Search results for "difunctionalization"

showing 2 items of 2 documents

Regio- and Stereoselective Chloro Sulfoximidations of Terminal Aryl Alkynes Enabled by Copper Catalysis and Visible Light

2021

Advanced synthesis & catalysis 2552-2556 (2021). doi:10.1002/adsc.202100162

copper catalysisvinyl sulfoximine660StereochemistryAryldifunctionalizationchemistry.chemical_elementGeneral Chemistryalkyne additionCoppervisible-light photoredox catalysisCatalysischemistry.chemical_compoundTerminal (electronics)chemistryddc:660StereoselectivityVisible spectrum
researchProduct

Recent Advances on the Halo- and Cyano-Trifluoromethylation of Alkenes and Alkynes

2021

Incorporation of fluorine into organic molecules is a well-established strategy in the design of advanced materials, agrochemicals, and pharmaceuticals. Among numerous modern synthetic approaches, functionalization of unsaturated bonds with simultaneous addition of trifluoromethyl group along with other substituents is currently one of the most attractive methods undergoing wide-ranging development. In this review article, we discuss the most significant contributions made in this area during the last decade (2012−2021). The reactions reviewed in this work include chloro-, bromo-, iodo-, fluoro- and cyano-trifluoromethylation of alkenes and alkynes.

difunctionalizationPharmaceutical Sciencechemistry.chemical_elementReviewAdvanced materialsalkynesAnalytical ChemistryOrganic moleculeschemistry.chemical_compoundQD241-441Unsaturated bondsDrug DiscoveryPhysical and Theoretical ChemistryTrifluoromethylalkenesTrifluoromethylationcyanotrifluoromethylationOrganic ChemistryCombinatorial chemistryhalotrifluoromethylationchemistryAlquensChemistry (miscellaneous)Fluorinesynthetic methodsMolecular MedicineQuímica orgànica
researchProduct