Search results for "electrodialysi"
showing 10 items of 159 documents
Optimization of net power density in Reverse Electrodialysis
2019
Abstract Reverse Electrodialysis (RED) extracts electrical energy from the salinity difference between two solutions using selective ion exchange membranes. In RED, conditions yielding a large net power density (NPD) are generally desired, due to the still large cost of the membranes. NPD depends on a large number of physical and geometric parameters. Some of these, for example the inlet concentrations of concentrate and diluate, can be regarded as “scenario” variables, imposed by external constraints (e.g., availability) or chosen by different criteria than NPD maximization. Others, namely the thicknesses HCONC, HDIL and the velocities UCONC, UDIL in the concentrate and diluate channels, c…
Energy harvesting by waste acid/base neutralization via bipolar membrane reverse electrodialysis
2020
Bipolar Membrane Reverse Electrodialysis (BMRED) can be used to produce electricity exploiting acid-base neutralization, thus representing a valuable route in reusing waste streams. The present work investigates the performance of a lab-scale BMRED module under several operating conditions. By feeding the stack with 1 M HCl and NaOH streams, a maximum power density of ~17 W m−2 was obtained at 100 A m−2 with a 10-triplet stack with a flow velocity of 1 cm s−1, while an energy density of ~10 kWh m−3 acid could be extracted by a complete neutralization. Parasitic currents along feed and drain manifolds significantly affected the performance of the stack when equipped with a higher number of t…
ELECTROCHEMICAL TREATMENT OF WASTEWATERS DRIVEN BY REVERSE ELECTRODIALYSIS PROCESSES
2014
Wastewater treatment technology is undergoing a transformation due to more restrictive regulations governing the dischar ge and disposal of hazardous pollutants. Electrochemical based technologies are very promising methods for treating wastewaters containing organic and inorganic pollutants resistant to biological processes or toxic for microorganisms. These methods present numerous advantages including the utilisation of a green reagent such as the electron, very high removal of numerous recalcitrant pollutants, efficient disinfection, high flexibility and no necessity to transport or stock chemical oxidants or reducents. O n the other hand, a wide utilisation of such methods is likely to…
Towards the simultaneous generation of electric energy and the abatement of organic pollutants by reverse electrodialysis processes
2012
In reverse electrodialysis (RED) processes, electrical energy is directly extracted from chemical potential gradients arising from salinity differences, especially from sea and river water [1]. In RED there are at least four complementary elements: (1) electrodes, where electron transfer reactions occur to allow the transformation of the charge carrier from ion to electron; (2) ion selective exchange membranes, which allow the selective transport of ions; (3) solvents, which make a continuum for ion transport; (4) electrolytes, i.e. the current carriers between cathode and anode. The redox process is usually chosen in order to limit the energetic losses, the cost of redox specie and electro…
Neutralization of acid and base solutions by Reverse Electrodialysis with Bipolar Membranes: a sustainable way to recover energy
2020
The large amount of acidic wastewaters produced in various industrial processes can have a large economic and environmental impact. Companies producing waste acid solutions have to send them to specific sites for the neutralization with alkaline solutions. However, efforts have been devoted so far to promote the acid recovery or its reuse. In the perspective of a more circular manufacturing approach, the present work proposes for the first time the use of the novel Bipolar Membrane Reverse Electrodialysis technology as a viable on-site way to convert the chemical energy associated to the pH gradient of waste acid/base solutions into electrical energy. Bipolar Membrane Reverse Electrodialysi…
Techno-economic evaluation of Reverse Electrodialysis process in different real environments
2018
Salinity Gradient Power is a promising renewable energy source based on the recovery of the chemical potential released from the mixing of solutions at different concentrations. Natural salinity gradients are extensively available worldwide in natural reservoirs. Reverse Electrodialysis is an innovative technology able to perform a direct conversion of the energy of mixing into electricity. Salinity gradients coming from natural resources or from human activities are worldwide available. In the present work a number of different scenarios, including natural resources (e.g. rivers, seas, lakes and salt ponds), industrial/urban wastes (e.g. brine and treated wastewaters) are analysed. The aim…
Electrochemical Processes and Apparatuses for the Abatement of Acid Orange 7 in Water
2014
We have studied the electrochemical treatment of aqu eous solutions contaminated by Acid Orange 7 (AO7) by electro-Fenton process (EF). The main object ive was to evaluate how the electrochemical route affects the performances of the d egradation process. EF process was carried out in a number of very different reactors: conventional bench scale electrochem ical cell, microfluidic electrochemical reactor, microbial fuel cell and stack for reverse electrodialysis processes. The utilisation of micro devices allowed to work without the addition of a supporting elec trolyte and improved the performances of EF. Microbial fuel cell did not need the supply of electric energy bu t our device requir…
A novel Reverse Electrodialysis application to generate power from low-grade heat
2015
A novel idea for the conversion of low-temperature heat into electricity is based on the generation of electricity from salinity gradients using a Reverse Electrodialysis (RED) device in a closed-loop system. In this concept a limited amount of artificial saline solutions can be used as the working fluids in a closed-loop. The solutions exiting from the RED unit are then regenerated, in order to restore the original salinity gradient, by means of a separation step, which uses low-temperature heat (40-100°C) as its energy source. A theoretical analysis of potentials of this technology is illustrated in the present work.
Energy generation and abatement of Acid Orange 7 in reverse electrodialysis cells using salinity gradients
2015
Abstract The simultaneous generation of electric energy and the treatment of wastewaters contaminated by an organic pollutant resistant to conventional biological processes, Acid Orange 7 (AO7), was achieved for the first time using proper redox processes by reverse electrodialysis using salinity gradients. The stack was fed with two aqueous solutions with different concentrations of NaCl and a synthetic wastewater contaminated by AO7. Various electrochemical approaches including electro-Fenton, electrogeneration of active chlorine (IOAC) and coupled process were performed in a stack equipped with 40–60 cell pairs and studied by focused electrolyses. The effect of the number of cell pairs a…
Investigation of electrode material – Redox couple systems for reverse electrodialysis processes. Part I: Iron redox couples
2012
Abstract The performances of electrodialysis (ED) and reverse electrodialysis (RED) processes depend on several factors, including the nature of the electrode material and of the redox couple adopted to make possible the conversion between electric power and chemical potential. In this paper, the possible utilization of iron-based redox couples (FeCl3/FeCl2, hexacyanoferrate(III)/hexacyanoferrate(II) and Fe(III)-EDTA/Fe(II)-EDTA) on graphite and DSA electrodes for RED processes was studied by a detailed experimental investigation. The hexacyanoferrate(III)/hexacyanoferrate(II) system was stable for long time (more than 12 days) in the absence of light and oxygen at high redox couple concent…