Search results for "decoupling"
showing 10 items of 87 documents
ChemInform Abstract: The Reaction of Aromatic α,β-Unsaturated Ketones with 4,5- Diamino-1,6-dihydropyrimidin-6-ones.
2010
The reaction of 4,5-diamino-1,6-dihydropyrimidin-6-ones 1 with one equivalent of the chalcones 2 leads in an acidic medium to the formation of the 2,4-diaryl-2,3,6,7-tetrahydro-1H-pyrimido[4,5-b][1,4]diazepin-6-ones 3a-m. The structure elucidation of the products is based on detailed nmr investigations including selective 13C[1H] decoupling experiments.
Conditions for waveguide decoupling in square-lattice photonic crystals
2004
We study coupling and decoupling of parallel waveguides in two-dimensional square-lattice photonic crystals. We show that the waveguide coupling is prohibited at some wavelengths when there is an odd number of rows between the waveguides. In contrast, decoupling does not take place when there is even number of rows between the waveguides. Decoupling can be used to avoid cross talk between adjacent waveguides.
Guaranteed and computable error bounds for approximations constructed by an iterative decoupling of the Biot problem
2021
The paper is concerned with guaranteed a posteriori error estimates for a class of evolutionary problems related to poroelastic media governed by the quasi-static linear Biot equations. The system is decoupled by employing the fixed-stress split scheme, which leads to an iteratively solved semi-discrete system. The error bounds are derived by combining a posteriori estimates for contractive mappings with functional type error control for elliptic partial differential equations. The estimates are applicable to any approximation in the admissible functional space and are independent of the discretization method. They are fully computable, do not contain mesh-dependent constants, and provide r…
Dynamical decoupling efficiency versus quantum non-Markovianity
2015
We investigate the relationship between non-Markovianity and the effectiveness of a dynamical decoupling protocol for qubits undergoing pure dephasing. We consider an exact model in which dephasing arises due to a bosonic environment with a spectral density of the Ohmic class. This is parametrised by an Ohmicity parameter by changing which we can model both Markovian and non-Markovian environments. Interestingly, we find that engineering a non-Markovian environment is detrimental to the efficiency of the dynamical decoupling scheme, leading to a worse coherence preservation. We show that each dynamical decoupling pulse reverses the flow of quantum information and, on this basis, we investig…
Preserving entanglement and nonlocality in solid-state qubits by dynamical decoupling
2014
In this paper we study how to preserve entanglement and nonlocality under dephasing produced by classical noise with large low-frequency components, as $1/f$ noise, by Dynamical Decoupling techniques. We first show that quantifiers of entanglement and nonlocality satisfy a closed relation valid for two independent qubits locally coupled to a generic environment under pure dephasing and starting from a general class of initial states. This result allows to assess the efficiency of pulse-based dynamical decoupling for protecting nonlocal quantum correlations between two qubits subject to pure-dephasing local random telegraph and $1/f$-noise. We investigate the efficiency of an "entanglement m…
One Rule to Rule Them All? Organisational Sensemaking of Corporate Responsibility
2015
Corporate responsibility (CR) has often been criticised as a decoupled organisational phenomenon: a publicly espoused rule that is not followed in daily organisational practices. We argue that a crucial reason for this criticism arises from the dominant in-house assumption of CR literature, which mitigates tensions and contradictions in organisational life by claiming that integrated rules result in coupled practices. We aim to provide new insights by problematising this in-house assumption and by examining how members of two organisations discursively make sense of CR, as a daily rule-bound practice, via three strategies: integration, differentiation and fragmentation. We elaborate the con…
Trends and cycles in CO2 emissions and incomes: Cross-country evidence on decoupling
2022
This paper provides cross-country evidence on the relationship between growth in CO2 emissions and real GDP growth from 1960 to 2018. The focus is on distinguishing longer-run trends in this relationship from short-run cyclical fluctuations, and on documenting changes in these relationships over time. Using two filtering techniques for separating trend and cycle, we find that long-run trends show evidence of decoupling in richer nations—particularly in European countries—but not yet in developing economies, and that there is stronger evidence of decoupling over the 1990 to 2018 sub-period than over the earlier 1960 to 1989 sub-period. There is also a strong cyclical relationship between emi…
Applications of the Fault Decoupling Device to Improve the Operation of LV Distribution Networks
2008
The aim of this paper is to present the operating principle of a new resonant device, called the fault decoupling device (FDD), able to improve power quality in electrical distribution systems. In low-voltage networks, this device can be employed in order to mitigate voltage dips due to faults or large induction motor startup. Moreover, in the presence of distributed-generation (DG) units, the FDD allows one to obtain various benefits such as a reduction of the fault current in each node of the network and an increase in the voltage at the DG unit node. In order to show the performances of the FDD, analytical studies and computer simulations were carried out which took into account various …
Trace element fractionation through halite crystallisation: Geochemical mechanisms and environmental implications
2019
Halite is an important mineral for industry, agriculture and food production. It crystallises after water evaporation, while the progressive growth of dissolved metal ions in brines is occurring. Then, halite exploitation may provide the delivery of metal ions in the environment and the mechanism of this trace element accumulation should be studied. In this work we investigate the distribution of lanthanides and Y (hereafter named Rare Earth Elements, REE), Zr and Hf between crystallising halite and brines in the Dead Sea as geochemical tools for recognising the mechanism of metal ion removal from brines and accumulation in halite. Halite forms cubic crystals where octahedral planes sometim…
Elastic Wave Near-Cloaking
2020
Cloaking elastic waves has, in contrast to the cloaking of electromagnetic waves, remained a fundamental challenge: the latter successfully uses the invariance of Maxwell's equations, from which the field of transformational optics has emerged, whereas the elastic Navier equations are not invariant under coordinate transformations. Our aim is to overcome this challenge, at least in practical terms, and thereby unlock applications in mechanics, ultrasound, vibration mitigation, non-destructive evaluation and elastic wave control. We achieve near-cloaking by recognising that, despite the lack of invariance, a decoupling into a system of form invariant potential equations together with a quant…