Search results for "dam"

showing 10 items of 3828 documents

Exploring the photothermo-catalytic performance of brookite tio2-ceo2 composites

2020

The thermocatalytic, photocatalytic and photothermo-catalytic oxidation of some volatile organic compounds (VOCs), 2-propanol, ethanol and toluene, was investigated over brookite TiO2-CeO2 composites. The multi-catalytic approach based on the synergistic effect between solar photocatalysis and thermocatalysis led to the considerable decrease in the conversion temperatures of the organic compounds. In particular, in the photothermo-catalytic runs, for the most active samples (TiO2-3 wt% CeO2 and TiO2-5 wt% CeO2), the temperature at which 90% of VOC conversion occurred was about 60 &deg

Cerium oxideMaterials science02 engineering and technologylcsh:Chemical technology010402 general chemistry01 natural sciencesRedoxCatalysisCatalysislcsh:Chemistrychemistry.chemical_compoundAir purification Brookite Cerium oxide Photocatalysis VOCslcsh:TP1-1185Physical and Theoretical ChemistryComposite materialcerium oxideEthanolBrookiteVOCsbrookitePhotothermal therapy021001 nanoscience & nanotechnologyToluene0104 chemical scienceslcsh:QD1-999chemistryair purificationvisual_artvisual_art.visual_art_mediumPhotocatalysisSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologyphotocatalysis
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Protection of Social Rights as a Permament Challenge for the European Union

2021

Social rights protection in the European Union has undergone significant development. Currently their protection is regulated by relevant treaty provisions and the Charter of Fundamental Rights (Charter), both of a primary law nature, as well as by the non-binding European Pillar of Social Rights (Pillar). The aim of the paper is the assessment of the social rights protection in the EU, and whether all social rights provided in the CFR have their counterparts in the EPSR, hence whether and in what way the EPSR assists the actual exercise of social rights provided by the CFR. Comparing the content of the above-mentioned legal instruments makes it possible to answer the question whether all s…

Charter of Fundamental Rights Social Pillar social rights European Labour Authority Social ScoreboardChemistrysocial rightsSocial rightsGeneral MedicineK1-7720Charter of Fundamental RightsLaw in general. Comparative and uniform law. JurisprudenceLawSocial PillarCharter of fundamental rightsmedia_common.cataloged_instanceEuropean Labour AuthorityEuropean unionSocial Scoreboardmedia_commonReview of European, Comparative and International Environmental Law
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Application of Genetic Algorithm on Parameter Optimization of Three Vehicle Crash Scenarios

2017

Abstract This paper focuses on the development of mathematical models for vehicle frontal crashes. The models under consideration are threefold: a vehicle into barrier, vehicle-occupant and vehicle to vehicle frontal crashes. The first model is represented as a simple spring-mass-damper and the second case consists of a double-spring-mass-damper system, whereby the front mass and the rear mass represent the vehicle chassis and the occupant, respectively. The third model consists of a collision of two vehicles represented by two masses moving in opposite directions. The springs and dampers in the models are nonlinear piecewise functions of displacements and velocities respectively. More spec…

ChassisComputer scienceModeling010103 numerical & computational mathematics02 engineering and technologyCollision01 natural sciencesCrash testfrontal crashvehicle-occupantDamperNonlinear system020303 mechanical engineering & transports0203 mechanical engineeringControl theoryControl and Systems EngineeringGenetic algorithmparameters estimationgenetic algorithm0101 mathematicsSimulationfrontal crash; genetic algorithm; Modeling; parameters estimation; vehicle-occupant; Control and Systems EngineeringMotor vehicle crash
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ATRIP protects progenitor cells against DNA damage in vivo

2020

AbstractThe maintenance of genomic stability during the cell cycle of progenitor cells is essential for the faithful transmission of genetic information. Mutations in genes that ensure genome stability lead to human developmental syndromes. Mutations in Ataxia Telangiectasia and Rad3-related (ATR) or in ATR-interacting protein (ATRIP) lead to Seckel syndrome, which is characterized by developmental malformations and short life expectancy. While the roles of ATR in replicative stress response and chromosomal segregation are well established, it is unknown how ATRIP contributes to maintaining genomic stability in progenitor cells in vivo. Here, we generated the first mouse model to investigat…

CheckpointsProgrammed cell deathDNA damage[SDV]Life Sciences [q-bio]610 MedizinBiologyDNA replicationDNA damage responseArticle03 medical and health sciences0302 clinical medicine610 Medical sciencesmedicineProgenitor celllcsh:QH573-671GeneMitosisComputingMilieux_MISCELLANEOUSCell proliferation030304 developmental biology0303 health scienceslcsh:CytologyDisease modelCell cyclemedicine.diseaseCell biologyApoptosis030220 oncology & carcinogenesisAtaxia-telangiectasiaCell Death & Disease
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Alkyloxy modified pyrene fluorophores with tunable photophysical and crystalline properties

2019

Novel alkyloxy modified 2,7-di-tert-butyl-4,5,9,10-tetra(arylethynyl)pyrenes were prepared through a straightforward Sonogashira coupling approach. Optical properties such as quantum yields and absorption/emission spectra of the fluorophores were investigated by UV/Vis and fluorescence measurements. Aggregation induced excimer formation of the chromophores in polar solvents and in the solid state was proved by the presence of a characteristic bathochromically shifted emission band and a decrease of the emission capability. These results strongly indicate the unexpected observation that the excimer formation of adjacent pyrene rings is not prevented by the introduction of bulky tert-butyl su…

ChemistryChemieSonogashira coupling02 engineering and technologyGeneral ChemistryChromophore010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistryExcimer01 natural sciencesFluorescenceCatalysis0104 chemical sciencesLiquid crystals Luminophore pyrene crystal packingchemistry.chemical_compoundMaterials ChemistryMoleculePyreneEmission spectrumSettore CHIM/07 - Fondamenti Chimici Delle TecnologieAbsorption (chemistry)0210 nano-technology
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Nanogel-antimiR-31 conjugates affect colon cancer cells behaviour

2017

Soft and flexible nanogels, produced by electron beam (e-beam) irradiation of poly(N-vinyl pyrrolidone) and acrylic acid, were evaluated as delivery devices of the inhibitor of miR-31, a small RNA molecule with an important role in colorectal cancer (CRC) progression. The nanogel carriers developed possess both carboxyl and primary amino groups; the former were activated to react with the primary amino group present in the purposely-functionalised AntimiR-31. Very high conjugation reaction yields were attained, as well as a remarkable colloidal and storage stability of the conjugates. The ability of these nanoconstructs to be internalized by cells and the specific interaction of conjugated …

ChemistryColorectal cancerGeneral Chemical EngineeringNanogels02 engineering and technologyGeneral ChemistryConjugated system010402 general chemistry021001 nanoscience & nanotechnologymedicine.disease01 natural sciencesIn vitro0104 chemical scienceschemistry.chemical_compoundBiochemistryBiological targetcolorectal cancer treatmentmedicineBiophysicsSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologyConjugateAcrylic acidNanogel
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The involvement of DNA damage response pathway in nuclear reorganization during netotic initiation

2019

ChemistryDNA damageGeneral Biochemistry Genetics and Molecular BiologyCell biologyBiopolymers and Cell
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Naturally occurring polyphenols as building blocks for supramolecular liquid crystals – substitution pattern dominates mesomorphism

2021

A modular supramolecular approach towards hydrogen-bonded liquid crystalline assemblies based on naturally occurring polyphenols is reported. The combination of experimental observations, crystallographic studies and semi-empirical analyses of the assemblies provides insight into the structure–property relationships of these materials. Here a direct correlation of the number of donor OH-groups as well as their orientation with the mesomorphic behavior is reported. We discovered that the number and orientation of the OH-groups have a stronger influence on the mesomorphic behavior of the supramolecular assemblies than the connectivity (e.g. stilbenoid or chalconoid) of the hydrogen bond donor…

ChemistryHydrogen bondLiquid crystallineProcess Chemistry and TechnologyChemieBiomedical EngineeringSupramolecular chemistryEnergy Engineering and Power Technology02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesIndustrial and Manufacturing Engineering0104 chemical sciencesCrystallographyChemistry (miscellaneous)Liquid crystalSupramolecular Chemistry Liquid Crystals Crystal Engineering Hydrogen BondingMaterials ChemistryChemical Engineering (miscellaneous)Settore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologyMolecular Systems Design & Engineering
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Highly Reduced Saturation Magnetization in Epitaxially Grown Ferrimagnetic Heusler Thin Films

2019

The key of spintronic devices using the spin-transfer torque phenomenon is the effective reduction of switching current density by lowering the damping constant and the saturation magnetization while retaining strong perpendicular magnetic anisotropy. To reduce the saturation magnetization, particular conditions such as specific substitutions or buffer layers are required. Herein, we demonstrate highly reduced saturation magnetization in tetragonal D022 Mn3–xGa thin films prepared by rf magnetron sputtering, where the epitaxial growth is examined on various substrates without any buffer layer. As the lattice mismatch between the sample and the substrate decreases from LaAlO3 and (LaAlO3)0.3…

ChemistryMaterials scienceSpintronicsCondensed matter physicsFerrimagnetismGeneral Chemical EngineeringGeneral ChemistryDamping constantThin filmEpitaxyQD1-999Current densityArticleACS Omega
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Photocatalytic and Catalytic Reactions in Gas–Solid and in Liquid–Solid Systems

2019

Abstract Heterogeneous photocatalytic and thermal-catalytic reactions are here presented focusing the differences and similarities between the two processes. When possible, the comparison was made for the same chemical reaction in the presence of an inorganic material playing the role of both catalyst or/and photocatalyst. Several examples are presented where a catalytic reaction can occur at milder experimental conditions and, particularly, at lower temperature when the system is also irradiated by UV and/or visible light. The differences in mechanistic aspects, conversions, and selectivities between catalytic and photocatalytic reactions will be also considered because these occurrences a…

ChemistryPhotocatalysisCatalytic versus photocatalytic reactions thermal-catalytic reactions photo-assisted reactions partial (photo)oxidation reactionsSettore CHIM/07 - Fondamenti Chimici Delle TecnologieActivation energyIrradiationLiquid solidGas solidPhotochemistryChemical reactionVisible spectrumCatalysis
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