Search results for "dispersion"

Structure and vibrational features of the protic ionic liquid 1,8-diazabicyclo[5.4.0]-undec-7-ene-8-ium bis(trifluoromethanesulfonyl)amide, [DBUH][TF…

2022

Abstract The Protic Ionic Liquid (PIL) formed by neutralization of the super-strong base 1,7-diazabicyclo[5.4.0]undec-7-ene (DBU) with the super-strong acid bis(trifluoromethanesulfonyl)-imide (TFSI), indicated as [DBUH][TFSI], has been investigated. Its chemical physical properties and structural features have been explored using a synergy of experimental and computational tools. Molecular Dynamics-rationalised X-ray diffraction patterns highlight the major role played by hydrogen bonding (HB) in affecting morphology in this PIL. A comparison between HB features in this and in related PILs has been presented, on the base of far-IR experiments and DFT analysis. Indications of a weaker HB in…

Soil aggregate stability in three Mediterranean environments

1996

Abstract This paper considers the effect of vegetation on soil aggregate stability in three different Mediterranean landscapes in Southeast Spain. Soils on limestone, marls and clays, with two levels of vegetation cover at each north-facing slopes of the study areas, were investigated. Three aggregate stability tests (CND, TDI and UD) based on the drop impact and ultrasonic dispersion methods and the Emerson dispersion test were performed. The results of the experiments show the positive influence of vegetation on aggregate stability. However, vegetation is less important than lithology in influencing soil aggregate stability. Soil depth and moisture also affect aggregation, but the relatio…

Experimental investigation on dispersion mechanisms in rigid and flexible vegetated beds

2018

Vegetation in channels strongly affects flow structure and turbulence, with consequences on the hydrological storage of nutrients and chemical tracers, the shelter of stream biota as well as the trapping or transport of sediments. At the same time, all these phenomena are inevitably subjected to alteration of hydrological conditions in fluvial systems due to climate change. The present study intends to provide a thorough investigation into the processes of transport and dispersion induced by flow turbulence within the vegetation structure. Specifically, velocity measurements in vegetated channels were intensively conducted and analyzed in the case of both flexible submerged and rigid emerge…

Atmospheric dispersion of volcanic CO 2 at Vulcano island

2001

Abstract Intensive carbon dioxide emanations occur throughout the island of Vulcano (Aeolian Archipelago, north of Sicily, Italy). The main sources of CO 2 on the island are the hot fumaroles (∼500°C) of the northern ridge of the La Fossa crater, the fumaroles of the Baia di Levante and the emission areas spread out both on the slopes of the cone and in the nearby plain. The carbon dioxide from the soil can be considered as being emitted at air temperature. In this work, CO 2 concentrations in the air over the island are estimated by means of two numerical codes. This paper takes advantage of the parallel knowledge gained from a previously written paper for SO 2 emissions from the La Fossa …

Engineering the hypersonic phononic band gap of hybrid Bragg stacks.

2012

We report on the full control of phononic band diagrams for periodic stacks of alternating layers of poly(methyl methacrylate) and porous silica combining Brillouin light scattering spectroscopy and theoretical calculations. These structures exhibit large and robust on-axis band gaps determined by the longitudinal sound velocities, densities, and spacing ratio. A facile tuning of the gap width is realized at oblique incidence utilizing the vector nature of the elastic wave propagation. Off-axis propagation involves sagittal waves in the individual layers, allowing access to shear moduli at nanoscale. The full theoretical description discerns the most important features of the hypersonic one…

Workplace Heterogeneity and the Returns to Versatility

2021

Abstract In the canonical random on-the-job search model with continuous firm heterogeneity, I show that a mean-preserving spread of the firm-productivity distribution raises the returns to mobility, i.e., the inter-firm mobility of workers as measured by the number of outside contacts per employment spell. Both sorting and rent-share mechanisms play a role. In a further contribution, I distinguish frictional and structural impediments to mobility in order to establish a link between mobility and skills via the concept of versatility. Versatility enhances a person’s mobility since a mismatch between job requirements and the person’s skill set is less likely to occur. I provide some statisti…

Experimental investigation of the kink effect and the low frequency noise properties in pseudomorphic HEMT’s

2005

The kink effect in low-noise pseudomorphic (AlGaAs/InGaAs) HEMT's has been examined in detail by investigating the steady-state and pulsed I-V characteristics, the behavior of the output conductance dispersion and the performance of the gate leakage current to understand its origin. No clear evidence of impact ionization occurrence in the InGaAs channel at kink bias conditions (V-DS.kink = 1.5 V) has been found, thus suggesting that the predominant mechanism should be attributed to trap-related phenomena. A significant rise of the gate current has been found at very high drain voltages (far from V-DS.kink) associated with low drain current values which is probably due to impact ionization o…

Dalla città compatta all’arcipelago metropolitano: riflessioni a margine di una lezione di Francesco Indovina

2010

Carbon Nanotubes Dispersion Assessment in Nanocomposites by Means of a Pulsed Thermographic Approach

2020

The extensive production of polymer composites reinforced by carbon nanotube is limited by the absence of non-destructive evaluation (NDE) methods capable of assessing product quality to guarantee compliance with specifications. It is well known that the level of dispersion of carbon nanotubes (CNTs) in the polymer matrix is the parameter that, much more than others, can influence their enhancement capabilities. Here an active Infrared Thermography Non Destructive Testing(IR-NDT) inspection, joined with pulsed phase thermography (PPT), were applied for the first time to epoxy-CNT composites to evaluate the level of dispersion of the nanoparticles. The PPT approach was tested on three groups…

"Table 22" of "Studies of quantum chromodynamics with the ALEPH detector"

1997

Unfolded values of the the mean multiplicity and dispersion of the multiplicity distributions integrated over the rapidity region -1.5 to 1.5.