Search results for "dynamics"
showing 10 items of 9782 documents
Non-uniform Sediment Transport Estimation in Non-equilibrium Situations: Case Studies
2014
Abstract Quantitative estimate of sediment transport in alluvial channels is one of the most important task in river engineering. Even today, numerical models of sediment transport processes are confronted with some difficulties, often of conceptual nature. One of these difficulties is the simulation of non-uniform sediment transport in non-equilibrium situations, which requires the characterization of the ability of the alluvial system to immediately overcome the variations of the sediment boundary conditions. In this work a 1-D numerical model, which includes a new expression of the so-called “adaptation coefficient”, has been applied to test its capability to simulate the transient bed p…
Thermodynamics of small systems embedded in a reservoir: a detailed analysis of finite size effects
2012
International audience; We present a detailed study on the finite size scaling behaviour of thermodynamic properties for small systems of particles embedded in a reservoir. Previously, we derived that the leading finite size effects of thermodynamic properties for small systems scale with the inverse of the linear length of the small system, and we showed how this can be used to describe systems in the thermodynamic limit [Chem. Phys. Lett. 504, 199 (2011)]. This approach takes into account an effective surface energy, as a result of the non-periodic boundaries of the small embedded system. Deviations from the linear behaviour occur when the small system becomes very small, i.e. smaller tha…
Structural, energetic and kinetic database of catalytic reactions: Benzyl alcohol to benzaldehyde oxidation on MnOx clusters
2021
Abstract Data here reported are connected with the research article “Benzyl Alcohol to Benzaldehyde Oxidation on MnO x Clusters: Unraveling Atomistic Features” Gueci et al. [1] . This work described and discussed structural and energetic results, calculated by Density Functional Theory (DFT). In order to get kinetic information, DFT results were refined by an original approach, which will be shortly described in the following article. The crossed analysis of experimental and computational energetic and kinetic data allowed to (i) reconstruct the complicated lattice that connects the primary and secondary mechanisms of the reaction and (ii) identify alternative process pathways capable of by…
Forecasting the Cell Temperature of PV Modules with an Adaptive System
2013
The need to reduce energy consumptions and to optimize the processes of energy production has pushed the technology towards the implementation of hybrid systems for combined production of electric and thermal energy. In particular, recent researches look with interest at the installation of hybrid system PV/T. To improve the energy performance of these systems, it is necessary to know the operating temperature of the photovoltaic modules. Furthermore, when photovoltaic (PV) systems replace the traditional building envelope materials and they are fully integrated (building integrated photovoltaic (BIPV)), it is very important to correctly assess their thermal behaviour. The determination of …
Optical properties of TiO2 suspensions: Influence of pH and powder concentration on mean particle size
2007
WOS: 000250584100025
A reaction engineering approach to kinetic analysis of photocatalytic reactions in slurry systems
2016
Abstract The knowledge of the rate equation is fundamental for the assessment of the activity of the photocatalytic material and for the study, design and optimization of photocatalytic reactors. In the case of photocatalytic reactions, the local volumetric rate of photon absorption (LVRPA) affects the reaction rate and its inherently uneven distribution within a “slurry” reactor makes complex a correct kinetic analysis. In the present work it is shown which are the critical aspects of the kinetic analysis in slurry reactors and how to carry out photocatalytic experiments to minimize the misinterpretations of the experimental results. In particular, the influence of the type of illumination…
Energy harvesting by waste acid/base neutralization via bipolar membrane reverse electrodialysis
2020
Bipolar Membrane Reverse Electrodialysis (BMRED) can be used to produce electricity exploiting acid-base neutralization, thus representing a valuable route in reusing waste streams. The present work investigates the performance of a lab-scale BMRED module under several operating conditions. By feeding the stack with 1 M HCl and NaOH streams, a maximum power density of ~17 W m−2 was obtained at 100 A m−2 with a 10-triplet stack with a flow velocity of 1 cm s−1, while an energy density of ~10 kWh m−3 acid could be extracted by a complete neutralization. Parasitic currents along feed and drain manifolds significantly affected the performance of the stack when equipped with a higher number of t…
A mathematical tool for describing the behaviour of a dense effluent discharge
2009
In many cases a dense effluent has to be discharged in the environment with possible harmful consequences. The preferred design for the relevant discharge unit is that of a simple or multi-port diffuser issuing jets at a given inclination above the horizontal. This work presents the follow-on developments of a model previously proposed to predict the behaviour of inclined dense jets issuing in a stagnant environment. It consists of a set of three ordinary differential equations that can be solved by standard numerical methods. Model outputs include information on the trajectory, spreading and dilution of inclined dense jets, return point position and concentration. Interestingly the model a…
Regeneration units for thermolytic salts applications in water & power production: State of the art, experimental and modelling assessment
2021
Abstract Thermolytic solutions are often proposed as high salinity or “draw” stream to generate a chemical potential driving force in Salinity Gradient Power (SGP) and Forward Osmosis (FO) technologies. Depleted “draw” solutions exiting the process can be regenerated by a thermal process powered at very-low grade heat, which is able to decompose the salt into gaseous ammonia and carbon dioxide, which can be stripped and then reabsorbed in the draw solution, restoring its initial concentration. In this work, two different experimental prototypes for the regeneration of ammonium bicarbonate aqueous solution were designed, built and tested. The effect of several operating parameters on the reg…
Quasi-isoactinic reactor for photocatalytic kinetics studies
2007
Photochemical reactors characterized by almost uniform values of the local volumetric rate of photon absorption (LVRPA), i.e., quasi-isoactinic photoreactors, are particularly suitable for assessing the influence of radiant field intensity in kinetic studies. In this work, Monte Carlo simulations have been performed to obtain LVRPA values in a flat photoreactor irradiated on both sides. This configuration appears to be particularly suitable for obtaining quasi-isoactinic conditions. The influence of catalyst albedo and scattering phase function is assessed, and the conditions for obtaining iso-actinicity are discussed. Finally, these conditions are related to an easy-to-measure parameter, n…