Search results for "diagenesis."
showing 10 items of 113 documents
Microbially-induced Fe and Mn oxides in condensed pelagic sediments (Middle -Upper Jurassic, Western Sicily)
2011
Abstract This article presents a petrographic comparison of the Rosso Ammonitico facies of Western Sicily and the original Rosso Ammonitico Veronese of Northern Italy based on a total of 27 sections. The Rosso Ammonitico has been the subject of numerous controversies that range from bathyal to shallow-water platform sedimentation. Therefore it seemed interesting to verify if the term Rosso Ammonitico has the same geologic connotation from region to region. The Middle-Upper Jurassic Rosso Ammonitico of Western Sicily is a condensed succession formed during a period of extensional synsedimentary tectonics related to the spreading of the Ionian Ocean. Slope-to-basin or pelagic carbonate deposi…
Geochemistry and mineralogy of travertine deposits of the SW flank of Mt. Etna (Italy): Relationships with past volcanic and degassing activity
2007
Abstract Travertine deposits outcropping in the lower SW flank of Mt. Etna were studied for their mapping, as well as for their chemical, mineralogical and isotopic compositions. These deposits are dated to about 24 to 5 ka in the Adrano area, located at the western limit of the study area. In this area travertines show high Mg contents and are composed mostly of dolomite, thus apparently ruling out any primary deposition in favour of a diagenetic origin. Travertines outcropping near Paterno, in the east part of the study area, should be younger than 18 ka. Those located to the SSW of Paterno (Paterno–Diga) show high Sr contents and aragonite as dominant mineralogical phase, thus suggesting…
The origin and timing of multiphase cementation in carbonates: Impact of regional scale geodynamic events on the Middle Jurassic Limestones diagenesi…
2009
The Middle Jurassic carbonates of the eastern part of the Paris Basin display surprisingly low values of porosity and permeability (Φ < 15‰ and K < 0.5 mD). The main objective of this study is to determine the causes and timing of the cementation that altered the petrophysical properties of these carbonates thereby destroying their potential as oil reservoirs; a fate that did not befall their equivalents in deeper, central parts of the Paris Basin. Using petrographic and geochemical analyses (stable O and C isotopes, Sr isotopes, major elements), we identify six calcitic spar stages, two dolomite stages, and several episodes of fracturing and stylolitization ordered in paragenetic sequence.…
Carbon-isotope record and palaeoenvironmental changes during the early Toarcian oceanic anoxic event in shallow-marine carbonates of the Adriatic Car…
2013
AbstractGeochemical (δ13C, δ18O and Mn) compositions of Lower Jurassic shallow-water carbonates cropping out in Croatia were analyzed to elucidate the impact of the early Toarcian oceanic anoxic event (T-OAE) on the Adriatic Carbonate Platform (AdCP). The bulk-rock carbon-isotope records through the studied sections (Velebit-A, Velebit-B and Gornje Jelenje) are characterized by two significant excursions: (i) an initial positive trend interrupted by a pronounced negative shift (c. 2.5‰) that is followed by (ii) an increasing trend of positive values (up to 4.5‰). A comparison with δ13C trends obtained from well-calibrated sections from other localities in Europe shows that the overall chara…
Characterization and origin of permeability-porosity heterogeneity in shallow-marine carbonates: from core scale to 3D reservoir dimension (Middle Ju…
2014
21 pages; International audience; Nuclear magnetic resonance (NMR), stable isotope geochemistry of micro-sampled cores, NMR well-logs and 3D modeling are used to investigate the carbonate permeability-porosity heterogeneity along 230 m-thick limestones of the Paris Basin. Despite the global low porosity and permeability of the limestones, two aquifers units with porosity greater than 15% were identified. These two aquifers are very different in terms of pore through radii and NMR signal. The first one (A1: Aquifer 1) is a 7 m-thick mudstone unit, dominated by extended microporosity with pore throat radii of 0.25 μm to 0.3 μm. The second one (A2: Aquifer 2) is a 15 m-thick oolitic grainstone…
Diagénesis, análisis de procedencia y ambiente tectónico de rocas siliciclásticas. Un caso de estudio en el Devónico Superior de la Cordillera Ibéric…
2022
This paper describes the petrography and infers the provenance of siliciclastic rocks from the Upper Devonian of the Iberian Chains (Tabuenca, NE Spain), and outlines the tectonic setting associated with the Ebro Massif. These Devonian deposits are constituted by four different siliciclastic units: the Rodanas, Bolloncillos, Hoya and Huechaseca Formations. The provenance and diagenesis of over 400 sedimentary rocks samples are studied with a combination of petrographic polarizing microscope, scanning electron microscopy, atomic absorption spectroscopy, X-ray fluorescence and X-ray diffraction. In this sense, AAS and XRF analysis were used to determine the content of Ca, Mg, Fe, Mn, Na, K an…
Discovery of Ca oxalate crystals associated with fungi in moss travertines (Bryoherms, freshwater heterogeneous stromatolites)
1995
Buffered decalcification of live moss and liverwort (Hepaticae) travertines resulted in the release of a large number of organisms (bacteria, cyanobacteria, fungi, eukaryotic algae, and small animals), which constitute an “organic mat”; (also called an algal mat or biofilm). This mat is calcified and commonly has laminations, allowing moss travertines to be considered as stromatolitic structures. After decalcification of 300 samples of travertines (using dilute acetic acid), only 9 released Ca oxalate crystals in the form of needle bundles, spherulites, and tetragonal bipyramidal prisms. These crystalline forms are identical to those found in some phanerophytes and soils. Mycelian filaments…
Hydro-mechanical behaviour of shallow Opalinus Clay shale
2019
In Switzerland, Opalinus Clay shale has been selected as the host formation for radioactive waste disposal. The minimum required depth of the repository is related to the long-lasting isolation required for the disposal (1 million years). During this period, possible erosion scenarios affecting the repository need to be analysed. Opalinus Clay from shallow depths (< 70 m) was sourced from a borehole in Northern Switzerland, where the formation was affected by a considerable exhumation process. This work aims to investigate the impact of the mentioned phenomenon on the hydro-mechanical behaviour of Opalinus Clay through one-dimensional consolidation and permeability measurements. Laboratory …
The natural hydrous sodium silicates from the northern bank of Lake Chad : occurrence, petrology and genesis
2005
Abstract Hydrous sodium silicates sometimes associated with zeolites, form in an alkaline environment, in which there is a high concentration of dissolved silica. Such an environment existed during the Holocene in N'Guigmi interdunal depressions (Lake Chad), which led to the precipitation of various types of hydrous sodium silicates, including magadiite, kenyaite, and zeolites. Scanning electron and optical microscope observations allow several microstructures to be distinguished. These microstructures result from either precipitation sequences or a transformation along a diagenetic gradient. New petrological, microstructural and geochemical data confirm the transformation of magadiite into…
Discrepancies between archaeological and 14C-based chronologies: problems and possible solutions
2018
14C dating of bone collagen is believed to produce the most reliable absolute dates for the Central European Early Neolithic, as the selection of bones in anatomical context minimises taphonomic problems. In contrast, a comparison of three newly published local or regional chronological models as well as a comparison of several series of dates from bone collagen, charcoal and cereals highlights problems probably caused by diagenetic influences, especially on collagen. Therefore, at least the checking of bone collagen 14C dates against charcoal or cereal dates from the same contexts seems to be indispensable.