Search results for "electromigration"
showing 10 items of 19 documents
Electroosmotic effects in the determination of ion mobilities of carrier-free radionuclides in free aqueous electrolyte solutions
2001
A device for on-line electromigration studies of radio-elements in free electrolytes has been tested by measuring the absolute individual ion mobilities of no-carrier-added single charged anions [99mTc]TcO4 - and [18F]F- and differently charged cations [137Cs]Cs+, [57Co]Co2+ and [241Am]Am3+ in inert aqueous electrolytes at 298.1 K. The observed ion mobilities were found to be influenced by electroosmosis in the migration tube. A relation to correct this effect is proposed. In addition, it was shown that the effect of electroosmosis may be suppressed by chemical treatment of the surface of the migration tube.
The electromigration and diffusion of hydrogen in molybdenum
1990
Abstract The electromigration and diffusion of hydrogen atoms in molybdenum were investigated using the resistance method in the temperature range 293–773 K. The following dependence of the diffusion coefficient D and electrical mobility vE on temperature were obtained: D = (5.3 ± 1.53) × 10 −10 exp {− (0.8 ± 0.01) eV kT } { m 2 s −1 } v E = (1.24 ± 0.19) × 10 −8 exp {− (0.9 ± 0.01) eV kT }{ m 2 ( V s ) −1 } . The hydrogen migrates towards the cathode and the effective valency grows with temperature, fulfilling the relation Z eff = (1.42 ± 0.03) − (5.0 ± 0.2) × 10 −8 (Ω m ) ρ ; where ρ is the specific electric resistance.
Investigation of Different Iontophoretic Currents Profiles for Short-Term Applications in Cosmetics.
2018
[EN] This study aimed at investigating the effect of electrical current profile upon the iontophoretic transport of (i) ascorbic acid (AA) and (ii) ellagic acid (EA), into porcine skin in vitro, and the impact of the physicochemical properties of both actives on their mechanism of transport when formulated in cosmetic compositions. The experiments were performed using a proprietary iontophoretic device containing a roller to apply the formulation. Three current profiles were tested: (i) galvanic direct current (DC), (ii) square unipolar pulse current (SPC), and (iii) galvanic direct current (DC) + pulse current (PC). The skin samples were collected at different sampling points, extracted an…
The influence of external uniaxial stretching on the electromigration and diffusion of hydrogen in iron
2009
Electromigration and diffusion of hydrogen in iron, depending on unit elongation, were investigated. The resistivity method was applied in the investigations. It was found that the obtained experimental results cannot be described by means of a single flux of hydrogen, which diffuses in the electric field. In order to explain the obtained results, we assumed the existence of the following two fluxes of hydrogen in the stretched metal: migration, according to the interstitial mechanism, and migration according to the interstitial-defective mechanism. The dependence of effective valences and diffusion coefficients for both mechanisms were determined.
Microwave-induced electromigration in multicomponent metallic alloys
2010
The crystallization of amorphous FeCoCuZrAlSiB alloy ribbons during microwave heating was investigated in situ using time-resolved X-ray powder diffraction. The formation of the nanocrystalline α-(Fe,Co)(SiAl) phase during the primary crystallization stage is followed by the crystallization of the residual glassy matrix. Scanning electron microscopy analysis after microwave exposure reveals the formation of nanosized hillocks evenly distributed over the ribbon surfaces. Local chemical composition analysis by energy-dispersive spectroscopy shows that the surface clusters are enriched in Cu and Al. The occurrence of this typical electromigration effect imposes a strong restriction on the dura…
Influence of the external stretching on hydrogen electromigration in palladium
2002
Abstract Electromigration and diffusion of hydrogen in palladium depending on unit elongation were investigated. It was found that the obtained experimental results cannot be described by means of a single flux of hydrogen, which diffuses in a gradient of electric field. In order to effectively explain the obtained results, a theoretical model was elaborated. It assumed the existence of the following two fluxes of hydrogen in the stretched metal: • Ji—of migration, according to the interstitial mechanism, and • Ji-d—of migration, according to the interstitial-defective mechanism. Dependence of effective valences and diffusion coefficients for both mechanisms of transportation were determine…
Pre-determining the location of electromigrated gaps by nonlinear optical imaging
2014
In this paper we describe a nonlinear imaging method employed to spatially map the occurrence of constrictions occurring on an electrically-stressed gold nanowire. The approach consists at measuring the influence of a tightly focused ultrafast pulsed laser on the electronic transport in the nanowire. We found that structural defects distributed along the nanowire are efficient nonlinear optical sources of radiation and that the differential conductance is significantly decreased when the laser is incident on such electrically-induced morphological changes. This imaging technique is applied to pre-determined the location of the electrical failure before it occurs.
Influence of external stretching on hydrogen electromigration in Pd and PdCu, PdAg alloys
2005
Influence of external stretching of Pd and Pd77Cu23 and Pd77Ag23 alloys on hydrogen electromigration in these systems was investigated. The electro-resistivity method was applied in the investigations. It was found that in order to furnish a full description of the kinetics and dynamics transport of hydrogen in the externally applied electric field to samples in the state of elastic and plastic stretching, it is not sufficient to provide a functional dependence of two commonly used parameters (diffusion coefficient D and effective valence Zeff) on degree of deformation. To describe the electromigration in these conditions a mathematical model was applied, which assumes the existence of two …
Contrôle de nano-antennes optiques par une commande électrique : tuner plasmonique et transduction
2011
Optical nano-antennae are the new class of components to control light/matterinteraction at the nanoscale. These devices are operating in the visible to near infraredpart of the spectrum. The properties of these nano objects are controlled by theform, the size and the material.In the radio frequency domain, the tuner changes dynamically the operatingwavelength of the antenna. In this thesis work, we search to transfer this conceptto the nanoscale. The principle is to change the load impedance of the antenna, i.e.changing the optical index of the dielectric medium around the nano-object. Forthat we used anisotropic liquid cristal molecules. The value of the optical index iscontrolled by appl…
Electron beam induced growth of silver nanowhiskers
2015
Abstract In this paper we report an electron beam induced rapid (up to several tens of nm/s) growth of silver nanowhiskers from silver nanowire networks coated with TiO 2 by sol–gel method. Different growth conditions are tested and it is demonstrated that growth is optimal for samples with the film thickness in the range 50–200 nm and previously annealed at 400 °C for 5–10 min. Growth mechanism is attributed to cooperative effect of several factors including diffusion of Ag into TiO 2 matrix during annealing, electromigration of Ag atoms caused by strong electric field, and presence of mechanical stresses at interfaces enhanced by thermal expansions due to local heating under e-beam illumi…