Search results for "electromagnetic"
showing 10 items of 1595 documents
Hot-Carrier Generation in Plasmonic Nanoparticles: The Importance of Atomic Structure
2020
Metal nanoparticles are attractive for plasmon-enhanced generation of hot carriers, which may be harnessed in photochemical reactions. In this work, we analyze the coherent femtosecond dynamics of photon absorption, plasmon formation, and subsequent hot-carrier generation through plasmon dephasing using first-principles simulations. We predict the energetic and spatial hot-carrier distributions in small metal nanoparticles and show that the distribution of hot electrons is very sensitive to the local structure. Our results show that surface sites exhibit enhanced hot-electron generation in comparison to the bulk of the nanoparticle. While the details of the distribution depend on particle s…
Electron transfer in ZnO–Fe2O3 aqueous slurry systems and its effects on visible light photocatalytic activity
2017
ZnFex (x = 0.025, 0.05, and 0.1) nanocomposites and pure ZnO and Fe2O3 photocatalysts were synthesized by a simple sol–gel route and characterized by means of specific surface area (SSA) analysis, X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), and transmission electron microscopy/energy dispersive X-ray spectroscopy (TEM/EDS). Their photocatalytic activity was investigated under visible light by using methylene blue (MB) and benzoic acid (BA) as model compounds. Coupling ZnO and Fe2O3 results in higher photocatalytic activity with respect to the pure materials. Photoelectrochemical characterization performed in slurry systems allowed the elucidation of the electronic struc…
Photoactivity under visible light of metal loaded TiO2 catalysts prepared by low frequency ultrasound treatment
2017
Abstract Visible-light responsive bare and metal loaded (Pt, Ag, Rh, Pd) TiO 2 photocatalysts were prepared by using a simple ultrasound treatment. This method induced bulk oxygen deficiency resulting in a narrowing bandgap (from 3.18 to 3.04 eV) and in visible light absorption. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), BET specific surface area (SSA) and pore size distribution (PSD), UV–vis diffuse reflectance spectroscopy (DRS), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). The photocatalytic activity of the samples was evaluated by using the 4-nitrophenol oxidation reaction and the photocatalytic oxidation of glucose w…
Doped TiO2 Nanomaterials and Applications
2008
This special issue brieflyreviews some trends and factors that have impacted heterogeneous photocatalysis with next generation TiO2 nanophotocatalysts that could absorband make use of both UV (290–400 nm) and visible (400–700 nm) sunlight to enhance process efficiencies, along with some issues of current debate in the fundamental understanding of the science that underpins the field. Preparative methods and some characteristics features of doped TiO2 as well as its environmental applications are presented and described. The next generation of doped TiO2 photocatalysts should enhance overall process photoefficiencies in many cases, since doped TiO2s absorb a greater quantity of solar radiati…
Effects of Ionising Radiation on Optical Properties of Lithium Niobate Single Crystals
2005
Studies of thermal and γ-irradiation effects on the optical properties in congruent lithium niobate single crystals containing Mg and Gd dopants including samples with double dopants Y, Mg are reported. Formation of defects at irradiation and thermal treatment of the samples is explored by analysis of the behaviour of electron absorption spectra. Considerable increase of absorption with the dose of γ-radiation is observed at 500 nm. The changes of absorption examined under different conditions are explained by creation and destruction of Nb 4+ defects.
Novel plasmonic sensor design using plasmon-induced transparency
2010
We introduce a novel sensor concept in the field of plasmonics, namely plasmon-induced transparency sensors. These sensors combine localized particle plasmon resonances with extremely small sensing volume with excellent sharp spectral resonances that show a good respose to refractive index changes of the surrounding environment. The principle is based on the plasmonic analog of electromagnetically induced transparency (EIT) between a radiative dipole and a nonradiative quadrupole antenna. This effect yields a spectrally narrow resonance within a broad localized particle plasmon resonance in the near-infrared spectral region [1, 2]. Using deposition of biotin and streptavidin, we demonstrate…
A Meshless Approach for Electromagnetic Simulation of Metallic Carbon Nanotubes
2009
In this paper, a study on the electromagnetic behaviour of a single wall carbon nanotube model is described. The electrons available for conduction are treated as a thin cylindrical layer fluid and their motion is described by means of classical hydrodynamics equations in linearized form. These equations are solved in time domain using the Smoothed Particle Hydrodynamics method. The method suitably handled runs on GRID environment.
Local structure of copper nitride revealed by EXAFS spectroscopy and a reverse Monte Carlo/evolutionary algorithm approach
2016
Physica scripta 91(5), 054003 (2016). doi:10.1088/0031-8949/91/5/054003
Low Temperature Optical Absorption by Magnons in KNiF3 and NiO Single-Crystals
2000
Optical absorption spectra of KNiF3 and NiO stoichiometric single-crystals were measured at 5 K in the range from 4000 to 50000 cm-1. The observed bands are interpreted based on the energy levels diagram for Ni2+ (3d 8 ) ion in a cubic crystal field. The crystal-field parameter Dq is equal to 766 cm-1 in KNiF3 and 890 cm-1 in NiO. Particular attention is paid to the band due to the magnetic-dipole 3A2g(F)→3T2g(F) transition, located at 7700 cm-1 in KNiF3 and at 8900 cm-1 in NiO. We show that the energy difference between the two peaks, located at the low energy side of the band, is related to the zone-center (k=0) one-magnon energy, so that the low-energy peak is attributed to the pure exci…
Optical, X-ray absorption and photoelectron spectroscopy investigation of the Co site configuration in Zn1−xCoxO films prepared by pulsed laser depos…
2007
Abstract In this paper, we investigate the Co site configuration in Zn1−xCoxO thin films by means of different spectroscopic techniques. Thin films were prepared by pulsed laser deposition with Co proportion from 1% to 30%. The Co 2p doublet observed in the X-ray photoelectron spectra exhibits the spin–orbit splitting and shake-up satellites typical of Co+2 ionization states. X-ray absorption spectra at the Co K-edge, taken in fluorescence mode, unambiguously show that Co atoms are in tetrahedral configuration substituting for Zn over the whole composition range. Optical absorption spectra provide further evidence of the tetrahedral coordination of Co cations, both through the internal tran…