Search results for "don"

A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces

2016

The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(II) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the isopropyl substituents on the NHSi ligand significantly enhance the stability of the complex, along with Fe-to-Si π-backbonding.

Effect of different concentrations of specific inhibitor of matrix metalloproteinases on the shear bond strength of self-adhesive resin cements to de…

2017

Background Considering the probability of chemical and enzymatic reactions between matrix metalloproteinases (MMPs) in the dentin structure and their specific inhibitors, the aim of the present study was to evaluate the effect of different concentrations of specific inhibitor of MMPs (galardin) on the shear bond strength of self-adhesive resin cements to dentin. Material and Methods Forty-eight sound human premolars were mounted in self-cured acrylic resin after removal of the enamel on the buccal and lingual surfaces. The dentin surfaces achieved were polished and prepared with 600-grit silicon carbide paper. The samples were divided into 3 groups (n=16) based on the concentration of galar…

The Impact of Vineyard Abandonment on Soil Properties and Hydrological Processes

2017

Spatio-temporal patterns of thermal anomalies and drought over tropical forests driven by recent extreme climatic anomalies

2018

The recent 2015–2016 El Niño (EN) event was considered as strong as the EN in 1997–1998. Given such magnitude, it was expected to result in extreme warming and moisture anomalies in tropical areas. Here we characterize the spatial patterns of temperature anomalies and drought over tropical forests, including tropical South America (Amazonia), Africa and Asia/Indonesia during the 2015–2016 EN event. These spatial patterns of warming and drought are compared with those observed in previous strong EN events (1982–1983 and 1997–1998) and other moderate to strong EN events (e.g. 2004–2005 and 2009–2010). The link between the spatial patterns of drought and sea surface temperature anomalies in th…

A multisensor fusion approach to improve LAI time series

2011

International audience; High-quality and gap-free satellite time series are required for reliable terrestrial monitoring. Moderate resolution sensors provide continuous observations at global scale for monitoring spatial and temporal variations of land surface characteristics. However, the full potential of remote sensing systems is often hampered by poor quality or missing data caused by clouds, aerosols, snow cover, algorithms and instrumentation problems. A multisensor fusion approach is here proposed to improve the spatio-temporal continuity, consistency and accuracy of current satellite products. It is based on the use of neural networks, gap filling and temporal smoothing techniques. …

Steroid Biomarkers Revisited - Improved Source Identification of Faecal Remains in Archaeological Soil Material.

2017

Steroids are used as faecal markers in environmental and in archaeological studies, because they provide insights into ancient agricultural practices and the former presence of animals. Up to now, steroid analyses could only identify and distinguish between herbivore, pig, and human faecal matter and their residues in soils and sediments. We hypothesized that a finer differentiation between faeces of different livestock animals could be achieved when the analyses of several steroids is combined (Δ5-sterols, 5α-stanols, 5β-stanols, epi-5β-stanols, stanones, and bile acids). We therefore reviewed the existing literature on various faecal steroids from livestock and humans and analysed faeces …

Was climatic cooling during the earliest Carboniferous driven by expansion of seed plants?

2021

Abstract The expansion of land plants is considered to have played a key role in triggering the Late Paleozoic Ice Age (LPIA), but evidence linking climatic events to terrestrial floral changes is limited. Here, we generated bulk carbonate δ13C, conodont δ18O and 87Sr/86Sr profiles from the lowermost Carboniferous of South China and Vietnam in order to investigate their relationship to contemporaneous land plant evolution. Climatic cooling in the mid-Tournaisian coincided with large perturbations to the global carbon cycle and continental weathering regimes as well as with a major diversification episode among seed plants. These relationships are consistent with terrestrial floral changes t…

Global-Scale Evaluation of Roughness Effects on C-Band AMSR-E Observations

2015

Quantifying roughness effects on ground surface emissivity is an important step in obtaining high-quality soil moisture products from large-scale passive microwave sensors. In this study, we used a semi-empirical method to evaluate roughness effects (parameterized here by the parameter) on a global scale from AMSR-E (Advanced Microwave Scanning Radiometer for EOS) observations. AMSR-E brightness temperatures at 6.9 GHz obtained from January 2009 to September 2011, together with estimations of soil moisture from the SMOS (Soil Moisture and Ocean Salinity) L3 products and of soil temperature from ECMWF’s (European Centre for Medium-range Weather Forecasting) were used as inputs in a retrieval…

Translating taxonomy into the evolution of conodont feeding ecology

2016

Conodont research has long been divided between utilitarian applications to solve geological problems versus analysis of their palaeobiology. However recent advances in conodont functional analysis allow these independent stands of research to be unified, decoding the functional implications of their morphological variation. We demonstrate this using synchrotron tomography and Finite Element Analysis, informed by occlusal and microwear analyses, to analyze functionally the classic evolutionary sequence of the genus Polygnathus. Our study shows that the evolution of the platform in Polygnathus occurred to accommodate and dissipate the stress accumulation derived from the tooth-like function …

Évolution rétrograde de Neospathodus au cours de la crise Permo - Triasique

2016

The Permian - Triassic evolution of platform conodonts (Gondolellidae) consists mainly in developing the carina and the platform. During the sublethal environmental stress conditions subsequent to the Permian - Triassic extinction, the Wuchiapingian - Griesbachian Clarkina lineage is replaced by the primitive looking platform-lacking Dienerian - Aegean Neospathodus kummeli - Kashmirella timorensis lineage. Moreover, above Jinogondolella denticulata, end of the Capitanian Jinogondolella lineage, “Neospathodus” arcucristatus, an atavistic blade-like homeomorph that lacks a platform, underlies Protoclarkina crofti, of the base of the anagenetic Clarkina lineage. These primitive-looking forms a…