Search results for "ding"
showing 10 items of 16709 documents
Force Distribution Analysis of Mechanochemically Reactive Dimethylcyclobutene
2013
Internal molecular forces can guide chemical reactions, yet are not straightforwardly accessible within a quantum mechanical description of the reacting molecules. Here, we present a force-matching force distribution analysis (FM-FDA) to analyze internal forces in molecules. We simulated the ring opening of trans-3,4-dimethylcyclobutene (tDCB) with on-the-fly semiempirical molecular dynamics. The self-consistent density functional tight binding (SCC-DFTB) method accurately described the force-dependent ring-opening kinetics of tDCB, showing quantitative agreement with both experimental and computational data at higher levels. Mechanical force was applied in two different ways, namely, exter…
Multicriteria evaluation of alternatives for remote monitoring systems of municipal buildings
2014
Abstract Conservation of natural resources drives municipalities to monitor their heat, power and water consumption more accurately. The objective of this study was to evaluate different implementation possibilities for remote monitoring systems for the municipal buildings of two medium-sized municipalities, Hollola and Nastola in Southern Finland. Four different alternatives were considered: (1) a system by an external service provider, (2) a system provided by the local energy distribution company, (3) a system built by the municipalities themselves, and (4) using the current manual system but with more frequent data collection. The alternatives were evaluated in terms of multiple functio…
Multi-hop D2D Communications with Network Coding : From A Performance Perspective
2019
Multi-hop device-to-device (D2D) communications play an important role in expanding D2D coverage. In this paper, we study a relay-based and network-coding-assisted (in particular, XOR coding) multi-hop D2D communication system. In the system, toward jointly considering the impact of interference and network traffic conditions on the quality of D2D communications, various channel fading models and traffic models are investigated, and the packet loss probability of D2D links is meticulously computed using these models. With the packet loss probability of D2D links, the general closed-form expressions of end-to-end packet loss probability (E2EPLP) of the system with the presence (or absence) o…
Performance of an asymmetric and asynchronous decode-and-forward FBMC relay system
2014
End-to-end link performance of an asymmetric and asynchronous dual-hop decode-and-forward (DF) relay system built up using a causal multirate filter bank multicarrier (FBMC) technique operated under Rayleigh fading is presented. Three main performance measures namely bit error rate (BER), outage probability and channel capacity are used for this evaluation and approximate closed-form expressions for them are also made available. FBMC setup is modeled in exact form without any approximations while customizing to one of the most efficient subcarrier filter. Simulations are carried out in quasi-static multipath fading channels under symmetric, asymmetric, synchronous and asynchronous condition…
Evidence of Weak Halogen Bonding: New Insights on Itraconazole and its Succinic Acid Cocrystal
2012
Exact knowledge of the crystal structure of drugs and lead compounds plays a significant role in the fields of crystal engineering, docking, computational modeling (drug–receptor interactions), and rational design of potent drugs in pharmaceutical chemistry. The succinic acid cocrystal of the systemic antifungal drug, itraconazole, reported by Remenar et al. (J. Am. Chem. Soc.2003, 125, 8456–8457) (CSD: IKEQEU), represents one of the classical examples displaying a molecular fitting mechanism in the solid state. In this work, we disclose the X-ray single-crystal structure of the cis-itraconazole–succinic acid (2:1) cocrystal and found that it differs slightly from the previously reported st…
Similar and equal relationships? Negotiating bisexuality in an enduring relationship
2015
In the public debate in Finland, same-sex couples’ right to legal recognition is routinely defended by stressing their sameness to heterosexual couples within the discourse of romantic love. This article explores how bisexual women and their partners use these discourses. The five couple interviews were analyzed by implementing discourse analysis. The results highlight how, when taking positions within the discourse of the enduring couple relationship, the interviewees drew on the discourse of romantic love. Woman’s bisexuality disappeared easily in this talk. Although it seemed effortless at first sight, negotiations and affective tensions arose when the interviewees tried to fit their re…
Paintings as Solid Affective Scaffolds
2019
We humans continuously reshape the environment to alter, enhance, and sustain our affective lives. This two‐way modification has been discussed in recent philosophy of mind as affective scaffolding, wherein scaffolding quite literally means that our affective states are enabled and supported by environmental resources such as material objects, other people, and physical spaces. In this article, I argue that under certain conditions, paintings function as noteworthy affective scaffolds to their creators. I begin with a theoretical overview of affective niche construction and affective scaffolding. Then, based on the criteria of robustness, concreteness, and dependability, I specify a more re…
Turning Heads on the Dance Floor: Synchrony and Social Interaction Using a Silent Disco Paradigm
2023
Music and dance appear to have a social bonding effect, which some have theorized is part of their ultimate evolutionary function. Prior research has also found a social bonding effect of synchronized movement, and it is possible that interpersonal synchrony could be considered the “active ingredient” in the social bonding consequences of music or dance activity. The present study aimed to separate the effects of synchrony from other factors associated with joint experience of dancing by using a “silent disco” manipulation, in which the timing of a musical stimulus was varied within a dyad in a freestyle dance setting. Three conditions were included: synchrony, tempo-shifted (in which the …
An Atypical Case of Taravana Syndrome in a Breath-Hold Underwater Fishing Champion: A Case Report
2013
Dysbaric accidents are usually referred to compressed air-supplied diving. Nonetheless, some cases of decompression illness are known to have occurred among breath-hold (BH) divers also, and they are reported in the medical literature. A male BH diver (57 years old), underwater fishing champion, presented neurological disorders as dizziness, sensory numbness, blurred vision, and left frontoparietal pain after many dives to a 30–35 meters sea water depth with short surface intervals. Symptoms spontaneously regressed and the patient came back home. The following morning, pain and neurological impairment occurred again and the diver went by himself to the hospital where he had a generalized to…
Design of mobile phones for older adults : An empirical analysis of design guidelines and checklists for feature phones and smartphones
2017
Design guidelines and checklists are suggested as a useful tool in the development and evaluation of interface design of mobile phones for older adults. Given the intense evolution of mobile phone design, understanding how the design guidelines and checklists have taken into account the advances in mobile phone usability for older adults is important for their correct application and future development. Thus, this study explores the usability dimensions of mobile phone design for older adults and the related changes in terms of time and the type of device (feature phones vs. smartphones) based on an expert coding of the eight mobile phone design guidelines and checklists for older adults pu…