Search results for "dienes"

showing 10 items of 170 documents

Mass Output and Particle Size Distribution of Glucocorticosteroids Emitted from Different Inhalation Devices Depending on Various Inspiratory Paramet…

2002

Efficient inhalation therapy depends on successful delivery of the drug to the lung. The efficacy of drug delivery is not only influenced by the characteristics of the inhalation device, but also by the patient's handling of the device and by the inspiratory maneuver achieved through the device. We analyzed the output characteristics of three different chlorofluorocarbon (CFC)-free breath-actuated inhalers for inhaled glucocorticosteroids (BUD Turbohaler, FP Diskus/Accuhaler and HFA-BDP Autohaler, respectively). Mass output and particle size distribution of drug aerosol delivered by the inhalers were determined depending on different inhalation parameters in vitro using an Andersen cascade …

AdultPulmonary and Respiratory MedicineAnti-Inflammatory AgentsPulmonary Disease Chronic Obstructivechemistry.chemical_compoundAdministration InhalationHumansPharmacology (medical)Particle SizeBudesonideChildPeak flow meterLungmeasurement_unitAerosolsChlorofluorocarbonInhalationNebulizers and VaporizersInhalerBeclomethasoneAsthmaAerosolAndrostadienesInhalationchemistryVolume (thermodynamics)Anesthesiameasurement_unit.measuring_instrumentRespiratory MechanicsFluticasoneParticleParticle sizeBiomedical engineeringJournal of Aerosol Medicine
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Activation of c-Jun N-terminal kinase 1 by UV irradiation is inhibited by wortmannin without affecting c-iun expression.

1999

Activation of c-Jun N-terminal kinases (JNKs)/stress-activated protein kinases is an early response of cells upon exposure to DNA-damaging agents. JNK-mediated phosphorylation of c-Jun is currently understood to stimulate the transactivating potency of AP-1 (e.g., c-Jun/c-Fos; c-Jun/ATF-2), thereby increasing the expression of AP-1 target genes. Here we show that stimulation of JNK1 activity is not a general early response of cells exposed to genotoxic agents. Treatment of NIH 3T3 cells with UV light (UV-C) as well as with methyl methanesulfonate (MMS) caused activation of JNK1 and an increase in c-Jun protein and AP-1 binding activity, whereas antineoplastic drugs such as mafosfamide, mito…

Alkylating AgentsProto-Oncogene Proteins c-junUltraviolet RaysStimulationBiologyenvironment and public healthWortmanninTransactivationchemistry.chemical_compoundMiceAnimalsPhosphatidylinositolCollagenasesProtein kinase AMolecular BiologyCell Growth and DevelopmentMitogen-Activated Protein Kinase 1Kinasec-junJNK Mitogen-Activated Protein KinasesCell Biology3T3 CellsMethyl MethanesulfonateMolecular biologyAndrostadienesEnzyme ActivationGene Expression Regulation NeoplasticTranscription Factor AP-1chemistryCalcium-Calmodulin-Dependent Protein KinasesPhosphorylationMitogen-Activated Protein KinasesWortmanninMolecular and cellular biology
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Effects of in vitro treatment with fluticasone propionate on natural killer and lymphokine-induced killer activity in asthmatic and healthy individua…

2001

Background: Topical corticosteroids are beneficial in the treatment of allergic respiratory disorders; they exert effects on a number of cells involved in allergic inflammatory reactions. On the other hand, major histocompatibility complex (MHC)-unrestricted cytotoxicity (i.e., natural killer [NK] cell activity) may play a role in the inflammatory allergic reaction. The objective was to gain insight into the mechanisms of the therapeutic effects of fluticasone propionate (FP), an inhaled corticosteroid used in asthma and rhinitis therapy. Therefore, we evaluated the NK and lymphokine-activated killer (LAK) activity of effector cells in vitro treated or not with FP. Methods: Evaluations were…

AllergyLymphocyteImmunologychemical and pharmacologic phenomenaFluticasone propionateNatural killer cellInterferonmedicineImmunology and AllergyHumansAnti-Asthmatic AgentsKiller Cells Lymphokine-ActivatedFluticasonebusiness.industryLymphokineInterleukinInterferon-alphamedicine.diseaseAsthmaAndrostadienesKiller Cells Naturalmedicine.anatomical_structureImmunologyFluticasonebusinessmedicine.drugAllergy
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Nacionālisma un militarizācijas izpausmes zemessardzes jaunajos bataljonos

2017

Latvijas nacionālo bruņoto spēku papildspēku grupa “Zemessardze” kopš tās atjoaunošanas 1991.gadā ir pieredzējusi brīvprātīgo plūsmas svārstības. Pēdējo trīs gadu laikā, sākot ar 2014. gadu, ir novērojams straujš kāpums gan jauno karavīru, gan bataljonu skaitā. Krasais kāpums, kas vēl nav sācis norimt un zemessargu pieaugošā klātbūtne sociālo mēdiju tīkolos, kopā ar ikgadējo budžeta pieaugumu nacionālās drošības nozarē, norāda uz centieniem normalizēt militārismu. Balstoties uz daļēji strukturētām intervijām, pētījums iepazīstina zemessargu pašu skatījumu un interpretāciju par viņu būtību, viņu atbildību un lomu sabiedrībā. Pētījums arī apskata dažādos transformāciju procesus, ko ietekmē br…

Brīvprātīgais militārais dienestsAntropoloģijaNacionālā identitāteMilitarizācijaNacionālisms
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3H-estradiol and3H-R5020 binding in cytosols of normal and neoplastic human ovarian tissue

1983

High-affinity cytoplasmic estrogen and progesterone receptors in normal and abnormal ovarian tissues were studied. Estradiol receptor was detectable in 65% and progesterone receptor in 36% of the malignant tumors; 39% of all malignant ovarian tissues were estradiol- as well as progesterone-receptor-positive. Tumors were said to be receptor-positive when the receptors bound greater than 5 fM steroid/mg cytosol protein. No correlations were found between receptor status and histopathological diagnosis. In normal ovarian tissues collected at various phases of the menstrual cycle no changes in [3H]-estradiol and [3H]-R5020 binding could be detected. Analysis of the receptor concentration for bo…

Cancer Researchmedicine.medical_specialtyReceptor StatusNorpregnadienesmedicine.drug_classmedia_common.quotation_subjectOvaryReceptors EstradiolBiologyTritiumPromegestoneCytosolOvarian carcinomaInternal medicineProgesterone receptormedicineHumansEstrogen Receptor StatusMenstrual cyclemedia_commonOvarian NeoplasmsTranscortinEstradiolOvaryEndocrinologymedicine.anatomical_structureReceptors EstrogenOncologyEstrogenFemaleReceptors Progesteronehormones hormone substitutes and hormone antagonistsTamoxifenmedicine.drugInternational Journal of Cancer
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Aspidin PB, a phloroglucinol derivative, induces apoptosis in human hepatocarcinoma HepG2 cells by modulating PI3K/Akt/GSK3β pathway.

2012

Aspidin PB, a phloroglucinol derivative isolated from Dryopteris fragrans (L.) Schott, has been previously reported to exert high biological activities. In the present study, we analyzed the apoptotic mechanisms of aspidin PB on human hepatoma cell line, HepG2. Initially, aspidin PB was shown to inhibit the growth of HepG2 cells in a time and dose-dependent manner. After treatment with aspidin PB for 72 h, 48 h and 24 h using MTT assay, the IC(50) values were 10.59 μM, 20.86 μM and 46.59 μM, respectively. Aspidin PB was capable to induce apoptosis, as measured by mitochondrial membrane potential (ΔΨm), acridine orange (AO) staining and propidium iodide (PI)/annexin V-FITC double staining. T…

Carcinoma HepatocellularApoptosisBiologyPhloroglucinolToxicologyWortmanninchemistry.chemical_compoundGlycogen Synthase Kinase 3Phosphatidylinositol 3-KinasesAnnexinHumansMTT assayPropidium iodideProtein kinase BProtein Kinase InhibitorsPI3K/AKT/mTOR pathwayCell ProliferationPhosphoinositide-3 Kinase InhibitorsMembrane Potential MitochondrialGlycogen Synthase Kinase 3 betaMicroscopy ConfocalAcridine orangeLiver NeoplasmsGeneral MedicineHep G2 CellsFlow CytometryMolecular biologyAndrostadieneschemistryApoptosisWortmanninProto-Oncogene Proteins c-aktSignal TransductionChemico-biological interactions
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1,3-Dipolar cycloaddition of diaryldiazomethanes across N-ethoxy-carbonyl-N-(2,2,2-trichloroethylidene)amine and reactivity of the resulting 2-azabut…

2016

Abstract 1,3-dipolar cycloaddition of diaryldiazomethanes Ar2C N2 across Cl3C–CH N–CO2Et 1 yields Δ3-1,2,4-triazolines 2. Thermolysis of 2 leads, via transient azomethine ylides 3, to diaryldichloroazabutadienes [Ar(Ar')C N–CH CCl2] 4. Treatment of 4a (Ar = Ar' = C6H5) and 4c (Ar = Ar' = p-ClC6H4) with NaSR in DMF yields 2-azabutadienes [Ar2C N–C(H) C(SR)2] 5. In contrast, nucleophilic attack of NaStBu on 4 affords azadienic dithioethers [Ar2C N–C(StBu) C(H)(StBu)] (7a Ar = C6H5; 7b Ar' = p-ClC6H4). The reaction of 4a with NaSEt conducted in neat EtSH produces [Ph2C N–C(H)(SEt)–CCl2H] 8, which after dehydrochloration by NaOMe and subsequent addition of NaSEt is converted to [Ph2C N–C(SEt) C…

Chemistry(all)StereochemistryGeneral Chemical Engineering124-TriazolineCrystal structure010402 general chemistry01 natural sciencesMedicinal chemistrychemistry.chemical_compoundThioetherNucleophile[CHIM]Chemical SciencesReactivity (chemistry)ThioetherCycloadditionComputingMilieux_MISCELLANEOUS2-Azabutadienes010405 organic chemistryGeneral ChemistryCycloaddition0104 chemical sciences3. Good healthchemistry13-Dipolar cycloadditionAzomethine ylidesChemical Engineering(all)Alkoxy groupPiperidineCopperMacrocyclic complexComptes Rendus Chimie
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Chlamydomonas reinhardtii in the landscape of pigments.

2004

▪ Abstract  This review focuses on the biosynthesis of pigments in the unicellular alga Chlamydomonas reinhardtii and their physiological and regulatory functions in the context of information gathered from studies of other photosynthetic organisms. C. reinhardtii is serving as an important model organism for studies of photosynthesis and the pigments associated with the photosynthetic apparatus. Despite extensive information pertaining to the biosynthetic pathways critical for making chlorophylls and carotenoids, we are just beginning to understand the control of these pathways, the coordination between pigment and apoprotein synthesis, and the interactions between the activities of these…

ChlorophyllRhodopsinNuclear geneChloroplastsved/biology.organism_classification_rank.speciesLight-Harvesting Protein ComplexesProtozoan ProteinsChlamydomonas reinhardtiiPhotosynthesisModels Biologicalchemistry.chemical_compoundHemiterpenesLycopeneBiosynthesisIsomerismPentanesBotanyGeneticsButadienesAnimalsPhotosynthesisModel organismCarotenoidPlant Proteinschemistry.chemical_classificationCell Nucleusbiologyved/biologyPigments Biologicalbiology.organism_classificationCarotenoidsChloroplastOxygenCytochrome b6f ComplexchemistryBiochemistryXanthophyllPhotoreceptor Cells InvertebrateChlamydomonas reinhardtiiAnnual review of genetics
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Valsts probācijas dienesta funkcija- izlīguma organizēšana un vadīšana kriminālprocesā ar starpnieka palīdzību

2015

Noziedzīga nodarījuma rezultātā likumpārkāpējs ir radījis kaitējumu noteiktai personai – cietušajam. Sabiedrībā valda uzskats, ka likumpārkāpēju var sodīt tikai bargs sods, bet ne vienmēr tas ir labākais risinājums. Bieži vien labs risinājums ir izlīgums, kas noslēgts starp cietušo un likumpārkāpēju. Izlīguma rezultātā likumpārkāpējs atzīst savu vainu, bet cietušais gūst gan morālu, gan finansiālu mierinājumu un atzīst, ka pēc izlīguma noslēgšanas viņam nav prasību pret likumpārkāpēju. Izlīgumā iesaistītās puses ar starpnieka palīdzību sarunu ceļā risina radušos konfliktu. Likumpārkāpējam bieži var būt pat smagāk satikt un uzklausīt cietušo klātienē, nekā izciest tiesas piespriesto sodu, tā…

CietušaisKriminālprocessStarpnieksValsts probācijas dienestsIzlīgumsJuridiskā zinātne
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Gold(I)-Catalyzed Intermolecular Cycloaddition of Allenamides with α,β-Unsaturated Hydrazones: Efficient Access to Highly Substituted Cyclobutanes

2014

α,β-Unsaturated N,N-dialkyl hydrazones undergo a mild [2 + 2] cycloaddition to allenamides when treated with a suitable gold catalyst. The method, which represents the first application of N,N-dialkyl hydrazones in gold catalysis, is compatible with a wide variety of substituents at the alkenyl moiety of the hydrazone component, proceeds with excellent levels of regio- and diastereoselectivity, and provides densely substituted cyclobutanes with good to excellent yields.

CyclobutanesLetterHydrazoneStereoisomerismBiochemistryMedicinal chemistryCatalysisCatalysisCombinatorial Chemistry TechniquesMoleculeOrganic chemistryMoietyPhysical and Theoretical ChemistryCycloadditionchemistry.chemical_classificationCycloaddition ReactionMolecular StructureOrganic ChemistryIntermolecular forceHydrazonesStereoisomerismAllenamidesCycloaddition3. Good healthAlkadienes:Investigación::23 Química [Materias]chemistryGoldCyclobutanes
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