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showing 10 items of 4363 documents

CCDC 1818063: Experimental Crystal Structure Determination

2018

Related Article: Ondřej Jurček, Hennie Valkenier, Rakesh Puttreddy, Martin Novák, Hazel A. Sparkes, Radek Marek, Kari Rissanen, Anthony P. Davis|2018|Chem.-Eur.J.|24|8178|doi:10.1002/chem.201800537

Space GroupCrystallographyethyl 27-bis{[(4-nitrophenyl)carbamoyl]amino}octahydronaphthalene-4a(2H)-carboxylate monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Raman spectroscopy of the high- and low-spin states of the spin crossover complex Fe(phen)2(NCS)2: an initial approach to estimation of vibrational c…

2000

Abstract Raman spectra of the spin-crossover complex Fe(phen)2(NCS)2 in the solid state have been recorded at 785 nm as a function of temperature to investigate the contribution of intramolecular vibrations to the entropy change, ΔS, associated with spin crossover. The modes of major interest for estimating the contribution lie in the range 100–500 cm−1, where the largest qualitative changes with temperature in the Raman spectra were observed. Analysis of these data, with the working assumption of an average frequency in this range as representative of the 15 distortion modes of an idealised FeN6 octahedron, leads to the conclusion that the intramolecular vibrations represent a primary cont…

Spin statesChemistryAnalytical chemistrySolid-stateGeneral Physics and AstronomyMolecular physicsVibrationsymbols.namesakeOctahedronSpin crossoverIntramolecular forcesymbolsCoherent anti-Stokes Raman spectroscopyPhysical and Theoretical ChemistryRaman spectroscopyChemical Physics Letters
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Search for WH production with a light Higgs boson decaying to prompt electron-jets in proton–proton collisions at \(\sqrt {s}=7\)  TeV with the ATLAS…

2013

A search is performed for WH production with a light Higgs boson decaying to hidden-sector particles resulting in clusters of collimated electrons, known as electron-jets. The search is performed with 2.04 fb[superscript −1] of data collected in 2011 with the ATLAS detector at the Large Hadron Collider in proton–proton collisions at √s=7 TeV . One event satisfying the signal selection criteria is observed, which is consistent with the expected background rate. Limits on the product of the WH production cross section and the branching ratio of a Higgs boson decaying to prompt electron-jets are calculated as a function of a Higgs boson mass in the range from 100 to 140 GeV.

Standard ModelAtlas detectorGeneral Physics and AstronomyElectron7. Clean energy01 natural sciencesSignal selectionHigh Energy Physics - ExperimentLepton-JetsHigh Energy Physics - Experiment (hep-ex)Naturvetenskap[PHYS.HEXP]Physics [physics]/High Energy Physics - Experiment [hep-ex]Nuclear ExperimentQCPhysicsddc:539Large Hadron ColliderSettore FIS/01 - Fisica SperimentaleSignal selectionBranching ratioATLASLarge Hadron ColliderComputingMethodologies_DOCUMENTANDTEXTPROCESSINGHiggs bosonLHCNatural SciencesParticle Physics - ExperimentParticle physics530 PhysicsCiências Naturais::Ciências FísicasHiggs bosonAstrophysics::High Energy Astrophysical Phenomena:Ciências Físicas [Ciências Naturais]FOS: Physical sciencesddc:500.2530Collimated lightNuclear physics0103 physical sciencesddc:530High Energy Physics010306 general physicsW BOSONScience & TechnologyProton proton collisions010308 nuclear & particles physicsBranching fractionATLAS detectorsHigh Energy Physics::PhenomenologyFísicaMassEnergiesHidden sectorProduction cross sectionHiggs boson; electron-jets; proton–proton collisions; ATLAS detectorHADRON-HADRON COLLISIONSExperimental High Energy PhysicsHigh Energy Physics::Experiment
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The anomalous magnetic moment of the muon in the Standard Model

2020

We are very grateful to the Fermilab Directorate and the Fermilab Theoretical Physics Department for their financial and logistical support of the first workshop of the Muon g -2 Theory Initiative (held near Fermilab in June 2017) [123], which was crucial for its success, and indeed for the successful start of the Initiative. Financial support for this workshop was also provided by the Fermilab Distinguished Scholars program, the Universities Research Association through a URA Visiting Scholar award, the Riken Brookhaven Research Center, and the Japan Society for the Promotion of Science under Grant No. KAKEHNHI-17H02906. We thank Shoji Hashimoto, Toru Iijima, Takashi Kaneko, and Shohei Nis…

Standard ModelNuclear Theorymagnetichigher-orderPhysics beyond the Standard ModelGeneral Physics and Astronomynucl-ex01 natural sciencesHigh Energy Physics - ExperimentSubatomär fysikHigh Energy Physics - Experiment (hep-ex)High Energy Physics - Phenomenology (hep-ph)Subatomic Physicsquantum electrodynamics[PHYS.HEXP]Physics [physics]/High Energy Physics - Experiment [hep-ex]Vacuum polarizationNuclear Experiment (nucl-ex)Nuclear Experimentfundamental constant: fine structurePhysicsQuantum chromodynamicsQEDAnomalous magnetic dipole momentnew physicsJ-PARC LabHigh Energy Physics - Lattice (hep-lat)Electroweak interactionlattice field theoryParticle Physics - Latticehep-phObservableHigh Energy Physics - PhenomenologyNuclear Physics - TheoryParticle Physics - ExperimentParticle physics[PHYS.NUCL]Physics [physics]/Nuclear Theory [nucl-th]nucl-th530 Physicsdispersion relationg-2Lattice field theoryFOS: Physical scienceshep-latnonperturbative[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]530Muon magnetic momentNuclear Theory (nucl-th)High Energy Physics - Latticemuonquantum chromodynamics0103 physical sciencesddc:530Nuclear Physics - Experiment010306 general physicsactivity reportperturbation theoryParticle Physics - PhenomenologyMuonmuon: magnetic momentelectroweak interaction[PHYS.HLAT]Physics [physics]/High Energy Physics - Lattice [hep-lat]hep-ex010308 nuclear & particles physicsvacuum polarization: hadronicHigh Energy Physics::Phenomenologyphoton photon: scatteringanomalous magnetic moment[PHYS.HPHE]Physics [physics]/High Energy Physics - Phenomenology [hep-ph]High Energy Physics::ExperimentPhysics Reports
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Measurements of Higgs boson production and couplings in diboson final states with the ATLAS detector at the LHC

2013

We acknowledge the support of ANPCyT, Argentina; YerPhI, Armenia; ARC, Australia; BMWF and FWF, Austria; ANAS, Azerbaijan; SSTC, Belarus; CNPq and FAPESP, Brazil; NSERC, NRC and CFI, Canada; CERN; CONICYT, Chile; CAS, MOST and NSFC, China; COLCIENCIAS, Colombia; MSMT CR, MPO CR and VSC CR, Czech Republic; DNRF, DNSRC and Lundbeck Foundation, Denmark; EPLANET, ERC and NSRF, European Union; IN2P3-CNRS, CEA-DSM/IRFU, France; GNSF, Georgia; BMBF, DFG, HGF, MPG and AvH Foundation, Germany; GSRT and NSRF, Greece; ISF, MINERVA, GIF, DIP and Benoziyo Center, Israel; INFN, Italy; MEXT and JSPS, Japan; CNRST, Morocco; FOM and NWO, Netherlands; BRF and RCN, Norway; MNiSW, Poland; GRICES and FCT, Portu…

Standard Modeldilepton: mass spectrumCiencias Físicas01 natural sciences7. Clean energySettore FIS/04 - Fisica Nucleare e SubnucleareHigh Energy Physics - ExperimentHiggs particle: hadroproduction//purl.org/becyt/ford/1 [https]High Energy Physics - Experiment (hep-ex)vector boson: fusion[PHYS.HEXP]Physics [physics]/High Energy Physics - Experiment [hep-ex]QCBosonPhysicsHIGGS BOSONLarge Hadron Collidervector boson: pair productiontransverse energy: missing-energy4. EducationATLAS experimentSettore FIS/01 - Fisica SperimentaleATLAS3. Good healthMassless particleCERN LHC CollHiggs particle: massPhysical SciencesComputingMethodologies_DOCUMENTANDTEXTPROCESSINGHiggs boson7000: 8000 GeV-cmsFísica nuclearAtlasLhcNeutrinoHiggs particle: decay modesParticle Physics - ExperimentCIENCIAS NATURALES Y EXACTASp p: scatteringNuclear and High Energy PhysicsParticle physicsmass spectrum: (4lepton)530 PhysicsCiências Naturais::Ciências Físicas:Ciências Físicas [Ciências Naturais]FOS: Physical sciencesddc:500.2ATLASdetector; LHC; Higgsbosonproduction; diboson530Massless ParticlesNnlo QCDNuclear physics0103 physical sciencesFysikddc:530High Energy Physics010306 general physicsTransverse-MomentumCondensed Matter::Quantum GasesHiggs particle: couplingScience & Technologyhep-ex010308 nuclear & particles physicsHigh Energy Physics::PhenomenologyFísicaQCD CorrectionsFermion//purl.org/becyt/ford/1.3 [https]Hadron CollidersDiboson ProductionAstronomíavector boson: leptonic decayHADRON-HADRON COLLISIONSProton-Proton CollisionsRoot-S=7 TevHiggs particle: hadroproduction ; Higgs particle: coupling ; vector boson: fusion ; p p: scattering ; CERN LHC Coll ; ATLAS ; Higgs particle: decay modes ; vector boson: pair production ; vector boson: leptonic decay ; mass spectrum: two-photon ; mass spectrum: (4lepton) ; dilepton: mass spectrum ; transverse energy: missing-energy ; Higgs particle: mass ; experimental results ; 7000: 8000 GeV-cmsExperimental High Energy PhysicsHigh Energy Physics::ExperimentCross-Sectionsmass spectrum: two-photonexperimental resultsLeptonBroken Symmetries
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Solid state conformational and theoretical study of complexes containing the (CxN)Pd moiety (CxN = 2-(phenylazo)phenyl-C,N and its derivatives)

2003

Palladium complexes having the 2-(phenylazo)phenyl-C,N ligand exhibit a planar chelating ring with NN and N–C distances longer and shorter respectively than those found in trans-azobenzene. The ligand is not planar upon complexation, the mean angle between the phenyl ring and the chelating one found in the Cambridge Structural Database being of 45.6°. We have quantified and characterised the kind of distortion from planar coordination around metallic centers. The method employed makes use of two improper torsion angles, tetrahedral distortion being most frequently found in phenylazophenyl palladium complexes. Crystal structures of three succinimidate complexes having the title moiety are re…

StereochemistryAb initiochemistry.chemical_elementGeneral ChemistryCrystal structureCatalysisMetalCrystallographychemistryvisual_artMaterials ChemistryTetrahedronvisual_art.visual_art_mediumMoietyDensity functional theoryChelationPalladiumNew J. Chem.
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Unusual interaction extended between the pyranose ring oxygen and Zn(II) center in the complexes derived from 4,6-O-butylidene/ethylidene-N-(α-hydrox…

2003

The Zn(II) complexes of 4,6-O-butylidene/ethylidene-N-(α-hydroxynaphthylidene/o-hydroxybenzylidene)-β-Image -glucopyranosylamine have been synthesized and characterized using spectral and analytical methods and structure for one of the products was established. The geometry of the complexes vary from unusual distorted trigonal bipyramidal to pseudo-bicapped tetrahedron depending upon the extent of binding of pyranose ring oxygens to the Zn(II) ion, as evidenced from crystal structures. Such interaction is also reflected on the optical rotation and CD spectral properties of these complexes in solution.

StereochemistryCenter (category theory)chemistry.chemical_elementPyranose Ring OxygenCrystal structureOxygenIonInorganic ChemistryCrystallographyTrigonal bipyramidal molecular geometryPseudo Bicapped TetrahedronchemistryPyranoseZn(Ii) ComplexesMaterials ChemistryTetrahedronPhysical and Theoretical ChemistryOptical rotationInorganic Chemistry Communications
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Synthesis and spectroscopic studies (Mo¨ssbauer, IR and NMR) of [R2SnCl2bipym] (R = butyl or phenyl) and the crystal and molecular structure of [Ph2S…

1994

Abstract The complexes [R 2 SnCl 2 bipym] (R = phenyl or butyl, bipym = 2,2′,6,6′-bipyrimidine) were synthesized and studied in solution by 1 H- and 13 C-NMR spectroscopy and in the solid state by IR and Mo¨ssbauer spectroscopy. The latter was also performed in frozen ethanolic solution. The structure of the phenyl complex was determined by single crystal diffraction methods. The value obtained for the angle C-SN-C in the phenyl compound is 169.3(2)° (X-ray) and 151° (Mo¨ssbauer), but the assignment of an octahedral configuration by Mo¨ssbauer spectroscopy is consistent with the structure determined by diffraction. The butyl complex is also octahedral and the two techniques show better agre…

StereochemistryChemistryCoordination numberOrganic ChemistryCrystal structureBiochemistryInorganic ChemistryCrystalNMR spectra databaseCrystallographyOctahedronX-ray crystallographyMaterials ChemistryMoleculePhysical and Theoretical ChemistrySpectroscopyJournal of Organometallic Chemistry
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Synthesis, crystal structure and magnetic properties of [Cu2(bpym)(N3)4] (bpym=2,2′-bipyrimidine)

1993

Abstract The compound of formula [Cu 2 (bpym)(N 3 ) 4 ] (bpym=2,2′-bipyrimidine) has been synthesized and its crystal structure determined by X-ray diffraction methods. It crystallizes in the monoclinic space group P 2 1 / n with cell constants: a =10.071(2), b =6.376(1), c =11.617(2) A and β=95.93(1)°; V =742.0(2) A 3 , D (calc., Z =2)=2.029 g cm −3 , M r =453.4, F (000)=448, λ (Mo Kα)=0.71073 A, μ (Mo Kα)=29.1 cm −1 and T =298 K. A total of 2027 reflections was collected over the range 3⩽2θ⩽55°; of these, 1723 were unique and 1427 were considered as observed ( I >3σ( I )) and used in the structural analysis. The final R and R w residuals were 0.0275 and 0.0328, respectively. The structure…

StereochemistryChemistryCrystal structureMagnetic susceptibilityInorganic ChemistryCrystallographychemistry.chemical_compoundOctahedronX-ray crystallographyMaterials ChemistryAntiferromagnetismMoleculeAzidePhysical and Theoretical ChemistryMonoclinic crystal systemInorganica Chimica Acta
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Synthesis and structural, spectroscopic and magnetic characterization of iron(II) and iron(III) complexes of N-2-pyridinylcarbonyl-2-pyridinecarboxim…

1993

Abstract One iron(II) complex of N -2-pyridinylcarbonyl-2-pyridinecarboximidate monoanion (bpca), [Fe(bpca) 2 ]·H 2 O ( 1 ), and three iron(III) complexes, [Fe(bpca)Cl 2 (H 2 O)]·(CH 3 ) 2 CO ( 2 ), [Fe(bpca) 2 ](NO 3 )·1.67H 2 O ( 3 ), [Fe(bpca) 2 ](ClO 4 ) ( 4 ), have been prepared and characterized by means of IR, UV-Vis and EPR spectroscopy and magnetic susceptibility measurements, where appropriate. The crystal structures of 1 – 3 have been determined from single crystal X-ray data, showing that the metallic ions are surrounded in all cases by distorted octahedral coordination spheres. From magnetic measurements it is evident that compounds 1 and 3 are practically in the low-spin state…

StereochemistryChemistryCrystal structureMagnetic susceptibilitylaw.inventionInorganic ChemistryMetalCrystallographyOctahedronlawvisual_artX-ray crystallographyMaterials Chemistryvisual_art.visual_art_mediumMoleculePhysical and Theoretical ChemistryElectron paramagnetic resonanceSingle crystalInorganica Chimica Acta
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