Search results for "dynamics."
showing 10 items of 9637 documents
Spinodal decomposition of a two-dimensional model alloy with mobile vacancies
1991
Abstract Monte Carlo simulations are performed for the initial stages of phase separation in a model binary alloy (AB), where unmixing is caused by a repulsive energy between atoms of different kind ( e AA = e BB = e ), and a small fraction c v of mobile vacancies is present (typically c v = 0.04.) Unlike previous work, where interdiffusion was modelled in an unrealistic way by direct interchange of A and B atoms for c v = 0, were use the vacancy mechanism of diffusion: A-atoms may jump to vacant sites with a rate Γ A and B-atoms may jump to vacant sites with a rate Γ B , no direct A–B interchange being permitted. It is shown that the overall time-scale on which phase separation proceeds ty…
Phase separation of an asymmetric binary fluid mixture confined in a nanoscopic slit pore: Molecular-dynamics simulations
2008
As a generic model system of an asymmetric binary fluid mixture, hexadecane dissolved in carbon dioxide is considered, using a coarse-grained bead-spring model for the short polymer, and a simple spherical particle with Lennard-Jones interactions for the carbon dioxide molecules. In previous work, it has been shown that this model reproduces the real phase diagram reasonable well, and also the initial stages of spinodal decomposition in the bulk following a sudden expansion of the system could be studied. Using the parallelized simulation package ESPResSo on a multiprocessor supercomputer, phase separation of thin fluid films confined between parallel walls that are repulsive for both types…
Subamorphous thermal conductivity of crystalline half-Heusler superlattices
2021
The quest to improve the thermoelectric figure of merit has mainly followed the roadmap of lowering the thermal conductivity while keeping unaltered the power factor of the material. Ideally an electron-crystal phonon-glass system is desired. In this work, we report an extraordinary reduction of the cross-plane thermal conductivity in crystalline (TiNiSn):(HfNiSn) half-Heusler superlattices (SLs). We create SLs with thermal conductivities below the effective amorphous limit, which is kept in a large temperature range (120–300 K). We measured thermal conductivity at room temperature values as low as 0.75 W m−1 K−1, the lowest thermal conductivity value reported so far for half-Heusler compou…
The global cracking laws for a finite-element model of no-tension material
1992
Abstract For perfect no-tension materials (NRT) the validity of the local stability postulate of Drucker, well known in plasticity, has been assumed so far and utilized to derive the local cracking laws, which relate cracking strain states and stress states to each other. On this base a finite-element (FE) model with suitable constitutive behaviour for the single FE is presented. Classical FE approaches enforce the cracking laws at the Gauss points of the FEs. In this work it is shown that taking into account cracking strains, suitably modelled, over the whole domain of the FE and making use of an energy approach lead to general cracking laws describing the constitutive behaviour of the who…
Two relaxation times and thermal nonlinear waves along wires with lateral heat exchange
2021
Abstract We propose a model for studying several nonlinear waves for heat transport along a cylindrical system with lateral non-linear heat transfer to the environment. We consider relaxational equations, each with its own relaxation time, for longitudinal heat transfer and for lateral heat transfer across the wall. We consider two kinds of nonlinear lateral heat transport: radiative heat transport, and flux-limited heat transport. This work generalizes our previous studies in which the relaxation time for the lateral heat transfer was considered equal to that of the longitudinal heat flux. We explore the influence of both relaxation times on the propagation speed of linear and nonlinear wa…
Experimental characterization of a novel configuration of thermoelectric refrigerator with integrated finned heat pipes
2021
Abstract Thermoelectric refrigerating systems (TER) are environment-friendly technologies. They have several advantages such as low maintenance costs, are less cumbersome and long lifetime. However, these systems have low coefficient of performance and are limited in achieving low temperature levels. This study investigates a new configuration of TE refrigerator employing a novel arrangement of heat sinks with integrated flat and finned heat pipes. A mathematical model is firstly developed to predict transient temperatures and cooling limit time. An experimental characterization is then performed and it includes optimization of energy consumption, cooling time, temperature levels and TE ref…
Wall collision and drug-carrier detachment in dry powder inhalers: Using DEM to devise a sub-scale model for CFD calculations
2018
Abstract In this work, the Discrete Element Method (DEM) is used to simulate the dispersion process of Active Pharmaceutical Ingredients (API) after a wall collision in dry powders inhaler used for lung delivery. Any fluid dynamic effects are neglected in this analysis at the moment. A three-dimensional model is implemented with one carrier particle (diameter 100 μm) and 882 drug particles (diameter 5 μm). The effect of the impact velocity (varied between 1 and 20 m s−1), angle of impact (between 5° and 90°) and the carrier rotation (±100,000 rad s−1) are investigated for both elastic and sticky walls. The dispersion process shows a preferential area of drug detachment located in the southe…
Critical Influence of Dielectric Sensitive Material and Manufactured Process in Microwave Gas-Sensing: Application of Ammonia Detection with an Inter…
2020
In this paper, authors propose a study on microwave gas sensors and the influence of critical key parameters such as the sensitive material and the circuit conception process. This work aims to determine the influence of these parameters on the quality of the final response of the microwave gas sensor. The fixed geometry of the sensor is a microstrip interdigital capacitor coated with a sensitive layer excited with two 50 Ω SMA ports. The sensitive material has been chosen in order to interact with the target gas: ammonia. Indeed, this gas interacts with phthalocyanine and metal oxides like hematite, TiO2. To explore the effect of the circuit manufacturing process, three series of samples a…
Increasing Nanoparticles’ Refractive Index Sensitivity
2012
Since the plasmon resonance of nanoparticles depends on the refractive index of the immediate environment, these particles form the basis of many sensing schemes . The sensitivity of plasmon sensors for the detection of changes in the environment varies greatly and depends on the particle material and its morphology (size and shape). To further increase this sensitivity by chemical modifications was another goal of my work.
Experiments and predictions of the transition of the flow pattern with impeller clearance in stirred tanks
2001
In the present work, the double- to single-loop flow pattern transition in a stirred vessel equipped with a Rushton turbine is investigated by Laser Doppler anemometry (LDA). In particular, the clearance at which such transition occurs is assessed by comparing axial velocity profiles underneath the impeller. Computational fluid dynamics (CFD) simulations of the same system are carried out, by employing the 'inner-outer' fully predictive computation strategy. The comparison of predicted results with the experimental data collected shows that the transition is well reproduced by simulations. A good agreement on the mean velocities is also observed but for the impeller discharge stream angle t…