Search results for "dipole"
showing 10 items of 982 documents
The à 1Au state and the T2 potential surface of acetylene: Implications for triplet perturbations in the fluorescence spectra of the à state
1996
The cis–trans isomerization reaction on the T2 surface of acetylene and the lowest excited singlet state of acetylene, A 1Au, are investigated by ab initio electronic structure theory. We report optimized geometries, dipole moments, and harmonic vibrational frequencies of stationary points and adiabatic energy differences between them using basis sets as large as triple‐ζ plus double polarization with higher angular momentum functions, TZ(2df,2pd), and theoretical methods up to coupled‐cluster singles and doubles with a perturbative triples correction [CCSD(T)] and the equation‐of‐motion coupled‐cluster method (EOM‐CCSD). Our theoretical predictions should aid the interpretation of observat…
Entropy of transfer of n-nitroalkanes from n-octane to water at 25�C
1984
Entropy of transfer of nitromethane, nitroethane, 1-nitrobutane, 1-nitropentane, and 1-nitrohexane from n-octane to water at 25°C is calculated using an electrostatic model. The calculations indicate that the electrostatic transfer entropy depends primarily on the dipole moment and the size of the-C−NO2 group, showing a trend which is similar to that previously found for the transfer free energy of the same process.
Space charge and induced dipole relaxation in solid electrolytes
1996
The space charge relaxation and induced dipole relaxation in solid electrolytes is discussed. The di-electric responses of these relaxations gives a satisfactory fit to the universal conductivity behaviours in the frequency range from DC to infrared.
Binary neutron star mergers: a jet engine for short gamma-ray bursts
2016
We perform magnetohydrodynamic simulations in full general relativity (GRMHD) of quasi-circular, equal-mass, binary neutron stars that undergo merger. The initial stars are irrotational, $n=1$ polytropes and are magnetized. We explore two types of magnetic-field geometries: one where each star is endowed with a dipole magnetic field extending from the interior into the exterior, as in a pulsar, and the other where the dipole field is initially confined to the interior. In both cases the adopted magnetic fields are initially dynamically unimportant. The merger outcome is a hypermassive neutron star that undergoes delayed collapse to a black hole (spin parameter $a/M_{\rm BH} \sim 0.74$) imme…
Large-scale Cosmic-Ray Anisotropies above 4 EeV Measured by the Pierre Auger Observatory
2018
We present a detailed study of the large-scale anisotropies of cosmic rays with energies above 4 EeV measured using the Pierre Auger Observatory. For the energy bins [4,8] EeV and $E\geq 8$ EeV, the most significant signal is a dipolar modulation in right ascension at energies above 8 EeV, as previously reported. In this paper we further scrutinize the highest-energy bin by splitting it into three energy ranges. We find that the amplitude of the dipole increases with energy above 4 EeV. The growth can be fitted with a power law with index $\beta=0.79\pm 0.19$. The directions of the dipoles are consistent with an extragalactic origin of these anisotropies at all the energies considered. Addi…
Indications of non-conservative mass-transfer in AMXPs
2019
Context. Since the discovery of the first Accreting Millisecond X-ray Pulsar SAX J1808.4-3658 in 1998, the family of these sources kept growing on. Currently, it counts 22 members. All AMXPs are transients with usually very long quiescence periods, implying that mass accretion rate in these systems is quite low and not constant. Moreover, for at least three sources, a non-conservative evolution was also proposed. Aims. Our purpose is to study the long term averaged mass-accretion rates in all the Accreting Millisecond X-ray Pulsars discovered so far, to investigate a non-conservative mass-transfer scenario. Methods. We calculated the expected mass-transfer rate under the hypothesis of a con…
Oceanic and atmospheric linkages with short rainfall season intraseasonal statistics over Equatorial Eastern Africa and their predictive potential
2014
Despite earlier studies over various parts of the world including equatorial Eastern Africa (EEA) showing that intraseasonal statistics of wet and dry spells have spatially coherent signals and thus greater predictability potential, no attempts have been made to identify the predictors for these intraseasonal statistics. This study therefore attempts to identify the predictors (with a 1-month lead time) for some of the subregional intraseasonal statistics of wet and dry spells (SRISS) which showed the greatest predictability potential during the short rainfall season over EEA. Correlation analysis between the SRISS and seasonal rainfall totals on one hand and the predefined predictors on th…
Modification of the southern African rainfall variability/ENSO relationship since the late 1960s
2000
Analysis of 149 raingauge series (1946–1988) shows a weak positive correlation between late summer rainfalls (January–March) in tropical southern Africa and the Southern Oscillation Index (SOI). The correlation coefficients have been unstable since World War II. They were close to zero before 1970 and significant thereafter. Before 1970, southern African late summer rainfalls were more specifically correlated with regional patterns of sea surface temperature (SST), mainly over the southwestern Indian Ocean. After 1970, teleconnections with near global SST anomaly patterns, i.e. over the central Pacific and Indian oceans, dominate the regional connections. The increase in the sensitivity of …
Measurement of untruncated nuclear spin interactions via zero- to ultralow-field nuclear magnetic resonance
2015
Zero- to ultra-low-field nuclear magnetic resonance (ZULF NMR) provides a new regime for the measurement of nuclear spin-spin interactions free from effects of large magnetic fields, such as truncation of terms that do not commute with the Zeeman Hamiltonian. One such interaction, the magnetic dipole-dipole coupling, is a valuable source of spatial information in NMR, though many terms are unobservable in high-field NMR, and the coupling averages to zero under isotropic molecular tumbling. Under partial alignment, this information is retained in the form of so-called residual dipolar couplings. We report zero- to ultra-low-field NMR measurements of residual dipolar couplings in acetonitrile…
Optical Shielding of Destructive Chemical Reactions between Ultracold Ground-State NaRb Molecules
2020
Polar quantum gases represent promising platforms for studying many-body physics and strongly correlated systems with possible applications e.g. in quantum simulation or quantum computation. Due to their large permanent electric dipole moment polar molecules in electric field exhibit strong long-range anisotropic dipole-dipole interactions (DDIs). The creation and trapping of ultracold dipolar diatomic molecules of various species are feasible in many experimental groups nowadays. However long time trapping is still a challenge even in the case of the so called nonreactive molecules which are supposed to be immune against inelastic collisions in their absolute ground state [1] . Various hyp…