Search results for "crafts."
showing 10 items of 101 documents
ChemInform Abstract: Indirect Regioselective Heteroarylation of Indoles Through a Friedel-Crafts Reaction with (E)-1,4-Diaryl-2-buten-1,4-diones.
2010
Abstract A two-step synthesis of 3-heteroaryl indoles has been developed. The first step of the sequence involves a Friedel–Crafts alkylation of indoles with 1,4-diaryl-2-buten-1,4-diones to give the corresponding indoles bearing a 1,4-dicarbonyl moiety. The reaction is catalyzed by InCl 3 and takes place with good yields. Cyclization of the diones under different Paal–Knorr conditions allows to prepare indoles substituted at the C3 position with 3-furanyl, 3-pyrrolyl- and 3-thienyl moieties.
Indirect regioselective heteroarylation of indoles through a Friedel–Crafts reaction with (E)-1,4-diaryl-2-buten-1,4-diones
2009
Abstract A two-step synthesis of 3-heteroaryl indoles has been developed. The first step of the sequence involves a Friedel–Crafts alkylation of indoles with 1,4-diaryl-2-buten-1,4-diones to give the corresponding indoles bearing a 1,4-dicarbonyl moiety. The reaction is catalyzed by InCl 3 and takes place with good yields. Cyclization of the diones under different Paal–Knorr conditions allows to prepare indoles substituted at the C3 position with 3-furanyl, 3-pyrrolyl- and 3-thienyl moieties.
Organocatalytic asymmetric addition of naphthols and electron-rich phenols to isatin-derived ketimines: highly enantioselective construction of tetra…
2015
A quinine-derived thiourea organocatalyst promoted the highly enantioselective addition of naphthols and activated phenols to ketimines derived from isatins. The reaction afforded chiral 3-amino-2-oxindoles with a quaternary stereocenter in high yields (up to 99%) with excellent enantioselectivity (up to 99% ee). To the best of our knowledge, this transformation is the first highly enantioselective addition of naphthols to ketimines
Arte Textil y tradición en la Provincia de Catamarca, Noroeste Argentino
2019
espanolLas tradiciones textiles en la Provincia de Catamarca, constituyen parte de una identidad cultural conformada a partir de elementos muy pujantes provenientes de distinto origen. Estos se traslucen tanto en estilos y tecnicas de piezas de exquisita estetica y calidad. Evidencian ademas, la historia de las industrias y manufacturas textiles que aportaron al desarrollo de esta actividad, considerada por sus habitantes como parte de su idiosincracia que -lamentablemente- con los anos tiende a desaparecer. EnglishThe textile traditions in the province of Catamarca, are part of a cultural identity formed from very vigorous elements from different origins. These are permeated both styles an…
Rémunérations, travail et niveaux de vie à Dijon à la fin du Moyen-Age
2019
The remuneration of work is a familiar concept in our modern world. It is well known that medieval societies also faced it, but we don’t know under what proportions, what influenced its level and how it participates to living standard. These are the central questions guiding this work, with Dijon at the end of the Middle Ages as a mooring point. The richness of Dijon medieval archives offers high quality material for the study of medieval remunerations. A first point of observation was established during the 1370-1395 period, where the cross-referencing of various documents made possible to systemically observe the importance of remunerations within Dijon society. Two other observation poin…
The black female slave takes literary revenge: Female gothic motifs against slavery in Hannah Crafts’s "The Bondwoman’s Narrative"
2015
The Bondwoman’s Narrative is a novel that functions as a story made up from Hannah Crafts’s experiences as a bondwoman and thus merges fact and fiction giving a thoroughly new account of slavery both committed to reality and fiction. Following and taking over the Gothic literary genre that spread in Europe as a reaction toward the Romantic spirit, Crafts uses it to denounce the degrading slavery system and, mainly, to scathingly attack the patriarchal roots that stigmatize black women as the ultimate victims. It is my contention that Hannah Crafts uses the female Gothic literary devices both to attack slavery and also to stand as a proper (African) American citizen capable of relating to th…
Designing Dissensual Common Sense: Critical Art, Architecture, and Design in Jacques Rancière’s Political Thought
2021
How can design be socially engaged and politically efficient, as proposed by discourses labeled as critical design? This article introduces a conceptualization and historiography of politically charged design discourse based on philosopher Jacques Rancière’s work on the intersections of politics, aesthetics, and critical artistic practices. By focusing especially on Rancière’s reading of the genealogy of design from Ruskin to constructivism and the Bauhaus, the article aims to show that there is an important connection between design and politics present in Rancière’s thought. Rather than solely revealing the oppressive dimension embedded in designed forms, for Rancière, design is itself a …
ChemInform Abstract: Organocatalytic Enantioselective Friedel-Crafts Alkylation of 1-Naphthol Derivatives and Activated Phenols with Ethyl Trifluorop…
2016
Financial support from the MINECO [Gobierno de Espana and FEDER (EU)] (CTQ2013-47949-P) and from Generalitat Valenciana (ISIC2012/001) is gratefully acknowledged. M.M.-M. thanks the Universitat de Valencia for a predoctoral grant. C. V. thanks MINECO for JdC contract. Access to NMR and MS facilities from the Servei central de support a la investigacio experimental (SCSIE)-UV is also acknowledged.
Characterization of some isomeric benzophenones by their mass spectra
1979
Benzophenones have been described to undergo characteristic α-cleavage and rearrangement processes upon mass spectrometric fragmentation. Recently two series of new and isomeric benzophenones have been prepared from phenylbenzoates by Fries rearrangement or directly by Friedel Crafts acylation. It is shown that the above mentioned diagnostic fragmentation processes can be used to characterize the resulting isomeric ortho or para hydroxy and ortho or para methoxy benzophenones unambigously.
Artesanado sedero y capital comercial en la Valencia del siglo XVIII
1997
The intense development of the «Verlagssystem» in the XVIII century silk industry in Valencia showed the difficulties of the traditional craftsmen to keep their economic independence. In order to fighy against it, the craftsmen adopted several initiatives, which dealt with the constitution of a share-holding company, as much as with the creation of a communal store to favour the suppley of raw materials to the factories. The most important project was the constitution of the «Compañía de Nuestra Señora de los Desamparados» in 1772. But the requirement of the General Board of Commerce to allow all the social classes to take part in shareholders, as it was not accompanied by the modification …