Search results for "dynamics"
showing 10 items of 9782 documents
The Thermodynamics of Insertion Electrochemical Electrodes—A Team Play of Electrons and Ions across Two Separate Interfaces
2018
Insertion electrochemical electrodes exhibit simultaneous electron and ion transfer, with the two transfers proceeding across different interfaces. Herein the thermodynamics of the overall electrochemical electrode reaction is discussed with respect to the thermodynamics of these two charge-transfer equilibria. This Minireview includes insertion electrochemical systems where the redox centers are in a solid phase and the ions are transferred between that phase and a solution, and also systems where the redox centers are in a liquid phase that is immiscible with another liquid phase and ions are transferred between the two liquid phases. The Minireview is intended to spark similar studies on…
On the modelling of an Acid/Base Flow Battery: An innovative electrical energy storage device based on pH and salinity gradients
2020
Abstract Electrical energy storage can enhance the efficiency in the use of fluctuating renewable sources, e.g. solar and wind energy. The Acid/Base Flow Battery is an innovative and sustainable process to store electrical energy in the form of pH and salinity gradients via electrodialytic reversible techniques. Two electromembrane processes are involved: Bipolar Membrane Electrodialysis during the charge phase and its opposite, Bipolar Membrane Reverse Electrodialysis, during the discharge phase. For the first time, the present work aims at predicting the performance of this energy storage device via the development of a dynamic mathematical model based on a multi-scale approach with distr…
Development of a membrane-less microfluidic thermally regenerative ammonia battery
2021
Thermally regenerative ammonia battery is a promising approach to make use of waste heat and generate electrical energy. However, according to literature, the price of the energy obtained by this device is much higher than alternative renewable technologies (such as wind, solar, geothermal, etc.). To make the process more viable for applicative purposes, it would be necessary to reduce dramatically the cost of the membrane or to avoid it. Hence, the aim of the present work is to increase the economic figures of thermally regenerative ammonia battery avoiding the use of membranes. It was concluded that this result can be obtained by developing the process in a microfluidic flow cell with lam…
Non-thermal radiation from a pulsar wind interacting with an inhomogeneous stellar wind
2017
Binaries hosting a massive star and a non-accreting pulsar are powerful non-thermal emitters due to the interaction of the pulsar and the stellar wind. The winds of massive stars are thought to be inhomogeneous, which could have an impact on the non-thermal emission. We study numerically the impact of the presence of inhomogeneities or clumps in the stellar wind on the high-energy non-thermal radiation of high-mass binaries hosting a non-accreting pulsar. We compute the trajectories and physical properties of the streamlines in the shocked pulsar wind without clumps, with a small clump, and with a large one. This information is used to compute the synchrotron and inverse Compton emission fr…
X-Ray crystallographic and computational study on uranyl-salophen complexes bearing nitro groups.
2017
In the solid state, salophen–UO2 complexes bearing one, two, or three NO2 groups lack the pronounced ligand curvature that represents a structural hallmark for this class of compounds. A detailed structural study based on single-crystal X-ray crystallography and computational methods, comprising molecular dynamics, gas-phase Hartree Fock, and DFT calculations, was carried out to investigate the coordination properties of the uranyl cation.
The Relevance of Kneading and Extrusion Parameters in the Manufacture of Active Porous Aluminas from Pseudoboehmites
1987
In order to study the effect-on crushing strength, attrition resistance, specific pore volume, and pore volume distribution of extrudates-of kneading and extrusion parameters in the manufacture of active porous aluminas, a commercial pseudoboehmite (Pural SB from Condea Chemie, Brunsbuttel, FRG) was employed. A minimum kneading torque was required to prepare an extrudable paste, predetermined by extrusion conditions. The torque had an upper limit with respect to certain extrudate properties. The amount of water and the concentration of nitric acid as binder solutions were found to have a decisive bearing on the mechanical properties and the distribution of the pore volume. Crushing strength…
Experimental Observations of Flow and Bed Processes in Large-Amplitude Meandering Flume
2009
Meanders of large amplitude often exhibit asymmetric planform shape or subsidiary bends. The present work is aimed at improving on understanding of the morphodynamic phenomena affecting the bed evolution of large amplitude meandering channels. Attention is focused on the development of the steady point bar-pool configuration and of the superimposed large-scale migrating bed forms; of particular interest is the role of the changing channel curvature and bed topography variation on flow pattern. A series of experiments was carried out in a sine-generated large-amplitude meandering flume, for two values of width-to-depth ratio. Maps documenting the bed topography and the flow pattern along the…
Experimental observations of upstream overdeepening
2005
The issue of morphodynamic influence in meandering streams is investigated through a series of laboratory experiments on curved and straight flumes. Both qualitative and quantitative observations confirm the suitability of the recent theoretical developments (Zolezzi & Seminara 2001) that indicate the occurrence of two distinct regimes of morphodynamic influence, depending on the value of the width ratio of the channel β. The threshold value βR separating the upstream from the downstream influence regimes coincides with the resonant value discovered by Blondeaux & Seminara (1985). Indeed it is observed that upstream influence may occur only in relatively wide channels, while narrower stream…
An intermediate level between the psychological and the neurobiological levels of descriptions of appraisal-emotion dynamics
2005
Conceptual space is proposed as an intermediate representation level between the psychological and the neurobiological levels of descriptions of appraisal and emotions. The main advantage of the proposed intermediate representation is that the appraisal and emotions dynamics are described by using the terms of geometry.
Role of the reagents consumption in the chaotic dynamics of the Belousov-Zhabotitinsky oscillator in closed unstirred reactors
2010
Chemical oscillations generated by the Belousov–Zhabotinsky reaction in batch unstirred reactors, show a characteristic chaotic transient in their dynamical regime, which is generally found between two periodic regions. Chemical chaos starts and finishes by following a direct and an inverse Ruelle–Takens–Newhouse scenario, respectively. In previous works we showed, both experimentally and theoretically, that the complex oscillations are generated by the coupling among the nonlinear kinetics and the transport phenomena, the latter due to concentration and density gradients. In particular, convection was found to play a fundamental role. In this paper, we develop a reaction–diffusion–convecti…