Search results for "defect"

showing 10 items of 879 documents

Magnetic Disaccommodation in Manganese Ferrites in the Temperature Region IV

1991

The magnetic relaxation in polycrystalline, nonstoichiometric manganese ferrite samples MnxFe3−xO4 is investigated as a function of the Mn content (0 ≦ x ≦ 1). The analysis of the experimental results shows that in the temperature region IV two different relaxation processes at 285 (IV) and 220 K (IVa) can be distinguished. The process IV exhibits orientational relaxation characteristics and is composed by the superposition of two Debye processes with activation energies close to 0.75 and 0.80 eV whereas relaxation IV a could be associated with vacancy migration through the lattice, but future investigations are necessary to probe this. Es wird die magnetische Relaxation in polykristallinen…

chemistry.chemical_classificationChemistrychemistry.chemical_elementManganese ferriteActivation energyManganeseCondensed Matter PhysicsElectronic Optical and Magnetic MaterialsCrystallographyNuclear magnetic resonanceVacancy defectMagnetic relaxationCrystalliteInorganic compoundSolid solutionPhysica Status Solidi (a)
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Glucose 6-phosphate dehydrogenase Palermo R257M: a novel variant associated with chronic non-spherocytic haemolytic anaemia

2010

chemistry.chemical_classificationHemolytic anemiahaemolytic anaemianew DNA mutationEnzyme defectHematologyhereditary genetic defectBiologymedicine.diseaseMicrobiologychemistry.chemical_compoundSettore MED/38 - Pediatria Generale E SpecialisticaEnzymeBiochemistrychemistryenzyme defectmedicineChronic non-spherocytic haemolytic anaemiaGlucose-6-phosphate dehydrogenaseSpherocytic anemiaG6PDBritish Journal of Haematology
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Ordering, phase behavior, and correlations of semiflexible polymers in confinement.

2021

Semiflexible polymers are ubiquitous in biological systems, e.g., as building blocks of the cytoskeleton, and they also play an important role in various materials due to their ability to form liquid-crystalline order. These rigid macromolecules are characterized by numerous (hierarchical) length-scales that define their static and dynamic properties. Confinement can promote uniform order, e.g., through capillary nematization in narrow slits, but it can also introduce long-ranged disruptions of the nematic ordering field through (unavoidable) topological defects in spherical containers. This Perspective concentrates on the theoretical description and computational modeling of such confined …

chemistry.chemical_classificationModels MolecularMaterials science010304 chemical physicsField (physics)PolymersGeneral Physics and AstronomyPolymer010402 general chemistry01 natural sciences0104 chemical sciencesTopological defectOrder (biology)chemistryLiquid crystalChemical physicsPhase (matter)0103 physical sciencesPhysical and Theoretical ChemistryMechanical PhenomenaThe Journal of chemical physics
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Diffusional Relaxation in Dimer Deposition

1992

In deposition of dimers on a 1D lattice substrate, we find by analytical arguments, supported by numerical Monte Carlo simulations, that the effect of added diffusional relaxation is to allow the full, saturation coverage, 100%, for large times. This limiting coverage is approached according to the ~ 1/√t power law preceded, for fast diffusion, by the mean-field crossover regime with the intermediate ~ 1/t behavior.

chemistry.chemical_compoundMaterials scienceAdsorptionchemistryVacancy defectLattice (order)DimerMonte Carlo methodKineticsGeneral Physics and AstronomyThermodynamicsLimitingPower lawEurophysics Letters (EPL)
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Defects in oxide glasses

2005

An insight into the present understanding of point defects in the simplest and the most radiation-resistant oxide glass, glassy silicon dioxide (silica) is presented. The defects and their generation processes in glassy and α-quartz forms of silicon dioxide are significantly different. The only defect, confirmed to be similar in both materials, is oxygen vacancy. In silica, additional defects of dangling bond type are generated from precursor sites formed by strained Si-O bonds, and by modifier ions. The optical absorption spectra of silica are dominated by paramagnetic dangling bond type defects: silicon dangling bond (“E′-center”) and oxygen dangling bond (“non-bridging oxygen hole center…

chemistry.chemical_compoundMaterials scienceSiliconchemistrySilicon dioxideRadicalVacancy defectDangling bondOxideMoleculechemistry.chemical_elementPhotochemistryCrystallographic defectphysica status solidi (c)
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Optical properties of lithium niobate single crystals

2005

Studies of thermal and γ-irradiation effects on the optical properties in congruous lithium niobate single crystals containing Y, Mg, Gd, B, and Zn dopants including samples with double dopants Y, Mg and Gd, Mg are reported. Formation of defects at irradiation and thermal treatment of the samples is explored by electron absorption spectra. Considerable increase of absorption with the dose of γ-radiation is observed at 500 nm. The changes of absorption examined under different conditions are explained by creation and destruction of Nb 4 + defects.

chemistry.chemical_compoundMaterials sciencechemistryAbsorption spectroscopyDopantLithium niobateAnalytical chemistryMineralogyIrradiationThermal treatmentAtmospheric temperature rangeAbsorption (electromagnetic radiation)Crystallographic defectphysica status solidi (c)
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The Effects of Admixtures on Resistance to Radiation of Lithium Niobate Crystals

2015

The studies of optical absorption and transmission of crystalline lithium niobate compounds modified by rare-earth and alkali-earth elements: LiNbO3: Y (0.46 wt %), LiNbO3: Y (0.32 wt %), Mg (0.24 wt %), LiNbO3: Mg (0.27 wt %), LiNbO3: Gd (0.004, 0.04, 0.26, and 0.43 wt %), and ostensibly pure LiNbO3 is reported. The features of absorption and transmission are examined with respect to the dosage of γ-irradiation, the annealing temperature, and the type and concentration of modifying admixtures. The features revealed in different ways of bleaching γ-irradiated and annealed in vacuum ostensibly pure lithium niobate crystals are used to refine the mechanisms of developing electron and point de…

chemistry.chemical_compoundMaterials sciencechemistryAnnealing (metallurgy)Lithium niobateAnalytical chemistryElectronRadiationCondensed Matter Physicsγ irradiationOn resistanceCrystallographic defectElectronic Optical and Magnetic MaterialsFerroelectrics
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Low-lying Rydberg states of HCl.

2008

Vertical excitation energies belonging to some different Rydberg series of hydrogen chloride have been determined with a coupled-cluster theoretical approach. These excitation energies have allowed us to calculate electric dipole transition intensities in HCl and allow additional assessment of the calculation approach presently used to provide an adequate description of the valence and Rydberg states of HCl. The molecular quantum defect orbital has been applied to the calculation of oscillator strengths. In particular, new insight is given on the assignment of states as the R1Pi, the 1Delta(4dpi and 5ppi), the 1Sigma+(4dpi), and the nddelta(1Pi, 1Phi) and 4f states.

chemistry.chemical_compoundQuantum defectsymbols.namesakeValence (chemistry)chemistryRydberg atomRydberg formulasymbolsPhysical and Theoretical ChemistryElectric dipole transitionAtomic physicsHydrogen chlorideExcitationThe journal of physical chemistry. A
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PtTe2: Potential new material for the growth of defect-free TeO2 single crystals

2008

Abstract The dissociation of Te–O bonds is the main drawback, which hampers the yield of large-sized paratellurite single crystals of high optical quality when using platinum crucibles. In this work, it is assumed that a catalytic dissociation process involves the intermediate formation of platinum tellurides, these ones being then responsible for entrapment of gas bubbles and black precipitates when growth proceeds. To alleviate this difficulty, we suggest that platinum ditelluride could be a chemically more appropriate compound instead of pure platinum. First experiments on direct transformation of platinum sheets into PtTe 2 under tellurium gas atmosphere are described, as well as the pr…

chemistry.chemical_elementDefect freeCondensed Matter PhysicsCrystallographic defectDissociation (chemistry)CatalysisInorganic ChemistryCrystallographychemistryMaterials ChemistryTellurium oxideTelluriumPlatinumSingle crystalJournal of Crystal Growth
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Guardia y custodia compartida impuesta

2018

Cuando una pareja con hijos comunes menores de edad deja de convivir surge la necesidad de determinar las reglas o normas por las que se regirá la nueva situación familiar. Estas normas pueden ser de carácter económico o personal. Entre las personales, y una sobre las que más les cuesta decidir a los progenitores, es la relativa al cuidado de los hijos y a cómo se va a dar continuidad a las relaciones con ellos una vez se haya producido la separación. Lo mejor sería que los propios progenitores pudieran llegar a un acuerdo al respecto ya que ellos son los que mejor conocen a sus hijos y los mejores conocedores de la situación que están viniendo. Pero en defecto de acuerdo será necesario det…

child?s interest. 418 437:CIENCIAS JURÍDICAS [UNESCO]2386-4567 22661 Actualidad jurídica iberoamericana 502169 2018 9 6653334 Guardia y custodia compartida impuesta Morera Villary una sobre las que más les cuesta decidir a los progenitoresParental authoritypor el contrarioBeatriz Cuando una pareja con hijos comunes menores de edad deja de convivir surge la necesidad de determinar las reglas o normas por las que se regirá la nueva situación familiar. Estas normas pueden ser de carácter económico o personal. Entre las personalespodrá adoptar la medida que considere mejor salvaguarda el interés superior de los menores. Patria potestadUNESCO::CIENCIAS JURÍDICASes la relativa al cuidado de los hijos y a cómo se va a dar continuidad a las relaciones con ellos una vez se haya producido la separación. Lo mejor sería que los propios progenitores pudieran llegar a un acuerdo al respecto ya que ellos son los que mejor conocen a sus hijos y los mejores conocedores de la situación que están viniendo. Pero en defecto de acuerdo será necesario determinar si es necesario que el Juez adopte alguna de las medidas solicitadas por los progenitores ointerés del menor.guarda y custodia compartidajoint custody
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