Search results for "ear-infrared spectroscopy"
showing 10 items of 139 documents
Nondestructive Direct Determination of Heroin in Seized Illicit Street Drugs by Diffuse Reflectance near-Infrared Spectroscopy
2008
A new method has been developed for the fast and nondestructive direct determination of heroin in seized street illicit drugs using partial least-squares regression analysis of diffuse reflectance near-infrared spectra. Data were obtained from untreated samples placed in standard glass chromatography vials. A heterogeneous population of 31 samples, previously analyzed by a reference method, was employed to build the calibration model and to have a separated validation set. Based on the use of zero-order data for a calibration set of 21 samples, after standard normal variate and quadratic linear removed baseline correction (detrending), in the wavelength range from 1111 to 1647 nm, 8 PLS fac…
Testing of the region of Murcia soils by near infrared diffuse reflectance spectroscopy and chemometrics.
2008
A partial least squares near infrared (PLS-NIR) method has been developed for the determination of several physicochemical parameters in soils from different locations of the Region of Murcia. The method was based on the proper chemometric treatment of diffuse reflectance spectra of soil samples. Reflectance spectra were scanned from samples stored in glass vials in the NIR region between 800 and 2600 nm, averaging 36 scans per spectrum at a resolution of 8 cm(-1). Models were built using reference data of 39 samples selected from a dendrogram obtained after hierarchical cluster analysis of NIR spectra of soils and prediction parameters were established from a validation set of 109 addition…
Electronic and vibrational signatures of the Au102p-MBA44 cluster
2011
Optical absorption of a gold nanocluster of 102 Au atoms protected by 44 para-mercaptobenzoic acid (p-MBA) ligands is measured in the range of 0.05-6.2 eV (mid-IR to UV) by a combination of several techniques for purified samples in solid and solution phases. The results are compared to calculations for a model cluster Au(102)(SMe)(44) based on the time-dependent density functional theory in the linear-response regime and using the known structure of Au(102)(p-MBA)(44). The measured and calculated molar absorption coefficients in the NIR-vis region are comparable, within a factor of 2, in the absolute scale. Several characteristic features are observed in the absorption in the range of 1.5-…
New insights into the surface functionalities and adsorption evolution of water molecules on silica gel surface: A study by second derivative near in…
2010
Accepted version of an article in the journal: Vibrational Spectroscopy. Published version available on Science Direct: http://dx.doi.org/10.1016/j.vibspec.2010.06.003 Surface functionalities and adsorption evolution of water molecules on silica gel samples were studied by second derivative near infrared spectroscopy. Four different silica gel samples with varying surface area were used in this experiment. Each of the dry samples was allowed to equilibrate with surrounding air and the near infrared spectra were accumulated at different time intervals using reflectance technique. The evolved spectra were analysed using second derivative technique to study the adsorption evolution of water mo…
Transition probabilities for some infrared O I spectral lines—Application for determining excitation temperatures in low temperature plasmas
2008
Intensities of selected spectral transitions of neutral oxygen emitted from a wall-stabilized arc have been measured. Applying reliable transition probability data taken from literature, Boltzmann plots have been constructed and the temperatures of the plasma have been obtained. At arc plasma conditions ensuring partial local thermal equilibrium, transition probabilities for 4 O I spectral lines from the near infrared spectral range have been obtained. These new results, together with data for two other studied O I spectral lines taken from the National Institute of Standards and Technology data base, are proposed as a suitable set of transition probabilities applicable for diagnostics of l…
Land surface temperature retrieval from LANDSAT TM 5
2004
In this paper, three methods to retrieve the land surface temperature (LST) from thermal infrared data supplied by band 6 of the Thematic Mapper (TM) sensor onboard the Landsat 5 satellite are compared. The first of them lies on the estimation of the land surface temperature from the radiative transfer equation using in situ radiosounding data. The others two are the mono-window algorithm developed by Qin et al. [International Journal of Remote Sensing 22 (2001) 3719] and the single-channel algorithm developed by Jime´nez-Mun˜oz and Sobrino [Journal of Geophysical Research 108 (2003)]. The land surface emissivity (LSE) values needed in order to apply these methods have been estimated from a…
Achromatic linear retarder with tunable retardance
2018
We present a universal design and proof-of-concept of a tunable linear retarder of uniform wavelength response in a broad spectral range. It consists of two half-wave retarders (HWR) between two quarter-wave retarders (QWRs), where the uniform retardance can be tuned continuously by simply rotating one of the HWRs. A proof-of-concept of this design is built by using commercially available Fresnel rhomb retarders that provide retardation with almost wavelength uniformity in the visible and near infrared from 450 to 1550 nm. The design is universal, since other achromatic QWRs and HWRs could also be employed. The system is experimentally demonstrated to control the state of polarization of a …
Conversion of nadir, narrowband reflectance in red and near-infrared channels to hemispherical surface albedo
1997
Abstract Measured nadir-viewed narrow-band reflectanees in red and near infrared channels simulating AVHRR Channels 1 and 2 are compared with measured integrated solar spectrum hemispherical albedos. Reflectanees and albedos were measured from an aircraft over four widely different vegetation surfaces in southeastern Tasmania (Australia). A linear function is used to simultaneously correct for narrow band to broad band conversion errors and to convert nadir viewed reflectances to hemispherical albedos. While the application of the conversion equation presented is limited to the vegetation types of the study, the equation is independent of vegetation type. Results indicate that the reflectan…
Near infrared spectroscopic study on the adsorption of methanol on silica gel
2013
Author's version of an article in the journal: Advanced Materials Research. Also available from the publisher at: http://dx.doi.org/10.4028/www.scientific.net/AMR.650.150 The silanol groups on Silica gel surface are sites for adsorption of polar molecules. Alcohols and other polar molecules are easily adsorbed by forming hydrogen bondings with OH groups on silica gel surface. A study on the adsorption of methanol on silica gel was carried out by using NIR spectroscopy in combination with ssecond derivative techniques. Four of the well characterised silica gel samples were used in this study. Each of the silica gel (0.25g) samples with different surface areas and silanol number was pressed i…
Partial least squares-near infrared determination of pesticides in commercial formulations
2007
Abstract A solvent free, fast and environmentally friendly near infrared-based methodology (NIR) was developed for pesticide determination in commercially available formulations. This methodology was based on the direct measurement of the diffuse reflectance spectra of solid samples and a multivariate calibration model (partial least squares, PLS) to determine the active principle concentration in commercial formulations. The PLS calibration set was built on using the spiked samples by mixing different amounts of pesticide standards and powdered samples. Buprofezin, Diuron and Daminozide were used as test analytes. Concentration of Buprofezin in the samples was calculated employing a 4-fact…