Search results for "decomposition"

A gradient-based decomposition approach to optimize pressure path and counterpunch action in Y-shaped tube hydroforming operations

2008

International audience; In tube hydroforming, the concurrent actions of pressurized fluid and mechanical feeding allows obtaining tube shapes characterized by complex geometries such as different diameters sections and/or bulged zones. Main process parameters are material feeding history (i.e., the punches velocity history), internal pressure path during the process, and (in T- or Y-shaped tube hydroforming) counterpunch action. What is crucial, in such processes, is the proper design of operative parameters aimed to avoid defects (for instance underfilling or ductile fractures). Actually, the design of tube hydroforming operations is mainly aimed to prevent bursting or buckling occurrence …

Round-handle decomposition ofS2×S1

2007

A round-handle decomposition is associated with a non-singular Morse–Smale flow on 3-manifolds prime to S 2× S 1. This decomposition has been built only for the 3-sphere S 3. In this paper we obtain the round-handle decomposition of non-singular Morse–Smale flows on S 2× S 1, in order to get all the different fattened round handles in this manifold. Some of them include non-separating boundary components that induce the topology of the links of periodic orbits.

Syntheses of novelN-([18F]fluoroalkyl)-N-nitroso-4-methyl-benzenesulfonamides and decomposition studies of corresponding19F- and bromo-analogues: pot…

2003

N-([ 18 F]fluoroalkyl)-N-nitroso-4-methyl-benzensulfonamides [n-alkyl = (-CH 2 ) [ 18,19 F]F, n=2-4)] were synthesized in radiochemical yields ranging from 75-90% to provide new secondary labelling precursors for the syntheses of 18 F-labelled compounds. Preliminary decomposition studies utilizing the corresponding non-radioactive 19 F-compounds as well as the bromo containing analogous compounds were performed to evaluate their stability regarding temperature and basicity of the labelling medium. Furthermore, initial difficulties in labelling these compounds led to the development of a modified labelling procedure applying nearly solvent-free conditions. Extensive decomposition experiments…

Synthesis and thermoelectric characterisation of bismuth nanoparticles

2009

An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi(SC12H25)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispe…

The terminal hyperspace of homogeneous continua

2010

Abstract We investigate the structure of the collection of terminal subcontinua in homogeneous continua. The main result is a reduction of this structure to six specific types. Three of these types are of one-dimensional spaces, and examples representing these types are known. It is not known whether higher dimensional examples having non-trivial terminal subcontinua and representing the three remaining types exist.

Properties and Structural Studies of Multi-Wall Carbon Nanotubes-Phosphate Ester Hybrids

2013

Long chain phosphate esters bearing at least one or two aryl groups have been synthesized and used for the preparation of stable multi-walled carbon nanotube (MWCNT) hybrids. The non-covalent interaction ester/MWCNT has been investigated by several techniques (SEM, UV-vis, 31P-NMR, RAMAN). The used phosphate ester derivatives demonstrated the ability to produce an excellent dispersion of MWCNT in CHCl3. The obtained dispersions showed a great stability from one to at least three weeks in the range of concentration considered. Thermal analysis showed an increase in the decomposition temperature for the hybrids with respect to pristine MWCNT.

Solar UV radiation and plant responses : assessing the methodological problems in research concerning stratospheric ozone depletion

2010

A Flux-Split Algorithm Applied to Relativistic Flows

1998

The equations of RFD can be written as a hyperbolic system of conservation laws by choosing an appropriate vector of unknowns. We give an explicit formulation of the full spectral decomposition of the Jacobian matrices associated with the fluxes in each spatial direction, which is the essential ingredient of the techniques we propose in this paper. These techniques are based on the recently derived flux formula of Marquina, a new way to compute the numerical flux at a cell interface which leads to a conservative, upwind numerical scheme. Using the spectral decompositions in a fundamental way, we construct high order versions of the basic first-order scheme described by R. Donat and A. Marqu…

The impact of baking on chlorinated paraffins: Characterization of C10–C17 chlorinated paraffins in oven-baked pastry products and unprocessed pastry…

2019

Abstract This study presents an HPLC–ESI–Q–TOF method for simultaneous quantification of short-chain chlorinated paraffins (SCCPs, C10–13) and an additional characterization of medium-chain chlorinated paraffins (MCCPs, C14–17) in oven-baked pastry products (n = 38) and unprocessed pastry dough material (n = 15). Almost 2 times higher SCCP levels were found in the dough material. ΣSCCP concentrations in products ranged from 0.3 ng g−1 to 23.0 ng g−1 (mean: 6.3 ng g−1), while the results for dough ranged from 5.8 ng g−1 to 22.8 ng g−1 (mean: 12.9 ng g−1). Regardless of the sample matrix, the most abundant CP homologue groups were hepta- and octa-chlorinated undecanes and dodecanes. The avera…

Versuche zur umsetzung von methylendiphenolen mit glucosederivaten und zur kondensation von O-phenylglucosidderivaten

1981

Attempts to apply known methods of glucosidation to oligo[(hydroxyphenylene)methylene]s were not satisfying. The reaction of 4,4'-dimethyl-2,2'-methylenediphenol (1a) with 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide gave a monoglucoside in 11% yield. A second attempt, the condensation of suitable O-phenylglucoside derivatives was unsuccessful. From a series of O-phenylglucosides (4) only 4-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyloxy)benzylbromide could be condensed with O-(4-hydroxymethylphenyl)-2,3,4,6-tetra-O-acetylglucopyranose to the corresponding diglucoside of 4,4'-oxydimethylenediphenol (7). Condensation reactions of the O-phenylglucoside 4k, to obtain an O-glucosidized poly[…