Search results for "current density"
showing 10 items of 99 documents
Effect of membrane profiles on the limiting current density in electrodialysis
2019
In the present work, we experimenrtally investigated the effect of different membrane profiles on the LCD, testing also different operating conditions.
Influence of doped charge transport layers on efficient perovskite solar cells
2018
Planar vacuum deposited p–i–n methyl ammonium lead tri-iodide perovskite solar cells are prepared with different electron and hole transporting layers, either doped or undoped. The effect of these layers on the solar cells performance (efficiency and stability) is studied. The main benefit of using doped layers lies in the formation of barrier free charge extraction contacts to the electrodes. However, this comes at the cost of increased residual absorption (reducing the current density and efficiency of the cells) and a decreased stability. A generic solar cell structure using undoped charge extraction layers is presented, containing a thin layer of a strong electron acceptor in between th…
A finite-difference method for numerical solution of the steady-state nernst—planck equations with non-zero convection and electric current density
1986
Abstract A computer algorithm has been developed for digital simulation of ionic transport through membranes obeying the Nernst—Planck and Poisson equations. The method of computation is quite general and allows the treatment of steady-state electrodiffusion equations for multiionic environments, the ionic species having arbitrary valences and mobilities, when convection and electric current are involved. The procedure provides a great flexibility in the choice of suitable boundary conditions and avoids numerical instabilities which are so frequent in numerical methods. Numerical results for concentration and electric potential gradient profiles are presented in the particular case of the t…
A High-Performance Asymmetric Supercapacitor Based on Tungsten Oxide Nanoplates and Highly Reduced Graphene Oxide Electrodes.
2021
Tungsten oxide/graphene hybrid materials are attractive semiconductors for energy-related applications. Herein, we report an asymmetric supercapacitor (ASC, HRG//m-WO3 ASC), fabricated from monoclinic tungsten oxide (m-WO3 ) nanoplates as a negative electrode and highly reduced graphene oxide (HRG) as a positive electrode material. The supercapacitor performance of the prepared electrodes was evaluated in an aqueous electrolyte (1 m H2 SO4 ) using three- and two-electrode systems. The HRG//m-WO3 ASC exhibits a maximum specific capacitance of 389 F g-1 at a current density of 0.5 A g-1 , with an associated high energy density of 93 Wh kg-1 at a power density of 500 W kg-1 in a wide 1.6 V ope…
Relation between microstructure and transport properties of epitaxial YBa2Cu3O7-d thin films.
1997
Abstract In order to understand the origin of the high critical current densities observed in thin superconducting films compared to single crystals we measured in several epitaxial YBa 2 Cu 3 O 7−δ thin films the magnetic field and temperature dependence of the superconducting current density j s and the dynamical relaxation rate Q ≡ d ln j s / d ln( d B/ dt ). For all samples we found that (i) the superconducting current density j s is independent of magnetic field up to a certain field B Φ . The value of this field, which is sample dependent, decreases with increasing temperature; (ii) for fields B>B Φ , the superconducting current density falls off as B −1/2 over several decades; (iii) …
On the determination of vortex creep parameters in superconductors using standard magnetization relaxation data
2011
The relaxation of the irreversible magnetic moment m(t) in YBa2Cu3O7 (YBCO) films was investigated as a function of temperature T and the external magnetic field H along the c axis applied in zero-field cooling conditions, for the determination of vortex creep parameters. The data analysis was performed using the T and current density dependence of the normalized vortex creep activation energy, or by the fit of the m(t) data with the well known interpolation formula in the framework of the general vortex creep equation. It was found that (i) even for specimens with strong static pinning the characteristic pinning energy remains small in the low-T range, where the vortex creep appearing in s…
Origin of high critical currents in YBa2Cu3O7−δ superconducting thin films
1999
Thin films of the high-temperature superconductor YBa2Cu3O7−δ exhibit both a large critical current (the superconducting current density generally lies between 1011 and 1012 A m−2 at 4.2 K in zero magnetic field) and a decrease in such currents with magnetic field that point to the importance of strong vortex pinning along extended defects1,2. But it has hitherto been unclear which types of defect—dislocations, grain boundaries, surface corrugations and anti-phase boundaries—are responsible. Here we make use of a sequential etching technique to address this question. We find that both edge and screw dislocations, which can be mapped quantitatively by this technique, are the linear defects t…
Large Area Deposition by Radio Frequency Sputtering of Gd0.1Ce0.9O1.95 Buffer Layers in Solid Oxide Fuel Cells: Structural, Morphological and Electro…
2021
We investigate the influence of position, under large circular sputtering targets, on the final electrochemical performance of 35 mm diameter button solid oxide fuel cells with sputter-deposited Gadolinium doped Ceria barrier layers, positioned in order to almost cover the entirety of the area associated with a 120 × 80 mm2 industrial cell. We compare the results obtained via structural and morphological analysis to the Electrochemical Impedance Spectroscopy (EIS) measurements performed on the button cells, disentangling the role of different parameters. The Atomic Force Microscopy analysis makes it possible to observe a decrease in the roughness values from the peripheral to the central zo…
Cavitation corrosion and repassivation kinetics of titanium in a heavy brine LiBr solution evaluated by using electrochemical techniques and Confocal…
2011
The cavitation corrosion behaviour of commercially pure Grade 2 titanium in a 992 g/l LiBr solution has been investigated at 25 °C using an ultrasound device. Cavitation was found to have more influence on the anodic branch than on the cathodic branch, shifting the corrosion potential, Ecorr, and the OCP value towards more negative potentials, and increasing the corrosion current density, icorr, by six times. The repassivation kinetics of Grade 2 titanium have also been studied in the 992 g/l LiBr solution, at 25 °C and various applied potentials, using cavitation to damage the electrode surface. The repassivation kinetics have been analysed in terms of the current density flowing from the …
Determination of limiting current density and current efficiency in electrodialysis units
2018
Abstract A crucial parameter for the design and operation of electrodialysis (ED) units is the limiting current density (LCD). This is often identified with the diffusion-limited current density, which corresponds to the complete solute depletion in the layer adjacent to the membrane. Current-voltage curves obtained from measurements with electrodes in contact with the solution (i.e. without membranes) are consistent with this interpretation and exhibit a horizontal plateau identifying LCD. However, real ED systems show more complex behaviours, with a reduced-slope tract instead of a plateau and a third region in which the current increases more markedly (overlimiting current). The phenomen…