Search results for "electromagnetic radiation"

UV photobleaching of carbon nanodots investigated by in situ optical methods.

2020

Carbon dots are a family of optically-active nanoparticles displaying a combination of useful properties that make them attractive for many applications in photonics and photochemistry. Despite the initial claims of high photostability of carbon dots even under prolonged illuminations, several recent studies have evidenced their photobleaching (PB) under UV light, detrimental for some applications. A study of the mechanism and dynamics of carbon dot PB can be considered a useful route to gather relevant information on the underlying photophysics of these nanoparticles, which is still widely debated. Here we report a study of the PB of carbon dots under UV light, conducted through optical ex…

Affordable, ultra-broadband coherent detection of terahertz pulses via CMOS-compatible solid-state devices

2017

We demonstrate the first fully solid-state technique for the coherent detection of ultra-broadband THz pulses (0.1-10 THz), relying on the electric-field-induced second-harmonic generation attained in integrated CMOS-compatible devices.

Transition radiation in the x-ray region from a low emittance 855 MeV electron beam

1997

A quasi-monochromatic hard x-ray beam with a photon energy of 33 keV has been produced from transition radiation (TR) at the Mainz Microtron MAMI. The radiator was a stack of 30 polyimide foils of 25 μm thickness and 75 μm separation and the monochromator a highly-oriented pyrolytic graphite crystal. The intrinsic bandwidth was measured with a critical absorption technique to be 100 eV. On the basis of these experiments a photon flux of 4⋅109/mm2s over an illuminated area of 5.7×125 mm2 can be expected from an optimized beryllium radiator at a beam current of 100 μA. At the K-absorption edge of titanium at 5 keV narrow band transition radiation has been observed from a stack of four foils o…

Photocycle of Excitons in Nitrogen-Rich Carbon Nanodots: Implications for Photocatalysis and Photovoltaics

2020

Nitrogen-rich carbon nanodots have emerged as promising nanomaterials for a wide range of applications where a highly emissive and photoactive material with low toxicity and cost-effectiveness is required. One of their hallmarks is indeed a bright, tunable fluorescence of excitonic nature. Disentangling the origin of their optical absorption and fluorescence properties and uncovering relaxation channels and interactions with solvents are some of the most debated issues in the field. Uncovering these aspects is essential for targeted applications, especially in the fields of photocatalysis but also photovoltaics and optoelectronics. Here, we present dedicated transient absorption measurement…

Defined-length Carbon-rich Conjugated Oligomers

2006

Radiation Defects in LiBaF3 Perovskites

2000

We investigated the electron paramagnetic resonance (EPR), recombination afterglow, thermostimulated luminescence (TSL) and absorption of LiBaF3 perovskites crystals X-irradiated at 80 K The self-trapped hole centre VK(F2-) oriented along the [110] axis and electron F type (FA) centres are identified. X-irradiation at temperatures below 200 K results in creation of a long-term temperature-independent afterglow-tunnelling luminescence (TL), with main emission bands at 300, 370 nm and 430 nm. The short wavelength TL bands are associated with the tunnelling recombination of the F type centre with the VK centre. The thermal stability of VK centre is estimated to be about 130 K.

Photothermal contrast reaches single-molecule sensitivity.

2011

Periodic unmixing of a binary metallic vapor

2005

We report on a type of surface structuring after short pulse laser ablation of a binary alloy. We observe the emergence of a concentric ring structure with changing elemental composition. The composition changes are interpreted by condensation of the ambient ablation vapor due to stress wave excitations in the ablation spot.

A Comparative Study of Top-Down and Bottom-Up Carbon Nanodots and Their Interaction with Mercury Ions

2021

We report a study of carbon dots produced via bottom-up and top-down routes, carried out through a multi-technique approach based on steady-state fluorescence and absorption, time-resolved fluorescence spectroscopy, Raman spectroscopy, infrared spectroscopy, and atomic force microscopy. Our study focuses on a side-to-side comparison of the fundamental structural and optical properties of the two families of fluorescent nanoparticles, and on their interaction pathways with mercury ions, which we use as a probe of surface emissive chromophores. Comparison between the two families of carbon dots, and between carbon dots subjected to different functionalization procedures, readily identifies a …

Poor optical stability of molecular dyes when used as absorbers in water-based tissue-simulating phantoms

2019

Biomedical optical systems and models can be easily validated by the use of tissue-simulating phantoms. They can consist of water-based turbid media which often include inks (India ink and molecular dyes) as absorbers. Optical stability of commonly exploited inks under the influence of light, pH changes and the addition of TiO2 and surfactant, was studied. We found that the exposure to ultraviolet and visible light can crucially affect the absorption properties of molecular dyes. On average, absorption peaks decreased by 47.3% in 150 exposure hours. Furthermore, dilution can affect ink’s pH and by that, its decay rate under light exposure. When TiO2 was added to the phantoms, all molecular …