Search results for "demonstrator"
showing 4 items of 4 documents
Design, construction and operational results of a pilot plant for the treatment and valorization of pickling waste solutions
2021
An innovative hybrid technology for both minimizing the waste production and optimizing the pickling process through the continuous control of pickling baths composition has been proposed by means of a pilot-plant installed at the Tecnozinco Srl, Carini (PA) hot-dip galvanizing plant. The recovery process has been accomplished by coupling a diffusion dialysis (DD), where HCl is recovered, a membrane distillation (MD), where HCl is concentrated, and a reactive precipitation (RP), where metal ions are recovered as iron hydroxide and ammonium/zinc chloride solution, to be used in the fluxing baths of the plant. The pilot plant was commissioned and operated using synthetic HCl solutions first a…
An integrated approach for the HCl and metals recovery from waste pickling solutions: pilot plant and design operations
2021
Abstract Continuous regeneration of industrial pickling solutions and recovery of valuable materials are implemented in a pilot-scale plant including diffusion dialysis (DD), where HCl is recovered, membrane distillation (MD), where HCl is concentrated, and reactive precipitation (CSTR), where metal ions are recovered in different forms. The integration of the three processes allows to minimize waste streams generation and to accomplish a closed-loop process, thus increasing the environmental sustainability and economic impact of the galvanizing industry. Process reliability was proved through the operation of a demonstrator in the real industrial environment of the Tecnozinco SrL hot-dip g…
AN INTEGRATED APPROACH FOR THE HCl AND METALS RECOVERY FROM WASTE PICKLING SOLUTIONS: PILOT PLANT DESIGN AND OPERATIONS
2020
Pickling is one of the key steps in the hot-dip galvanizing process, where HCl solutions are largely used to remove metal oxides from metallic surfaces, thus generating spent waste liquors containing high concentrations of metals and acid. Disposal of the industrial pickling waste dramatically affects the hot-dip galvanizing industry economics and environmental footprint. Thus, reducing strong acid waste disposal is one of the most beneficial steps to enhance the process sustainability. Moreover, the continuous regeneration of pickling solutions enhances pickling rate and process performance, also minimizing industrial wastewater disposal and chemicals consumption promoting the circular use…
DEVELOPMENT AND MODELING OF MEMBRANE PROCESSES FOR THE REGENERATION OF ACID PICKLING SOLUTIONS
2021
The doctoral thesis focuses on a novel integrated process for the recovery and valorisation of acid and metal salts present in the waste solutions of the pickling process. The proposed process is based on the integration of two innovative membrane technologies, the Diffusion Dialysis and the Membrane Distillation, coupled with a reactive precipitation section. This hybrid process allows the recovery and the enhancement of waste solutions, as well as optimal operating conditions for the continuous pickling process, thus improving its efficiency. Hydrochloric acid recovery was assessed through a detailed study on the Diffusion Dialysis process by implementing a wide experimental campaign usin…