Search results for "dron"

The odd association of a C3h trisamidinium cation and tosylate anion with a series of linear oxalate-bridged trinuclear heterometallic complexes

2013

A series of six isostructural heterometallic trinuclear oxalate-bridged complexes of the formula (TDbenz)(2)(TsO)(2)[M(II)(H(2)O)(2){(μ-ox)M(III)(ox)(2)}(2)]·6H(2)O·2CH(3)OH (TDbenz = 1,3,5-tris[2-(1,3-diazolinium)]benzene; TsO = 4-methylbenzenesulfonate; ox = oxalate; M(III) = Fe, M(II) = Mn (1), Fe (2), Co (3); M(III) = Cr, M(II) = Mn (4), Fe (5), Co (6)) have been synthesized from (NH(4))(3)[M(III)(ox)(3)]·3H(2)O, the chloride salts of the divalent metal ions and the tosylate salt of 1,3,5-tris[2-(1,3-diazolinium)]benzene (trisamidinium). Whereas the crystal structures of compounds 2, 3, 4 and 5 have been investigated by single-crystal X-ray diffraction, the structures of 1 and 6 have be…

Dimensionally controlled hydrogen-bonded nanostructures: synthesis, structure, thermal and magnetic behaviour of the tris-(chelated)nickel(II) comple…

2002

Abstract Single crystals of the compound of formula [Ni(bipy)3]Cl2·5.5H2O (bipy=2,2′-bipyridine) have been prepared and structurally characterised by X-ray diffraction. The structure analysis reveals that the complex has an approximate D3 symmetry. The coordination sphere consists of six nitrogen atoms of the three-bipyridine ligands in an octahedral arrangement about the nickel. One of the chlorine ions is surrounded by twelve CH⋯Cl hydrogen bonds. Three kinds of layers are found in the crystal structure: (i) the Λ-[Ni(bipy)3]2+ cation; (ii) the water/chloride positions (O(1w)/Cl(21) to O(7w)/Cl(27)); (iii) the Δ-[Ni(bipy)3]2+ cation and a chloride ion (Cl(1)). The layers are stacked in t…

A novel series of rhenium-bipyrimidine complexes: synthesis, crystal structure and electrochemical properties

2007

Four novel rhenium complexes of formula [ReCl(4)(bpym)] (1), [ReBr(4)(bpym)] (2) PPh(4)[ReCl(4)(bpym)] (3) and NBu(4)[ReBr(4)(bpym)] (4) (bpym = 2,2'-bipyrimidine, PPh(4) = tetraphenylphosphonium cation and NBu(4) = tetrabutylammonium cation), have been synthesized and their crystal structures determined by single-crystal X-ray diffraction. The structures of 1 and 2 consist of [ReX(4)(bpym)] molecules held together by van der Waals forces. In both complexes the Re(iv) central atom is surrounded by four halide anions and two nitrogen atoms of a bpym bidentate ligand in a distorted octahedral environment. The structures of 3 and 4 consist of [ReX(4)(bpym)](-) anions and PPh(4)(+) () or NBu(4)…

Molecular, Supramolecular Structures Combined with Hirshfeld and DFT Studies of Centrosymmetric M(II)-azido {M=Ni(II), Fe(II) or Zn(II)} Complexes of…

2021

The supramolecular structures of the three metal (II) azido complexes [Fe(4bzpy)4(N3)2]

Formation and distortion of iodidoantimonates(III): the first isolated [SbI6]3- octahedron

2017

The ability to intentionally construct, through different types of interactions, inorganic–organic hybrid materials with desired properties is the main goal of inorganic crystal engineering. The primary deformation, related to intrinsic interactions within inorganic substructure, and the secondary deformation, mainly caused by the hydrogen bond interactions, are both responsible for polyhedral distortions of halogenidoantimonates(III) with organic cations. The evolution of structural parameters, in particular the Sb—I secondary- and O/N/C—H...I hydrogen bonds, as a function of temperature assists in understanding the contribution of those two distortion factors to the irregularity of [SbI6]…

Retraction notice to “trans-Tetrakis(pyridine)dichloroiron(II) as catalyst for Suzuki cross-coupling in ethanol and water” [Tetrahedron Lett. 49 (200…

2009

Kaon Photo- and Electroproduction on Nucleons

1995

We extend previous models of kaon photo- and electroproduction in order to include all six isospin channels. It is found that the inclusion of the few available data for the reactions γp → K 0 Σ − in the fit leads to drastically reduced Born coupling constants g Λ and g Σ . The result suggests the need to include hadronic form factors in a gauge invariant fashion. It is also shown that the K 0 form factor can be seen in K 0 Λ electroproduction.

Unpolarized and polarized elementary kaon electroproduction cross sections measured at MAMI

2012

Present and future research into the electroproduction of kaons plays an im- portant role at Mainz Microtron MAMI. With the Kaos spectrometer employed for kaon detection in the multi-spectrometer facility, cross section measurements of the exclusive p(e;e 0 K + ); 0 reactions at low momentum transfers have been performed. Isobar and Regge-plus-resonance models were compared with the data. These measurements have clearly discriminated between e ective Lagrangian models for photo- and electroproduc- tion of strangeness. New experiments with polarized beam at low four-momentum transfer are addressing the imaginary part of the longitudinal-transverse response in this process, that can be separa…

Limits on anomalous trilinear gauge boson couplings from WW, WZ and Wγ production in pp¯ collisions at s=1.96 TeV

2012

We present searches for the anomalous γWW and ZWW trilinear gauge boson couplings from WW and WZ production using lepton plus dijet final states and a combination with results from Wγ, WW, and WZ production with leptonic final states. The analyzed data correspond to up to 8.6fb -1 of integrated luminosity collected by the D0 detector in pp- collisions at s=1.96TeV. We set the most stringent limits at a hadron collider to date assuming two different relations between the anomalous coupling parameters δκ γ, λ, and δg1Z for a cutoff energy scale Λ=2TeV. The combined 68% C.L. limits are -0.057lδκ γl0.154, -0.015lλl0.028, and -0.008lδg1Zl0.054 for the LEP parameterization, and -0.007lδκl0.081 an…

The nature of Lambda (1405) hyperon resonance in chiral dynamics

2010

10th International Conference on Hypernuclear and Strange Particle Physics. Tokai, JAPAN, SEP 14-18, 2009