Search results for "efficient"
showing 10 items of 1603 documents
Multi-resolution error analysis of predicted absorption coefficients. Method and computer implementation. Application to the IR spectrum of methane a…
2009
A general method for the estimation of the confidence interval of molecular absorption coefficients is presented. It combines statistical numerical experiments with analytical calculations. The method uses line parameter predictions (position and intensity) with known estimated uncertainties. The propagation of errors from line parameters to absorption coefficients or cross-sections are analyzed in detail as a function of the resolution. This work is especially intended to provide expert information for applications requiring theoretical predictions for which the present state of the art of line by line high-resolution modeling is not accurate enough to meet the experimental precision. As a…
Multi-Resolution error analysis of predicted absorption coefficients. Method and computer implementation. Application to the infrared spectrum of met…
2009
A general method for the estimation of the confidence interval of molecular absorption coefficients is presented. It combines statistical numerical experiments with analytical calculations. The method uses line parameter predictions (position and intensity) with known estimated uncertainties. The propagation of errors from line parameters to absorption coefficients or cross-sections are analyzed in detail as a function of the resolution. This work is especially intended to provide expert information for applications requiring theoretical predictions for which the present state of the art of line by line high-resolution modeling is not accurate enough to meet the experimental precision. As a…
Experimental and theoretical study of line mixing in methane spectra. III. The Q branch of the Raman nu(1) band
2000
International audience; The shape of the nu(1) Raman Q branch of CH4 perturbed by Ar and He at room temperature has been studied. Stimulated Raman spectroscopy (SRS) experiments have been made in the 2915-2918 cm(-1) spectral region for total pressures from 0.4 to 70 atm and mixtures of approximate to 5% CH4 with He and Ar. Analysis of the spectra demonstrates that the shape of the Q branch is significantly influenced by line mixing and much narrower than what is predicted by the addition of individual line profiles. For the first time, a model is proposed for the calculation and analysis of the effects of collisions on the considered spectra. In this approach, the rotational part of the re…
Thermodiffusion anisotropy under a magnetic field in ionic liquid-based ferrofluids
2021
International audience; Ferrofluids based on maghemite nanoparticles (NPs), typically 10 nm in diameter, are dispersed in an ionic liquid (1-ethyl 3-methylimidazolium bistriflimide - EMIM-TFSI). The average interparticle interaction is found to be repulsive by small angle scattering of X-rays and of neutrons, with a second virial coefficient A2 = 7.3. A moderately concentrated sample at Φ = 5.95 vol% is probed by forced Rayleigh scattering under an applied magnetic field (up to H = 100 kA m-1) from room temperature up to T = 460 K. Irrespective of the values of H and T, the NPs in this study are always found to migrate towards the cold region. The in-field anisotropy of the mass diffusion c…
Libération du sodium et des composés d'arôme dans des modèles fromagers aromatisés : influence de la structure et de la composition
2010
Authorities have called for salt content to be reduced in various food products. Cheese appears to be one of the most targeted products. In order to understand how to reduce salt content in model cheeses without modifying salty perception, the interactions between in-mouth sodium release and cheese composition and structure have to be studied. . The current study was conducted to determine how the release of aroma compounds and sodium ions could be modified by the structure and the composition of model cheese (lipid/protein ratio, sodium content ...). This will be done by in vivo and in vitro approaches. 23Na Nuclear Magnetic Resonance (NMR) spectroscopy was used to study the mobility and t…
Acoustical properties of air-saturated porous material with periodically distributed dead-end pores
2015
International audience; A theoretical and numerical study of the sound propagation in air-saturated porous media with straight main pores bearing lateral cavities (dead-ends) is presented. The lateral cavities are located at " nodes " periodically spaced along each main pore. The effect of periodicity in the distribution of the lateral cavities is studied, and the low frequency limit valid for the closely spaced dead-ends is considered separately. It is shown that the absorption coefficient and transmission loss are influenced by the viscous and thermal losses in the main pores as well as their perforation rate. The presence of long or short dead-ends significantly alters the acoustical pro…
Propriétés acoustiques de matériaux poreux saturés d'air incluant une porosité partiellement ouverte
2010
International audience; Nous étudions les propriétés d'un matériau à microgéométrie complexe incluant une porosité partiellement ouverte ou de culs-de-sacs. Ce type de matériau peut être obtenu par dissolution de grains de sel (NaCl) noyés dans une matrice de métal solidifié. Cette matrice est obtenue après invasion sous pression négative et à haute température des grains de sels par le métal sous forme liquide, puis refroidissement jusqu'à solidification du métal. La comparaison des résultats expérimentaux et théoriques sur le coefficient d'absorption acoustique d'une couche de ce métal poreux montre que le modèle de Biot-Johnson-Allard ne fournit pas des résultats aussi satisfaisants que …
Study of relationships between the structure of aroma compounds and their retention-release between vapour phase and dairy gels
2010
An integrated approach physicochemistry and structures activity relationships has been carried out to study the aroma compounds retention-release phenomenon in a fat free dairy gel added with pectin. This study aimed to identify the molecular properties that govern this phenomenon assuming that modifying the structure leads automatically to a change in the retention-release of aroma compounds. For this purpose, we have determined the partition coefficients of 28 aroma compounds in water, in pectin gels and in dairy gels supplemented or not supplemented with pectin, at equilibrium conditions using the PRV method (Phase Ratio Variation). Then, we have performed a structure-retention relations…
A simple method for estimating downward longwave radiation from surface and satellite data by clear sky
1990
Abstract An attempt to derive downward longwave radiation at the surface in clear sky conditions is presented. A method that integrates satellite-measured infrared radiation temperatures with ground measurements of water vapour pressure is applied to Meteosat data. Satellite-derived fluxes are compared with corresponding ground-measured fluxes at three different sites in France and during various seasons. Comparison of the daily averaged fluxes shows a correlation coefficient of 0–88 and an r.m.s. difference between satellite estimates and ground measurements of 12 Wm-2.
Improving IoT Communications Based on Smart Routing Algorithms
2018
International audience; Due to the recorded success by Internet of Things (IoT) technology, more and more domains use it as a communications and exchange network such as e-health, smart cities, vehicles, etc. IoT don’t stop integrating an important number of components and objects that are characterized by their complexity and heterogeneity. Such constraints make the existing routings protocols unsuitable for IoT communications. To accomplish all the expected tasks and satisfy the user services, it is important to guarantee a quality of communication that answers to the requirements of the various applications in terms of data and processing (availability, integrity, efficiency, etc.). The …