Search results for "critical points"

showing 4 items of 44 documents

Protein dynamical transition vs. liquid-liquid phase transition in protein hydration water

2013

In this work, we compare experimental data on myoglobin hydrated powders from elastic neutron scattering, broadband dielectric spectroscopy, and differential scanning calorimetry. Our aim is to obtain new insights on the connection between the protein dynamical transition, a fundamental phenomenon observed in proteins whose physical origin is highly debated, and the liquid-liquid phase transition (LLPT) possibly occurring in protein hydration water and related to the existence of a low temperature critical point in supercooled water. Our results provide a consistent thermodynamic/dynamic description which gives experimental support to the LLPT hypothesis and further reveals how fundamental …

biothermics critical points liquid-liquid transformations molecular biophysics proteins solvation supercooling waterSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)
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Existence of three solutions for a mixed boundary value system with (p_1,...,p_m)-Laplacian

2014

In this paper we prove the existence of at least three weak solutions for a mixed boundary value system with (p_1,,...,p_m)-Laplacian. The approach is based on variational methods.

critical points variational methods p-LaplacianSettore MAT/05 - Analisi Matematica
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Relationship between volume and energy of vector fields

2001

Abstract A unified study of energy and volume functionals is presented here by determining the critical points of a functional that extends simultaneously energy and volume and that is defined on the product of the manifold of smooth maps C∞(M,N) times the manifold M of riemannian metrics on M. The restriction of this functional to different submanifolds of the space of vector fields X (M)× M is also considered, and used to study several functionals generalizing volume and energy or total bending of vector fields

volumeenergy and total bending of vector fieldscritical pointsMathematical analysisBendingVolume and energy functionalsSpace (mathematics)Manifoldvariational problemsComputational Theory and MathematicsVolume (thermodynamics)Product (mathematics)Fundamental vector fieldVector fieldGeometry and TopologyMathematics::Differential GeometryAnalysisEnergy (signal processing)MathematicsDifferential Geometry and its Applications
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Kinetics of phase separation in thin films: Lattice versus continuum models for solid binary mixtures

2008

A description of phase separation kinetics for solid binary (A,B) mixtures in thin film geometry based on the Kawasaki spin-exchange kinetic Ising model is presented in a discrete lattice molecular field formulation. It is shown that the model describes the interplay of wetting layer formation and lateral phase separation, which leads to a characteristic domain size $\ell(t)$ in the directions parallel to the confining walls that grows according to the Lifshitz-Slyozov $t^{1/3}$ law with time $t$ after the quench. Near the critical point of the model, the description is shown to be equivalent to the standard treatments based on Ginzburg-Landau models. Unlike the latter, the present treatmen…

wettingMaterials scienceStatistical Mechanics (cond-mat.stat-mech)Condensed matter physicscritical pointsGinzburg-Landau theoryTime evolutionFOS: Physical sciencesBinary numberfree energyLattice constantthin filmsCritical point (thermodynamics)Lattice (order)Ising modelWettingphase separationThin filmCondensed Matter - Statistical MechanicsWetting layerPhysical Review E
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