability, and can be removed under mild chemical conditions. For the first time, we have the opportunity to analyze a series of oligothienoacenes to gain insight into the fundamental structure–property relationships with respect to the addition of each ring. Furthermore, this series of compounds can be directly compared to other well-studied series of closely related oligomers, such as nonfused oligothiophenes and fully fused all-syn oligothienoacenes. [7] To gain precise insight into relationships between the structure and properties of a wide range of p-conjugated molecular Herein, we study the p-conjugational pr…
A Mechano-Chemical Coupling for Hydrogen Diffusion in Metals Based on a Thermodynamic Approach
2014
Hydrogen diffusion in metals is still an ongoing topic of research due to its technical relevance (hydrogen embrittlement, hydrogen storage...). In the last decades, significant progress in understanding the time evolution of the hydrogen concentration in solids was completed. This paper presents a modeling of hydrogen diffusion with a general and thermodynamically based diffusion concept coupled with mechanical and chemical aspects. This model was previously used to simulate the oxidation of a metal [1][2]. This concept has been upgraded to offer a thoroughly macroscopic behavior law used to simulate hydrogen diffusion in metal parts under mechanical loadings. The thermodynamic approach of…
Ambiguities in organizations and the routines of behavior and change
2015
Purpose– The aim of this article is threefold: the primary aim is conceptual by outlining two ideal-typical ideas about organizational life. These models offer rival ideas about how organizations balance seemingly conflicting patterns of behaviour and change in everyday life. The second ambition of the article is to outline a theoretical approach of organizational life arguing that even fairly loosely coupled organizations may be profoundly patterned by everyday routines as much as by ambiguity. The third and final ambition is to offer empirical illustrations from organizations that are often considered as archetypes of loose coupling and ambiguities: jazz orchestras and university organiza…