Search results for "decomposition"
showing 10 items of 766 documents
ChemInform Abstract: Facile Synthesis of Pyrazoles and Pyrroles via Thermolysis of Tetrazolo[1,5-b]pyridazines, Tetrazolo[1,5-a]pyrimidines and Tetra…
2010
Abstract A simple and high yielding preparation of pyrazoles and pyrroles is described. Thermolysis of tetrazolo[1,5- b ]pyridazines, tetrazolo[1,5- a ]pyrimidines and tetrazolo[1,5- a ]pyridines allowed easy ring contraction thus providing a facile preparation of cyanopyrazole and cyanopyrrole heterocycles. Since the cyano group is a versatile precursor of other functionalities, the reaction appears of particular interest for the construction of a variety of pyrazoles and pyrroles. The simple preparation of the starting tetrazole derivatives, the relatively mild conditions employed, and the very short reaction times make this versatile procedure of great synthetic utility and applicable bo…
Shift-Invariant Canonical Polyadic Decomposition of Complex-Valued Multi-Subject fMRI Data with a Phase Sparsity Constraint
2020
Canonical polyadic decomposition (CPD) of multi-subject complex-valued fMRI data can be used to provide spatially and temporally shared components among groups with both magnitude and phase information. However, the CPD model is not well formulated due to the large subject variability in the spatial and temporal modalities, as well as the high noise level in complex-valued fMRI data. Considering that the shift-invariant CPD can model temporal variability across subjects, we propose to further impose a phase sparsity constraint on the shared spatial maps to denoise the complex-valued components and to model the inter-subject spatial variability as well. More precisely, subject-specific time …
Information Transfer in Linear Multivariate Processes Assessed through Penalized Regression Techniques: Validation and Application to Physiological N…
2020
The framework of information dynamics allows the dissection of the information processed in a network of multiple interacting dynamical systems into meaningful elements of computation that quantify the information generated in a target system, stored in it, transferred to it from one or more source systems, and modified in a synergistic or redundant way. The concepts of information transfer and modification have been recently formulated in the context of linear parametric modeling of vector stochastic processes, linking them to the notion of Granger causality and providing efficient tools for their computation based on the state&ndash
A TOPOLOGICAL STUDY OF PLANAR VECTOR FIELD SINGULARITIES A tribute to Ivar Bendixson
2019
In this paper one extends results of Bendixson [B] and Dumortier [D] about the germs of vector fields with an isolated singularity at the origin of IR 2 , not accumulated by periodic orbits. As new tool, one introduces minimal curves, which are curves surrounding the origin, with a minimal number of contact points with the vector field. Moreover, the arguments are essentially topological, with no use of a desingularization theory, as it is the case in [D]. 2000 Mathematics Subject Classification : 34C05, 34A26.
Interactive evolutionary multiobjective optimization with modular physical user interface
2022
© 2022 Copyright held by the owner/author(s). Incorporating the preferences of a domain expert, a decision-maker (DM), in solving multiobjective optimization problems increased in popularity in recent years. The DM can choose to use different types of preferences depending on his/her comfort, requirements, or the problem being solved. Most papers, where preference-based and interactive algorithms have been proposed, do not pay attention to the user interfaces and input devices. If they do, they use character or graphics-based preference input methods. We propose the option of using a physical or tactile input device that gives the DM a better sense of control over providing his/her preferen…
A decomposition approach for multidimensional knapsacks with family-split penalties
2022
The optimization of Multidimensional Knapsacks with Family-Split Penalties has been introduced in the literature as a variant of the more classical Multidimensional Knapsack and Multi-Knapsack problems. This problem deals with a set of items partitioned in families, and when a single item is picked to maximize the utility, then all items in its family must be picked. Items from the same family can be assigned to different knapsacks, and in this situation split penalties are paid. This problem arises in real applications in various fields. This paper proposes a new exact and fast algorithm based on a specific Combinatorial Benders Cuts scheme. An extensive experimental campaign computational…
Geometry and quasisymmetric parametrization of Semmes spaces
2011
We consider decomposition spaces R 3 /G that are manifold factors and admit defining sequences consisting of cubes-with-handles of finite type. Metrics on R 3 /G constructed via modular embeddings of R 3 /G into a Euclidean space promote the controlled topology to a controlled geometry. The quasisymmetric parametrizability of the metric space R 3 /G×R m by R 3+m for any m ≥ 0 imposes quantitative topological constraints, in terms of the circulation and the growth of the cubes-with-handles, on the defining sequences for R 3 /G. We give a necessary condition and a sufficient condition for the existence of such a parametrization. The necessary condition answers negatively a question of Heinone…
Semi-terminal continua in homogeneous spaces
2016
A semi-terminal continuum Y in a space X is defined by the condition that no two disjoint subcontinua of X intersect both Y and X-Y. Though numerous obvious examples of such continua can be found in arcs, trees and tree-like continua, these examples are related to the non-homogeneity of the space, and having semi-terminal continua in a homogeneous continuum is counter-intuitive. Recently, a large collection of homogeneous spaces with semi-terminal, non-terminal subcontinua has been found. This paper is devoted to studying these spaces and the general structure of homogeneous continua related to the presence of semi-terminal subcontinua.
On approaches for solving computationally expensive multiobjective optimization problems
2016
In this thesis, we consider solving computationally expensive multiobjective optimization problems that take into account the preferences of a decision maker (DM). The aim is to support the DM in identifying the most preferred solution for problems that have several conflicting objectives and when the evaluation of the candidate solutions is time consuming. This is conducted by replacing computationally expensive functions with computationally inexpensive functions, known as surrogates. First, based on a literature survey, we introduce two frameworks, i.e., a sequential and an adaptive framework, based on which surrogate-based methods are classified and compared. We then identify relevant cha…
A new copper(II) chelate complex with polyamines as fire retardant and epoxy hardener: Synthesis, crystal and electronic structure, and thermal behav…
2020
A new (ethylenediamine-N,N′)-(diethylenetriamine-N,N′,N″)-copper(II) hexafluoridosilicate complex, [Cu(eda)(deta)]SiF6 (1) (eda – ethylenediamine; deta – diethylenetriamine), was synthesized by direct interaction of anhydrous CuSiF6 with polyethylenepolyamine (pepa – H2N[C2H4NH]nH, where n = 1 (eda) and 2 (deta)). The crystals of 1 were characterized by IR spectroscopy and X-ray diffraction. Compound 1 consists of SiF62− discrete anions and [Cu(eda)(deta)]2+ complex cations whose Cu2+ ions are chelated by eda and deta. The coordination polyhedron of Cu(II) atom is an elongated square pyramid which consists of four nitrogen atoms belonging to NH2 groups of eda and NH2 and NH groups of …