Search results for "cracking"
showing 10 items of 102 documents
Decalin and Tetralin as Probe Molecules for Cracking and Hydrotreating the Light Cycle Oil
2001
Abstract Cracking of tetralin and decalin was carried out over several zeolites to establish the effect of the pore topology of the catalyst on product distribution. These molecules were chosen as probe molecules, because they indicate which catalyst is the best for cracking or hydrotreating the light cycle oil (LCO) fraction, which is obtained directly from fluid catalytic cracking units. A set of zeolites with medium-sized (ZSM-5, MCM-22, ITQ-2), large (USY, Beta), and ultralarge pores (UTD-1), as well as a mesoporous MCM-41, were used as catalysts at 723 K. The results demonstrate that pore size and topology have a strong influence on diffusion, and consequently, on activity and selectiv…
Moisture dependence on mechanical properties of pine nuts from Pinus pinea L.
2012
Abstract Mechanical properties of pine nut shell are very important in the cracking process. Before industrial cracking shell moisture is adjusted by water soaking in order to avoid the breaking up of the nuts. In this work the moisture dependence of the mechanical properties of pine nut shells were studied in order to improve the industrial cracking process. Relationship between nut size and moisture content was studied and no significant differences were found for shell dimensions at four different moisture levels, 9.79%, 16.71%, 20.98% and 25.05% (dry basis). Compression tests were carried out on pine nuts at nine different moisture contents between 1.38% and 25.48% (db) and their main m…
Converting olefins to propene: Ethene to propene and olefin cracking
2018
ABSTRACTDemand for propene as a petrochemical building block keeps growing, while its availability has been decreased by the adoption of shale gas resources, among others. Efforts to optimize its production by conventional means (including modified fluid catalytic cracking) and new on-purpose production technologies (including ethene to propene (ETP) and olefin cracking) are being pursued. This work reviews the progress made on olefin conversion processes, including the ETP reaction, which is still under development, and the cracking of butenes and higher olefins (C5–C8). The factors analyzed include the catalytic performance of different zeolite materials and their modifications to increas…
Product selectivity effects during cracking of alkanes at very short and longer times on stream
1996
Abstract Cracking of C 7 , C 10 , C 12 and C 14 n-alkanes, over USY, Beta and ZSM-5 zeolites was carried out in a reaction system which allows to obtain instantaneous conversions at very short times on stream. With this system the influence of operation variables, chain length of the paraffin fed, and catalyst structure on product selectivity was established. Positive and negative effects of catalyst decay on product selectivity were obtained, and this behaviour could be simulated by using a deactivation model in which the rate of deactivation depends on the product concentration. It was observed that olefin/paraffin, branched/normal paraffin, branched/normal olefin ratios and aromatic sele…
Microcracking in piezoelectric materials by the Boundary Element Method
2019
A 3D boundary element model for piezoelectric polycrystalline micro-cracking is discussed in this contribution. The model is based on the boundary integral representation of the electro-mechanical behavior of individual grains and on the use of a generalized cohesive formulation for inter-granular micro-cracking. The boundary integral formulation allows to address the electro-mechanical boundary value problem in terms of generalized grain boundary and inter-granular displacements and tractions only, which implies the natural inclusion of the cohesive laws in the formulation, the simplification of the analysis pre-processing stage, and the reduction of the number of degrees of freedom of the…
Modelling stress-corrosion microcracking in polycrystalline materials by the Boundary Element Method
2019
The boundary element method is employed in this study in conjunction with the finite element method to build a multi-physics hybrid numerical model for the computational study of stress corrosion cracking related to hydrogen diffusion in polycrystalline microstructures. More specifically a boundary integral representation is used to represent the micro-mechanics of the aggregate while an explicit finite element method is used to model inter-granular hydrogen diffusion. The inter-granular interaction between contiguous grains is represented through cohesive laws, whose physical parameters depend on the concentration of inter-granular hydrogen, diffusing along the interfaces according to the …
Brittle failure in polycrystalline RVEs by a grain-scale cohesive boundary element formulation
2013
Polycrystalline materials are commonly employed in engineering structures. For modern applica- tions a deep understanding of materials degradation is of crucial relevance. It is nowadays widely recognized that the macroscopic material properties depend on the microstructure. The polycrystalline microstructure is characterized by the features of the grains and by the phys- ical and chemical properties of the intergranular interfaces, that have a direct influence on the evolution of the microstructural damage. The experimental investigation of failure mechanisms in 3D polycrystals still remains a challenging task. A viable alternative, or complement, to the experiments is Computational Microm…
IM-5 zeolite for steam catalytic cracking of naphtha to produce propene and ethene. An alternative to ZSM-5 zeolite
2013
Steam catalytic cracking of naphtha in smaller FCC units can be considered an option to produce more ethene and propene. These units will operate at high reaction temperatures and in the presence of steam. The profitability of these units could be improved with the use of new catalysts with higher activity and hydrothermal stability, without compromising the selectivity to light olefins. We have explored the possibilities of IM-5 zeolite for high temperature steam catalytic cracking (SCC) of a naphtha, as an alternative to commonly used ZSM-5 zeolite. So, we compare the catalytic activity, the effect of operating variables of the process and the yields of interest products between the two z…
A computationally effective 3D Boundary Element Method for polycrystalline micromechanics
2015
An effective computational framework for homogenization and microcracking analysis of polycrystalline RVEs is presented. The method is based on a recently developed grain-boundary formulation for polycrystalline materials and several enhancements over the original technique are introduced to reduce the computational effort needed to model three-dimensional polycrystalline aggregates, which is highly desirable, especially in a multiscale perspective. First, a regularization scheme is used to remove pathological entities, usually responsible for unduly large mesh refinements, from Voronoi polycrystalline morphologies. Second, an improved meshing strategy is used, with an aim towards meshing r…
Microstructural modifications resulting from the dehydration of gypsum
2001
Various faces of dehydrated gypsum-cleaved blocks and single crystals have been investigated using optical microscopy, SEM, and TEM. The orientation of the cracks with respect to the initial gypsum structure and the Miller indices of all possible crack planes have been determined. These crack planes have been found to be few and to correspond to planes of high atomic density in the initial and final structures, therefore characterised by a low surface tension. These observations allow us to propose cracking criteria based on general concepts of crystal growth. The cracks' dimensions measured on different faces of the pseudomorph are distributed over several orders of magnitude and seems to …